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材料导报  2022, Vol. 36 Issue (10): 21010137-7    https://doi.org/10.11896/cldb.21010137
  无机非金属及其复合材料 |
海水及养护方式对硅酸盐水泥性能的影响
王传林1,2,*, 刘泽平1, 张腾腾1, 张宇轩1
1 汕头大学土木与环境工程系,广东 汕头 515063
2 广东省结构安全与监测工程技术研究中心,广东 汕头 515063
Influence of Seawater and Curing Conditions on the Hydration Performance of Portland Cement
WANG Chuanlin1,2,*, LIU Zeping1, ZHANG Tengteng1, ZHANG Yuxuan1
1 Department of Civil and Environmental Engineering, Shantou University, Shantou 515063, Guangdong, China
2 Guangdong Engineering Center for Structure Safety and Health Monitoring, Shantou 515063, Guangdong, China
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摘要 海水含有多种盐类,会对硅酸盐水泥的水化反应产生影响。本工作研究了拌和水、养护水和养护温度对硅酸盐水泥水化及性能的影响。通过试验发现,海水作为拌和水能够促进硅酸盐水泥的早期水化,生成钙矾石和Friedel盐,并提高水泥石密实度,但是在后期会因盐结晶压力等因素破坏硅酸盐水泥基体微观结构,对其强度产生不利影响。而海水作为养护水对硅酸盐水泥会产生腐蚀作用。海水中的盐离子渗透进水泥基体内部与水化产物反应,生成钙矾石和Friedel盐等物质,增大基体体积,降低其力学性能。高温能够促进硅酸盐水泥的溶解-成核-沉淀过程,提高其早期强度。上述三因素对硅酸盐水泥早期强度影响的显著性顺序为拌和水>养护温度>养护水。
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王传林
刘泽平
张腾腾
张宇轩
关键词:  硅酸盐水泥  海水  养护方式  水化性能  力学性能    
Abstract: Seawater contains a variety of salts, which affects the hydration reaction of Portland cement. The effects of mixing water, curing water and curing temperature on the hydration and properties of Portland cement were studied in this work. The results indicate that seawater as mi-xing water can accelerate the early-age hydration of Portland cement by producing ettringite and Friedel's salt as well as improve the compactness of the matrix. However, at the late stage, the salt crystallization pressure leads to the formation of micro-cracks in the Portland cement matrix, which negatively affects the strength. Seawater as curing water can corrode Portland cement. The ions in seawater penetrate into the cement matrix and produce ettringite and Friedel's salt by reacting with the hydration products, which causes the expansion of the cement matrix and even-tually leads to the decrease of mechanical properties. High temperature can accelerate the procedure of dissolution-nucleation-precipitation of Portland cement and improve its early-age strength. The significancy of the influence on the early-stage strength of Portland cement of the above three factors is as follows: mixing water > curing temperature > curing water.
Key words:  Portland cement    seawater    curing method    hydration property    mechanical property
发布日期:  2022-05-24
ZTFLH:  TU528  
基金资助: 汕头大学科研启动经费(NTF17011)
通讯作者:  clwang@stu.edu.cn   
作者简介:  王传林,汕头大学讲师。2016年毕业于英国利兹大学土木工程专业,获得博士学位。在国内外各类期刊发表论文20余篇。主要从事结构加固、超高性能混凝土的研发和应用及海水海砂混凝土研究。
引用本文:    
王传林, 刘泽平, 张腾腾, 张宇轩. 海水及养护方式对硅酸盐水泥性能的影响[J]. 材料导报, 2022, 36(10): 21010137-7.
WANG Chuanlin, LIU Zeping, ZHANG Tengteng, ZHANG Yuxuan. Influence of Seawater and Curing Conditions on the Hydration Performance of Portland Cement. Materials Reports, 2022, 36(10): 21010137-7.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21010137  或          http://www.mater-rep.com/CN/Y2022/V36/I10/21010137
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