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材料导报  2021, Vol. 35 Issue (15): 15143-15152    https://doi.org/10.11896/cldb.20050066
  金属与金属基复合材料 |
金属表面离子印迹材料的研究进展
孔志云1,2, 樊龙伟1,2, 杜亚杰1,2, 牛昌昌3, 狄然1,2, 张环1,2, 魏俊富1,2
1 天津工业大学,分离膜与膜过程省部共建国家重点实验室,天津 300387
2 天津工业大学环境科学与工程学院,天津 300387
3 内蒙古综合交通科学研究院有限责任公司,呼和浩特 010000
Research Progress of Ion Imprinted Materials on Metal Surface
KONG Zhiyun1,2, FAN Longwei1,2, DU Yajie1,2, NIU Changchang3, DI Ran1,2, ZHANG Huan1,2, WEI Junfu1,2
1 State Key Laboratory of Separation Membrane and Membrane Process, Tiangong University, Tianjin 300387, China
2 School of Environmental Science and Engineering, Tiangong University, Tianjin 300387, China
3 Inner Mongolia Comprehensive Transportation Research Institute Co., Ltd., Huhhot 010000, China
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摘要 金属离子印迹聚合物是以金属离子为模板,在静电、络合、配位等作用下与功能单体相互作用,在一定条件下交联聚合后去除模板离子,获得具有许多特定形状和大小的孔穴的聚合物。由于离子印迹聚合物具有与模板离子大小、电荷和空间结构相匹配的稳定空腔,对模板离子有较高的特异识别性和亲和性,在离子分离、富集以及传感识别等领域有着广阔的应用前景。在金属表面离子印迹材料的制备过程中,载体材料的选择不仅在材料稳定性方面起着至关重要的作用,而且对重金属的特异识别性有一定的协同作用。本文对近年来硅基类、碳基类、磁性类、树脂基类、纤维类为载体材料的离子印迹材料进行了简要的综述,为表面离子印迹材料的研究和应用提供参考。
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孔志云
樊龙伟
杜亚杰
牛昌昌
狄然
张环
魏俊富
关键词:  金属离子印迹聚合物  重金属  载体材料    
Abstract: Ion imprinted polymers, which have many cavities with special shapes and sizes, are prepared by copolymerization of functional monomer and cross-linking agent in the presence of template metal ions through coordination, electrostatic or complexation interactions. It was widely used in ion separation, enrichment and sensing identification areas because the ion-imprinted polymers have stable cavities matched the size, charge and spatial structure for template ions, and have high specificity and affinity for template ions. During the process of surface ion-imprinted polymers preparation, the choice of carrier not only played a vital role in the stability of the material, but also had a certain synergistic effect on the specific identification of heavy metal ions. In the paper, ion-imprinted polymers based on silicon-based, carbon-based, magnetic, resin-based, and fiber-based are reviewed in recent years, which would provide a reference for the research and application of surface ion-imprinted polymers.
Key words:  ion imprinted polymer    heavy metal    carrier material
               出版日期:  2021-08-10      发布日期:  2021-08-31
ZTFLH:  X522  
基金资助: 国家自然科学基金项目(51708406);内蒙古自治区科技重大专项(zdzx2018029);天津市科技计划项目(18ZXJMTG00120)
作者简介:  孔志云,天津工业大学讲师,毕业于天津工业大学,并获得材料学博士学位。主要从事环境功能材料在污染物去除中的应用和环境污染物的快速富集及检测等研究。
引用本文:    
孔志云, 樊龙伟, 杜亚杰, 牛昌昌, 狄然, 张环, 魏俊富. 金属表面离子印迹材料的研究进展[J]. 材料导报, 2021, 35(15): 15143-15152.
KONG Zhiyun, FAN Longwei, DU Yajie, NIU Changchang, DI Ran, ZHANG Huan, WEI Junfu. Research Progress of Ion Imprinted Materials on Metal Surface. Materials Reports, 2021, 35(15): 15143-15152.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20050066  或          http://www.mater-rep.com/CN/Y2021/V35/I15/15143
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