丝瓜络基3D多级孔结构掺氮活性炭的制备及储能特性

doi:10.11896/cldb.21080011

材料导报

2023, Vol. 37

Issue (5): 21080011-7 https://doi.org/10.11896/cldb.21080011

高分子与聚合物基复合材料

丝瓜络基3D多级孔结构掺氮活性炭的制备及储能特性

白小杰^†, 宋生南^†, 卓祖优, 刘海雄, 陈燕丹^*

福建农林大学材料工程学院,福州 350108

Activated Carbon Derived from Loofah Sponge with Three-dimensional Hierarchical Porous Structure and Its Energy Storage Performance

BAI Xiaojie^†, SONG Shengnan^†, ZHUO Zuyou, LIU Haixiong, CHEN Yandan^*

College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou 350108,China

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摘要丝瓜络具有立体管束状结构,在制备生物质基三维(3D)多孔炭材料方面具有独特优势。以丝瓜络为原料,聚磷酸铵为活化剂、形貌保护剂和氮掺杂源,确立了制备丝瓜络基3D多孔炭材料的优化工艺条件。实验结果表明,经过预炭化处理所制得的样品CAC-1-550,比表面积为738 m²/g,总孔容为0.43 cm³/g,较一步炭化活化法所制样品AC-1-550均有明显提高。电化学测试结果表明,在电流密度为0.5 A/g时,CAC-1-550的比电容可达260 F/g,且经6 000次的循环充放电后,电容保持率为116%,循环稳定性能优良。在功率密度为1 674 W/kg时,最高能量密度为37.2 Wh/kg,优于绝大多数文献中所报道的超级电容器炭电极材料。当功率密度大幅增加到33.5 kW/kg时,能量密度仍达9.3 Wh/kg,CAC-1-550展现出良好的电化学性能,并显示出作为超级电容器的电极材料具有很大的应用潜力。

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关键词: 丝瓜络聚磷酸铵 3D多级孔炭超级电容器电极材料

Abstract: Loofah sponge with three-dimensional bundled micro-structure has unique advantages in the preparation of biomass-based 3D porous carbon materials. Using loofah sponge as raw material and ammonium polyphosphate as activator, morphology protector and nitrogen doping source, the optimal process conditions for the preparation of luffa-based 3D porous carbon materials were established. The results showed that the specific surface area and total pore volume of the CAC-1-550 sample prepared with pre-carbonization treatment were 738 m²/g and 0.43 cm³/g, respectively, which were significantly higher than those of AC-1-550. The electrochemical test results showed that the specific capacitance of CAC-1-550 could reach 260 F/g at 0.5 A/g, and the capacitance retention rate was 116% after 6 000 cycles of charge and discharge. When the power density was 1 674 W/kg, the maximum energy density could reach 37.2 Wh/kg, which was better than that of most carbon electrode materials of supercapacitor widely reported in literatures. When the power density drastically increased to 33.5 kW/kg, the energy density was still up to 9.3 Wh/kg, CAC-1-550 showed appealing electrochemical performance and indicated great potential as an electrode material for supercapacitor applications.

Key words: loofah sponge ammonium polyphosphate 3D hierarchical porous carbon electrode material

出版日期: 2023-03-10 发布日期: 2023-03-14

ZTFLH:

TQ424.1

基金资助: 国家自然科学基金(31870561)

通讯作者: ^*陈燕丹,福建农林大学教授、博士研究生导师。2005年7月毕业于中国科学院福建物质结构研究所物理化学专业,获理学博士学位。2005年8月至今任教于福建农林大学材料工程学院。研究方向为生物质资源高效转化利用。近年来在国内外刊物上发表学术论文30多篇,其中被SCI/EI收录20多篇。作为第一发明人已有5项国家发明获得授权。fjaucyd@163.com

作者简介: †共同第一作者
白小杰,2021年6月毕业于福建农林大学,获得工程硕士学位,研究方向为生物质能源与炭材料。宋生南,2020年6月本科毕业于周口师范学院,现为福建农林大学材料工程学院硕士在读研究生,研究方向为生物质化学与材料工程。

引用本文:

白小杰, 宋生南, 卓祖优, 刘海雄, 陈燕丹. 丝瓜络基3D多级孔结构掺氮活性炭的制备及储能特性[J]. 材料导报, 2023, 37(5): 21080011-7.
BAI Xiaojie, SONG Shengnan, ZHUO Zuyou, LIU Haixiong, CHEN Yandan. Activated Carbon Derived from Loofah Sponge with Three-dimensional Hierarchical Porous Structure and Its Energy Storage Performance. Materials Reports, 2023, 37(5): 21080011-7.

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http://www.mater-rep.com/CN/10.11896/cldb.21080011 或 http://www.mater-rep.com/CN/Y2023/V37/I5/21080011

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