Research Progress of the Organosilicone Segmented Copolymer's Preparation and Application
DAI Feiliang1,*, FU Zien1, JIANG Jinbo1, TU Weiping2
1 Guangzhou Baiyun Chemical Industry Co., Ltd., Guangzhou 510080, China 2 School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510630, China
Abstract: Silicone polymer materials, compared with traditional carbon-based polymer materials, show outstanding advantages such as high and low temperature resistance, aging resistance and flexibility, which owe to high bond energy and large bond-angle of their molecular skeleton structure. Silicone polymer materials have been widely used in all walks of life in the national economy; however, low tensile strength and low tear strength restrict its application range to a certain extent. Although the mechanical strength could be improved through adding reinforcing fillers in physical blending, such improvements based on the non-molecular scale are relatively limited. The block copolymerization method can integrate two heterogeneous materials into one, and organosilicone segmented copolymer (OSSC) can be realized by using block chemical reactions to introduce traditional high-strength carbon polymer molecular chains into the organosilicon polymer segments. OSSCs are a hybrid with both silicone polymer segment and organic carbon polymer segment, and have gradually developed into a new type of polymer mate-rial combing the unique characteristics of silicone polymers and the general properties of organic carbon polymer. The synthesis of OSSC is the prerequisite for its deve-lopment and application. This article mainly reviews the synthesis and preparation methods of OSSCs in the last 10 years. Primarily it briefly introduces the preparation of the α,ω-reactive functionally terminated (telechelic) polydimethylsiloxane, and then focuses on the one-step synthesis method of block copolymer (such as ionic polymerization method, ATRP, ROP polymerization method, etc.). The multi-step synthesis methods of forming block copolymers through introducing polyurethane, polyester, polyamide, polyimide, etc. separately into polydimethylsiloxane are described, and the relationship between their physical/chemical properties (or application properties) and their structure is discussed. Finally, the development of OSSCs was prospected.
戴飞亮, 付子恩, 蒋金博, 涂伟萍. 有机硅(碳)嵌段共聚物的合成及其应用研究进展[J]. 材料导报, 2022, 36(9): 20070144-12.
DAI Feiliang, FU Zien, JIANG Jinbo, TU Weiping. Research Progress of the Organosilicone Segmented Copolymer's Preparation and Application. Materials Reports, 2022, 36(9): 20070144-12.
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