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材料导报  2023, Vol. 37 Issue (19): 22030161-8    https://doi.org/10.11896/cldb.22030161
  无机非金属及其复合材料 |
自蔓延高温合成先进材料的研究新进展
李正宁1,*, 喇培清2, 孟倩1,2, 王鸿鼎1, 王文科1, 康纪龙1, 蒲永亮1
1 兰州交通大学材料科学与工程学院,兰州 730070
2 兰州理工大学有色金属先进加工与再利用省部共建国家重点实验室,兰州 730050
New Progress in Self-propagating High Temperature Synthesis of Advanced Materials
LI Zhengning1,*, LA Peiqing2, MENG Qian1,2, WANG Hongding1, WANG Wenke1, KANG Jilong1, PU Yongliang1
1 School of Materials Science and Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China
2 State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
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摘要 自蔓延高温合成(SHS)技术利用反应体系自身的放热来维持反应的进行,是高效低成本制备特殊性能先进材料的方法之一。本文概述了自蔓延高温反应的燃烧机理,通过热力学计算证明了反应体系自加热实现高温的可能性,并介绍了化学计量数、反应物料量、保护气压力、反应物料颗粒大小、坯料密度和点火方式等工艺参数对SHS反应的影响,综述了SHS在无机非金属、金属间化合物、块体合金等材料制备中的研究新进展,最后总结了现有SHS的一些技术瓶颈、工艺难点以及相应的解决路径,并分析了该技术实现大规模产业化应用所需的条件。
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李正宁
喇培清
孟倩
王鸿鼎
王文科
康纪龙
蒲永亮
关键词:  自蔓延高温合成  无机非金属材料  金属间化合物  块体合金    
Abstract: Self-propagating high temperature synthesis (SHS) technology uses the reaction system itself to maintain the heat of the reaction. It is one of the efficient and low-cost methods to prepare advanced materials with special properties. In this paper, the combustion mechanism of the self-propagating high temperature reaction is summarized, the influence of reaction parameters such as stoichiometry of the reactants, quantity of reactants, gas pressure, reactant particle size, green density and ignition method, is briefly reported. The research progress of SHS in the preparation of inorganic nonmetallic materials, intermetallic compounds, bulk alloys and other materials is reviewed. Finally, some technical bottlenecks, technological difficulties and corresponding solutions of existing SHS technology are summarized, and the technical conditions for large-scale industrial application of this technology are analyzed.
Key words:  SHS    inorganic nonmetallic material    intermetallic compound    bulk alloy
出版日期:  2023-10-10      发布日期:  2023-09-28
ZTFLH:  TB303  
基金资助: 甘肃省教育厅创新基金项目(2021A-038);甘肃省自然科学基金项目(20JR10RA266;21JR7RA312);兰州交通大学青年基金(2020057)
通讯作者:  *李正宁,兰州交通大学材料科学与工程学院副教授、硕士研究生导师。2014年兰州理工大学材料加工工程专业硕士毕业,2019年兰州理工大学材料物理与化学专业博士毕业后到兰州交通大学工作至今。目前主要从事材料燃烧合成制备与性能调控、高性能金属材料制备与强韧化等方面的研究工作。发表论文10余篇,包括Materials Letters、Metals and Materials International、Journal of Rare Earths、Materials Characterization等。lzn015@mail.lzjtu.cn   
引用本文:    
李正宁, 喇培清, 孟倩, 王鸿鼎, 王文科, 康纪龙, 蒲永亮. 自蔓延高温合成先进材料的研究新进展[J]. 材料导报, 2023, 37(19): 22030161-8.
LI Zhengning, LA Peiqing, MENG Qian, WANG Hongding, WANG Wenke, KANG Jilong, PU Yongliang. New Progress in Self-propagating High Temperature Synthesis of Advanced Materials. Materials Reports, 2023, 37(19): 22030161-8.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22030161  或          http://www.mater-rep.com/CN/Y2023/V37/I19/22030161
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