共活化法制备等级多孔炭材料及其储能性能研究

doi:10.11896/cldb.23080193

材料导报

2025, Vol. 39

Issue (3): 23080193-7 https://doi.org/10.11896/cldb.23080193

无机非金属及其复合材料

共活化法制备等级多孔炭材料及其储能性能研究

邹振羽, 刘伟, 李朋娟, 李晓丽^*

东北林业大学化学化工与资源利用学院,哈尔滨 150040

Preparation of Hierarchical Porous Carbon Materials by the Coactivation Method and Their Energy Storage Properties

ZOU Zhenyu, LIU Wei, LI Pengjuan, LI Xiaoli^*

College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040, China

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摘要为了进一步提高生物质活性炭的电化学储能性能,本工作以废弃桉木屑为前驱体,经低共熔溶剂(Deep eutectic solvent,DES)法抽提处理后,再以磷腈衍生物(HCPCP-K)和氢氧化钾(KOH)为共活化剂,制备了等级多孔炭材料(HPC)。其中,HPC-1-4.35材料的比表面积为1 987.43 m²/g,总孔体积为1.313 6 cm³/g,微/介孔比例接近1∶1。电化学测试结果表明,HPC-1-4.35电极材料在电流密度为1 A/g时比电容为555 F/g,在电流密度为20 A/g时比电容达398 F/g,表明其具有出色的倍率性能。由其组装的对称电容器HPC-1-4.35∥HPC-1-4.35在功率密度为179.7 W/kg时能量密度达到30.6 Wh/kg,在电流密度为2 A/g时经过5 000次充放电循环后电容保持率为85%。在-20 ℃、功率密度为63.07 W/kg时,该电容器的能量密度为9.8 Wh/kg,表明其具有较好的低温储能性能,有望拓宽超级电容器的适应温度范围。

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	邹振羽
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关键词: 共活化剂氮磷掺杂等级多孔碳超级电容器

Abstract: In order to further improve the electrochemical energy storage performance of activated biomass carbon, hierarchical porous carbon material (HPC) was obtained by activating the waste wood pre-extracted with DES using different proportions of KOH and cyclotriphosphazene deri-vatives (HCPCP-K) as co-activators. Among the carbon materials obtained, the optimal carbon material HPC-1-4.35 possesses a high surface area and a total pore volume up to 1 987.43 m²/g and 1.313 6 cm³/g, respectively, and the corresponding proportion of microporous and mesoporous was close to 1∶1. Electrochemical tests showed that HPC-1-4.35 electrode displayed excellent specific capacitance of 555 F/g at a current density of 1 A/g and 398 F/g at a current density of 20 A/g, which revealed excellent rate capability. Meanwhile, in the two-electrode system, the assembled symmetric supercapacitors HPC-1-4.35∥HPC-1-4.35 exhibited a higher specific energy density of 30.6 Wh/kg with an excellent power density of 179.7 W/kg at room temperature and a perfect energy density of 9.8 Wh/kg at a power density of 63.07 W/kg at -20 ℃. Furthermore, it showed good cycling stability because the capacitance retention rate was 85% after 5 000 cycles of charging and discharging at a current density of 2 A/g.

Key words: co-activator nitrogen and phosphorus doping hierarchical porous carbon materials supercapacitor

出版日期: 2025-02-10 发布日期: 2025-02-05

ZTFLH:

TQ424.1

基金资助: 黑龙江省自然科学基金联合引导项目(LH2020C040)

通讯作者: *李晓丽,博士,东北林业大学化学化工与资源利用学院副教授、硕士研究生导师。目前主要从事生物质碳材料的制备与性能研究、磷腈衍生物合成与阻燃性能研究。lixiaoli0903@163.com

作者简介: 邹振羽,东北林业大学化学化工与资源利用学院硕士研究生。目前主要从事生物质碳材料电化学储能性能研究。

引用本文:

邹振羽, 刘伟, 李朋娟, 李晓丽. 共活化法制备等级多孔炭材料及其储能性能研究[J]. 材料导报, 2025, 39(3): 23080193-7.
ZOU Zhenyu, LIU Wei, LI Pengjuan, LI Xiaoli. Preparation of Hierarchical Porous Carbon Materials by the Coactivation Method and Their Energy Storage Properties. Materials Reports, 2025, 39(3): 23080193-7.

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http://www.mater-rep.com/CN/10.11896/cldb.23080193 或 http://www.mater-rep.com/CN/Y2025/V39/I3/23080193

1 Baig M M, Khan M A, Gul I H, et al. Journal of Electronic Materials, 2023, 52 (9), 5775.
2 Abdullin K A, Gabdullin M T, Kalkozova Z K, et al. Energies, 2023, 16 (11), 19.
3 Koohi-Fayegh S, Rosen M A. Journal of Energy Storage, 2020, 27, 23.
4 Oyedotun K O, Ighalo J O, Amaku J F, et al. Journal of Electronic Materials, 2023, 52 (1), 96.
5 Kumar Y A, Koyyada G, Ramachandran T, et al. Nanomaterials, 2023, 13 (6), 35.
6 Arumugam B, Mayakrishnan G, Manickavasagam S K S, et al. Crystals, 2023, 13 (7), 28.
7 Duan H J, Liu Y J, Zhao X M. Textile Research Journal, 2023, 93 (15-16), 3884.
8 Liang Y, Huang G, Zhang Q, et al. Journal of Molecular Liquids, 2021, 330, 115580.
9 Shrestha L K, Shrestha R G, Shahi S, et al. Journal of Oleo Science, 2023, 72 (1), 11.
10 Zheng C Q, Gong H, Jiang Y W, et al. ACS Applied Nano Materials, 2023, 6 (15), 14136.
11 Song S J, Ma F W, Wu G, et al. Journal of Materials Chemistry A, 2015, 3 (35), 18154.
12 Feng H B, Hu H, Dong H W, et al. Journal of Power Sources, 2016, 302, 164.
13 Liang Q H, Ye L, Huang Z H, et al. Nanoscale, 2014, 6 (22), 13831.
14 Khalafallah D, Quan X Y, Ouyang C, et al. Renewable Energy, 2021, 170, 60.
15 Lan D W, Chen M Y, Liu Y C, et al. Journal of Materials Science-Materials in Electronics, 2020, 31 (21), 18541.
16 Correa C R, Otto T, Kruse A. Biomass & Bioenergy, 2017, 97, 53.
17 Xu C P, Arancon R A D, Labidi J, et al. Chemical Society Reviews, 2014, 43 (22), 7485.
18 Zhang X F, Ma X F, Hou T, et al. Angewandte Chemie-International Edition, 2019, 58 (22), 7366.
19 Wang Q, Wang Y, Zeng J J, et al. Flatchem, 2022, 34, 8.
20 Song Y, Xing X, Bu Y, et al. Modern Chemical Industry, 2022, 42 (3), 199.
21 Wang Y, Ruan W, Zhou Y. Modern Chemical Industry, 2023, 43 (2), 142.
22 Nazari N, Abadi M D M, Khachatourian A M, et al. Diamond and Related Materials, 2023, 137, 12.
23 Wang J A, Wang M F, Liang Y, et al. Physica B-Condensed Matter, 2023, 648, 6.
24 Bing B C, Li B, Jia H, et al. Chinese Journal of Applied Chemistry, 2009, 26 (7), 753(in Chinese).
邴柏春, 李斌, 贾贺, 等. 应用化学, 2009, 26 (7), 753.
25 Suopajarvi T, Ricci P, Karvonen V, et al. Industrial Crops and Pro-ducts, 2020, 145, 111956.
26 Nouri S, Haghseresht F. Adsorption-Journal of the International Adsorption Society, 2004, 10 (1), 69.
27 Qin C, Wang S R, Wang Z P, et al. Journal of Energy Storage, 2021, 33, 10.
28 Lillo-Rodenas M A, Cazorla-Amoros D, Linares-Solano A. Carbon, 2003, 41 (2), 267.
29 Kamiya A, Togawa T. The Bulletin of Mathematical Biophysics, 1972, 34 (4), 431.
30 Kamiya A, Togawa T, Yamamoto A. Bulletin of Mathematical Biology, 1974, 36 (3), 311.
31 Hulicova D, Kodama M, Hatori H. Chemistry of Materials, 2006, 18 (9), 2318.
32 Liu M X, Gan L H, Xiong W, et al. Energy & Fuels, 2013, 27 (2), 1168.
33 Xu S W, Zhao Y Q, Xu Y X, et al. Journal of Power Sources, 2018, 401, 375.
34 Xue D F, Zhu D Z, Xiong W, et al. ACS Sustainable Chemistry & Engineering, 2019, 7 (7), 7024.
35 Zhang Y, Zhang L, Cheng L, et al. Applied Surface Science, 2021, 538, 8.
36 Chen J, Wei H M, Chen H J, et al. Electrochimica Acta, 2018, 271, 49.
37 Wang T, Zang X B, Wang X M Z, et al. Energy Storage Materials, 2020, 30, 367.
38 Liu H Y, Song H H, Chen X H, et al. Journal of Power Sources, 2015, 285, 303.
39 Qie L, Chen W M, Xu H H, et al. Energy & Environmental Science, 2013, 6 (8), 2497.
40 Qian W J, Sun F X, Xu Y H, et al. Energy & Environmental Science, 2014, 7 (1), 379.
41 Wu M, Xu S, Li X, et al. Journal of Energy Storage, 2021, 40, 8.

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