Research Progress of the Properties and Mechanism of Heavy Metal Pb2+ Absorbed by Agricultural and Forestry Waste in Wastewater
WANG Luxing1, ZHOU Xintao1, LUO Zhongqiu1,2, MU Weihong1, MA Yue1, SHAO Zhoujun1
1 Faculty of Chemical Engineering,Kunming University of Science and Technology, Kunming 650500, China 2 The Higher Educational Key Laboratory for Phosphorus Chemical Engineering of Yunnan Province, Kunming University of Science and Technology, Kunming 650500, China
Abstract: Excessive Pb2+ in human body can cause some diseases such as anemia, renal failure, endocrine system and central nervous system disorders. Pb2+ pollution may exist in the form of waste water and solid waste. Among them, the Pb2+ containing waste water can not only directly cause the water source pollution, but also contaminate the soil in the related area. So the treatment of Pb2+ containing waste water is urgent. Pb2+ can be removed from water by means of ion exchange, chemical precipitation, electrochemical method, membrane filtration and adsorption method. Adsorption method has been extensively used for the treatment of waste water due to its high efficiency, easy operation and low cost. Commercial activated carbon has better adsorption effect to treat waste water, but the high cost limits its utilization as an adsorbent. Hence, it is a key point to develop an alternative of activated carbon for the technology of wastewater treatment. Agricultural and forestry waste (AFW) has been widely used to remove the Pb2+ in wastewater due to the advantages such as wealth sources, great varieties, low cost, good adsorption effect and renewability. Moreover, the adsorption efficiency of AFW can be improved by means of acid-base salt modification, structure modification, carbonization modification, organic solvent modification and compound modification. Meanwhile the factors such as the initial concentration of Pb2+, amount of adsorbent, pH value, adsorption temperature and time have great influences on the adsorption efficiency of AFW. AFW can efficiently adsorb the Pb2+ in wastewater through ion exchange, coordination action, physical adsorption and chemical precipitation. The adsorption kinetics can be described by pseudo second order, and the thermodynamics can be calculated by Langmuir isotherm model and Freundlich thermodynamic model. This paper reviewes the research progress on the adsorption of Pb2+ in wastewater by AFW. The modification of AFW, the influence factors of Pb2+ adsorption and adsorption mechanism are discuss in this paper. We also discuss the directions of future research on the adsorption of Pb2+ by AFW, thus to provide a reference for the development of stable and renewable AFW adsorbents.
王路星, 周新涛, 罗中秋, 母维宏, 马越, 邵周军. 农林废弃物吸附废水中重金属Pb2+的性能及机理研究进展[J]. 材料导报, 2020, 34(17): 17115-17123.
WANG Luxing, ZHOU Xintao, LUO Zhongqiu, MU Weihong, MA Yue, SHAO Zhoujun. Research Progress of the Properties and Mechanism of Heavy Metal Pb2+ Absorbed by Agricultural and Forestry Waste in Wastewater. Materials Reports, 2020, 34(17): 17115-17123.
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2020, Vol. 34 
