Research Progress on Preparation of Fe-Al Intermetallic Compounds and Coatings
WANG You1, DENG Nan1, TONG Zhenfeng2, ZHOU Zhangjian1
1 School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China 2 School of Nuclear Science and Engineering, North China Electric Powder University, Beijing 102206, China
Abstract: Fe-Al intermetallic compounds have been widely focused due to their high creep resistance, good wear resistance, and high-temperature anti-oxidation and vulcanization resistance. However, these compounds contain three grain structures, B2, DO3 and A2, which are difficult to control them accurately. Also, high brittleness at room temperature of DO3 brings difficulties in preparation and processing. These shortcomings greatly limit the application of Fe-Al intermetallic compounds. This paper summarized several common preparation methods of Fe-Al intermetallic compound block materials including traditional casting me-thod and powder metallurgy method. As well as the additive manufacturing technology, some coatings' preparation methods, for example, cold spraying, hot spray and some other methods, which have been developed in recent years, were introduced as important points. At the same time, referring to the key question of reaction control between Fe and Al in coatings, this paper focused on how to predict the sequence of the synthesis reaction of Fe-Al intermetallic compounds, which were generated in the original position of the interface reaction of Fe-Al coatings and proposed two prediction methods—phase diagram method and enthalpy change calculation method. Among them, the phase diagram can only represents the phase distribution in the heat balance state, and each phase region barely represents final products that are obtained under specific temperature and composition, thus the dynamic process of the occurrence of Fe-Al intermetallic compounds cannot be judged. Therefore, this paper calculated the enthalpy change value from the perspective of thermodynamics, combined with Kirchhoff formula, calculated, and plotted the enthalpy-temperature curve of common Fe-Al intermetallic compounds, and analyzed the reaction sequence of Fe-Al intermetallic compounds. The theoretical and experimental results of the enthalpy calculation method were highly compatible, thus could modify the phase diagram method, which is of great significance for the preparation of specific Fe-Al intermetallic compounds.
作者简介: 王优,2019年6月毕业于北京科技大学,获得工学学士学位。现为北京科技大学材料与工程学院无机非金属系硕士研究生,在周张健教授的指导下进行研究。目前主要研究领域为Fe-Al涂层制备及界面反应。 周张健,北京科技大学材料科学与工程学院教授、博士研究生导师。2007年7月在北京科技大学取得博士学位,2009年在德国于利希研究中心进行博士后研究工作。主要科研项目有科技部ITER计划课题“聚变堆用ODS钢的批量制备技术及关键服役性能研究”,国际原子能机构(IAEA)国际合作计划(CRP)等。在相关领域发表论文100余篇,包括Journal of Alloy and Compounds、Materials Science and Engineering、Journal of Nuclear Materials、Corrosion Science等。
引用本文:
王优, 邓楠, 佟振峰, 周张健. 铁铝金属间化合物及其涂层制备的研究进展[J]. 材料导报, 2021, 35(21): 21221-21227.
WANG You, DENG Nan, TONG Zhenfeng, ZHOU Zhangjian. Research Progress on Preparation of Fe-Al Intermetallic Compounds and Coatings. Materials Reports, 2021, 35(21): 21221-21227.
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2021, Vol. 35 
