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《材料导报》期刊社  2017, Vol. 31 Issue (6): 61-65    https://doi.org/10.11896/j.issn.1005-023X.2017.06.013
  材料研究 |
镁含量和硅对铁-锌铝镁合金固-液扩散偶中Fe-Al反应层的影响
马坤1, 2, 刘亚1, 2, 涂浩1, 2, 苏旭平1, 2, 王建华1, 2
1 常州大学江苏省材料表面科学与技术重点实验室, 常州 213164;
2 常州大学江苏省光伏科学
与工程协同创新中心, 常州 213164
Effect of Mg Content and Si on Fe-Al Reaction Layer in Solid-Liquid
Diffusion Couples of Fe/Zn-Al-Mg Alloys
MA Kun1,2, LIU Ya1,2, TU Hao1,2, SU Xuping1,2, WANG Jianhua1,2
1 Jiangsu Key Laboratory of Materials Surface Science and Technology, Changzhou University, Changzhou 213164;

2 Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering,
Changzhou University, Changzhou 213164
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摘要 在热浸镀锌中,铁基表面Fe-Al化合物层的形成会影响镀层的生长和质量。将Fe/(Zn-11%Al-3%Mg)和Fe/(Zn-11%Al-x%Mg-0.2%Si)扩散偶在600 ℃下进行25 min的固-液扩散实验,利用扫描电子显微镜(SEM)和能谱仪(EDS)研究了镁含量和硅对铁-锌铝镁合金固-液界面Fe-Al合金层形成的影响。结果表明,Fe/(Zn-11%Al-3%Mg)固-液扩散偶反应层由FeAl3和Fe2Al5相层组成;随着Mg含量的增加,Fe/(Zn-11%Al-x%Mg-0.2%Si)扩散偶中反应层的厚度呈现先增加后减少再增加的变化趋势,当镁含量为3%时反应层厚度最薄;Fe/(Zn-11%Al-3%Mg)扩散偶中Fe-Al反应层的平均厚度比Fe/(Zn-11%Al-3%Mg-0.2%Si)扩散偶中反应层的厚度大60 μm,证明Si元素起到抑制Fe-Al反应层形成的作用。研究结果为解释Super Dyma合金镀层中不形成明显的Fe-Al抑制层提供了实验依据。
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马坤
刘亚
涂浩
苏旭平
王建华
关键词:  热浸镀锌  固-液扩散偶  界面反应  Fe-Al反应层    
Abstract: In hot dip galvanization, the formation of Fe-Al compound layer on steel surface affects the growth and quality of coatings. Fe/(Zn-11%Al-3%Mg) and Fe/(Zn-11%Al-x%Mg-0.2%Si) solid-liquid diffusion couples were annealed at 600 ℃ for 25 min. Scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS) were adopted to study the effect of Mg content and Si on the formation of Fe-Al reaction layer. The results showed that the reaction layer in Fe/(Zn-11%Al-3%Mg) solid-liquid diffusion couple was composed of FeAl3 and Fe2Al5 phase. With the increase of Mg content, the thickness of the reaction layer in Fe/(Zn-11%Al-x%Mg-0.2%Si) diffusion couple increased firstly, then decreased and increased finally. The thickness of reaction layer was the thinnest when magnesium content was 3%. The average thickness of Fe-Al reaction layer in Fe/(Zn-11%Al-3%Mg) diffusion couple was obviously larger than that in Fe/(Zn-11%Al-3%Mg-0.2%Si) diffusion couple, which proved that Si played a role in inhibiting the formation of Fe-Al reaction layer. The results could be used for explaining the reason that there was no obvious Fe-Al inhibition layer forming in the coating of Super Dyma alloy.
Key words:  galvanization    solid-liquid diffusion couple    interface reaction    Fe-Al reaction layer
               出版日期:  2017-03-25      发布日期:  2018-05-02
ZTFLH:  TG111.6  
  TG113.1  
基金资助: 国家自然科学基金(51271041)
通讯作者:  王建华:男,1964年生,教授,研究方向为金属表面改性 Tel:0519-86330233,E-mail:wangjh@cczu.edu.cn   
作者简介:  马坤:男,1992年生,硕士研究生,研究方向为金属表面改性,E-mail:Free_kun@163.com
引用本文:    
马坤, 刘亚, 涂浩, 苏旭平, 王建华. 镁含量和硅对铁-锌铝镁合金固-液扩散偶中Fe-Al反应层的影响[J]. 《材料导报》期刊社, 2017, 31(6): 61-65.
MA Kun, LIU Ya, TU Hao, SU Xuping, WANG Jianhua. Effect of Mg Content and Si on Fe-Al Reaction Layer in Solid-Liquid
Diffusion Couples of Fe/Zn-Al-Mg Alloys. Materials Reports, 2017, 31(6): 61-65.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.06.013  或          http://www.mater-rep.com/CN/Y2017/V31/I6/61
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