耐热酚醛树脂基活性炭的制备及其超级电容器性能研究

doi:10.11896/cldb.21040224

材料导报

2023, Vol. 37

Issue (4): 21040224-7 https://doi.org/10.11896/cldb.21040224

无机非金属及其复合材料

耐热酚醛树脂基活性炭的制备及其超级电容器性能研究

盛蕊^1,2,†, 唐婷婷^1,2,†, 田敏^1,2, 袁舒慧^1,2, 张苏^1,2,*, 范壮军^3,*

1 新疆大学碳基能源资源化学与利用国家重点实验室,乌鲁木齐 830046
2 新疆大学化学学院,乌鲁木齐 830046
3 中国石油大学(华东)材料科学与工程学院,山东青岛 266580

Research on Heat-resistant Phenolic Resin-based Activated Carbon for Supercapacitor Electrodes

SHENG Rui^1,2,†, TANG Tingting^1,2,†, TIAN Min^1,2, YUAN Shuhui^1,2, ZHANG Su^1,2,*, FAN Zhuangjun^3,*

1 State Key Laboratory of Chemistry and Utilization of Carbon-based Energy Resources, Xinjiang University, Urumqi 830046, China
2 College of Chemistry, Xinjiang University, Urumqi 830046, China
3 School of Materials Science and Engineering, China University of Petroleum, Qingdao 266580, Shangdong, China

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摘要活性炭因其大比表面积和低成本的优势,被广泛应用于超级电容器电极材料中。然而在活性炭的制备过程中,前驱体往往需要进行预炭化/氧化等处理以增强其热稳定性,这将会提高制备成本和工艺复杂性,不利于实际应用需求。为解决这一问题,本工作利用具有高度交联结构的耐热酚醛树脂为前驱体,通过一步活化法制备具有超高比表面及优异导电性的活性炭电极材料。最佳碱炭质量比为3:1时所制备的活性炭比表面积高达2 656 m²·g^-1。在6 mol·L^-1 KOH电解液中测试了活性炭电极的电容储能性能,1 A·g^-1时其比容量高达305.5 F·g^-1,在50 A·g^-1的超大电流密度下电容保持率有63.8%,远高于目前商业活性炭水平。另外,其在高质量负载量下仍具有优异的容量、倍率、循环性能,表现出巨大的应用潜质。

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	盛蕊
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	张苏
	范壮军

关键词: 酚醛树脂活性炭高比表面积高负载超级电容器

Abstract: Activated carbon is widely used for supercapacitor electrode material due to its large specific surface area and low cost. However, precursors often need to be pre-carbonized/oxidized to improve the stability in the preparation of activated carbon. Thus, the high preparation cost and process complexity inhibits the practical application. Herein, we proposed a one-step chemical activation method to prepare activated carbon with high specific surface area and conductivity using a highly cross-linked phenolic resin as the precursor. At the optimized KOH to carbon mass ratio of 3:1, the specific surface area of the activated carbon was as high as 2 656 m²·g^-1. When used as the electrode materials for supercapacitors, it showed a high capacitance of 305.5 F·g^-1 at 1 A·g^-1 and an outstanding rate performance of 63.8% capacitance retention at 50 A·g^-1 in 6 mol·L^-1 KOH electrolyte, which were much higher than the commercial activated carbon. In addition, it still remains good capacitance, rate performance and cycle stability at high electrode mass loadings, showing great potential for practical application.

Key words: phenolic resin activated carbon high specific surface area high mass loading supercapacitor

出版日期: 2023-02-25 发布日期: 2023-03-02

ZTFLH:

O646

基金资助: 国家自然科学基金(52062046;51702275;51972342;51872056);新疆维吾尔自治区自然科学基金(2020D01C019);山东省泰山学者人才计划项目(ts20190922);山东省自然科学基金重大基础研究(ZR2019ZD51)

通讯作者: * 张苏,新疆大学化学学院副教授、硕士生导师。2016年于北京化工大学博士毕业。主要从事低维炭材料的结构设计、合成及其在超级电容器、锂离子电池等电化学储能器件中的应用理论研究。近年来在相关领域国际学术期刊如Adv. Energy Mater.、 Adv. Funct. Mater.、 Nano Energy、 Energy Storage Mater.、 J. Mater. Chem. A、 Carbon等发表学术论文50余篇。suzhangs@163.com
范壮军,中国石油大学(华东)材料科学与工程学院教授、博士生导师。2003年博士毕业于中国科学院山西煤炭化学研究所。研究方向覆盖纳米炭材料的结构调控及批量制备、超级电容器,锂/钠/钾离子电池、固态电池等新型储能体系的基础及应用研究。近年来在相关领域国际学术期刊如Chem. Soc. Rev.、Adv. Mater.、Energy Environ. Sci.、Adv. Energy Mater.、ACS Nano、 Adv. Funct.Mater.、Nano Energy等发表论文270余篇。fanzhj666@163.com

作者简介: 盛蕊,新疆大学化学学院讲师。1995年于新疆大学分析化学专业本科毕业,2000年于新疆大学物理化学专业硕士毕业后于新疆大学工作至今。目前主要从事功能材料研究和无机化学课程教学工作。近年来在相关领域国际学术期刊如J. Mater. Chem. A、 Carbon、Materials Today Energy、ACS Appl. Mater. Interfaces、Scientific Reports等发表学术论文20余篇。
唐婷婷,2019年6月毕业于沈阳化工大学,获得工学学士学位。现为新疆大学化学学院硕士研究生,在张苏副教授的指导下进行研究。目前主要研究方向为炭材料结构设计及其在超级电容器中的性能研究。
†共同第一作者

引用本文:

盛蕊, 唐婷婷, 田敏, 袁舒慧, 张苏, 范壮军. 耐热酚醛树脂基活性炭的制备及其超级电容器性能研究[J]. 材料导报, 2023, 37(4): 21040224-7.
SHENG Rui, TANG Tingting, TIAN Min, YUAN Shuhui, ZHANG Su, FAN Zhuangjun. Research on Heat-resistant Phenolic Resin-based Activated Carbon for Supercapacitor Electrodes. Materials Reports, 2023, 37(4): 21040224-7.

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http://www.mater-rep.com/CN/10.11896/cldb.21040224 或 http://www.mater-rep.com/CN/Y2023/V37/I4/21040224

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