线型酚醛树脂结构改性的研究进展

doi:10.11896/cldb.22050233

材料导报

2023, Vol. 37

Issue (23): 22050233-10 https://doi.org/10.11896/cldb.22050233

高分子与聚合物基复合材料

线型酚醛树脂结构改性的研究进展

陈双¹, 雷子萱², 徐力², 李嘉玄², 陈栋梁¹, 强军锋^1,*, 刘育红^2,*

1 西安科技大学材料科学与工程学院,西安 710054
2 西安交通大学化学工程与技术学院,西安 710049

Research Progress on Structural Modification of Novolac Resin

CHEN Shuang¹, LEI Zixuan², XU Li², LI Jiaxuan², CHEN Dongliang¹, QIANG Junfeng^1,*, LIU Yuhong^2,*

1 College of Materials Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, China
2 School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 6456KB )
输出: BibTeX | EndNote (RIS)

摘要酚醛树脂具有良好的力学性能和耐高温性,被广泛应用于航天、建筑等多个领域,尤其作为高性能碳/碳复合材料或碳/酚醛耐烧蚀材料的基体树脂。传统酚醛树脂固化过程释放挥发分,固化后交联结构存在不足,如紧密堆砌的刚性芳环导致其脆性高,易氧化的酚羟基与亚甲基降低了其耐热性和残炭率。传统酚醛的多层次结构设计和改性是满足酚醛树脂在新型复合材料成型工艺和高性能热防护领域应用的关键,例如在线型酚醛分子结构中引入可加成官能团,如炔丙基、烯丙基等,借助此类基团之间的热聚合实现酚醛树脂的加成固化,还可以对酚醛树脂进行结构设计改性,如羟基醚化、环氧化或引进钼、硼、有机硅等组分,通过化学键接和物理缠结实现对分子结构的调控。这类新型酚醛树脂从本质上避免了固化过程中小分子的逸出,更易于制备出高质量的复合材料。鉴于此,本文着重叙述了几种典型的结构改性线型酚醛树脂及其在烧蚀防护领域的研究和应用进展。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	陈双
	雷子萱
	徐力
	李嘉玄
	陈栋梁
	强军锋
	刘育红

关键词: 酚醛树脂结构改性加成固化耐热复合材料

Abstract: Phenolic resin has excellent mechanical properties and high temperature resistance, and is widely used in aerospace, architecture and other fields as the matrix resin of high-performance carbon/carbon composites or carbon/phenolic ablation resistant materials. The traditional phenolic resin releases volatiles during curing process, and its cross-linking structure after curing is deficient. For example, the tightly stacked rigid aromatic rings cause its high brittleness, the easily oxidized phenolic hydroxyl groups and methylene groups reduce its heat resistance and carbon residue rate. The multi-level structure design and modification of traditional phenolic resin is the key to satisfy its application in the field of new composite molding process and high-performance thermal protection. For example, the introduction of additive functional groups like propargyl groups and allyl groups into the novolac resin can achieve additive curing by thermal polymerization process. Through hydroxyl etherification reaction, epoxidation reaction or the introduction of molybdenum, boron, silicone and other components into the resin matrix, the molecular structure of resin can be regulated through chemical bonding and physical entanglement, then the structural design modification of phenolic resin can be achieved. This type of new phenolic resin essentially avoids the escape of small molecules during the curing process, and is easier to prepare high-quality composites. In summary, this paper focuses on several typical structural modified novolac resins and their research progress in the field of ablation protection.

Key words: phenolic resin structural modification addition curing thermostability composite material

出版日期: 2023-12-10 发布日期: 2023-12-08

ZTFLH:

TQ323.1

基金资助: 陕西省重点研发计划-两链融合(2021GXLH-Z-020);国家自然科学基金-中物院联合基金(U193010027);国家自然科学基金(51873171)

通讯作者: * 强军锋,西安科技大学材料科学与工程学院副教授、硕士研究生导师。2000年西安交通大学专业本科毕业,2004年西安交通大学化学工程专业硕士毕业后到西安科技大学工作至今,2011年西安交通大学电子科学与技术专业博士毕业。目前主要从事导电高分子材料合成及应用、生物工程材料的制备及应用研究工作。发表论文20余篇。qjfcamel@163.com;刘育红,西安交通大学化工学院教授、博士研究生导师。2001年南京理工大学高分子材料科学与工程专业本科毕业,2004年西安交通大学化学工程专业硕士研究生毕业,2008年西安交通大学化学工程专业博士研究生毕业后到西安交通大学大学工作至今。目前主要从事多组分聚合物的微观结构调控,航天热防护复合材料基体树脂,成型工艺及关键技术的研究工作。发表论文40余篇,获得中国授权发明专利10项。liuyuh@xjtu.edu.cn

作者简介: 陈双,2020年6月于西安科技大学获得工学学士学位。现为西安科技大学材料科学与工程学院硕士研究生,在刘育红教授和强军锋副教授指导下进行研究。目前研究领域为高性能酚醛树脂的结构设计与调控——POSS改性酚醛树脂。

引用本文:

陈双, 雷子萱, 徐力, 李嘉玄, 陈栋梁, 强军锋, 刘育红. 线型酚醛树脂结构改性的研究进展[J]. 材料导报, 2023, 37(23): 22050233-10.
CHEN Shuang, LEI Zixuan, XU Li, LI Jiaxuan, CHEN Dongliang, QIANG Junfeng, LIU Yuhong. Research Progress on Structural Modification of Novolac Resin. Materials Reports, 2023, 37(23): 22050233-10.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.22050233 或 http://www.mater-rep.com/CN/Y2023/V37/I23/22050233

1 Hirano K, Asami M. Reactive and Functional Polymers, 2013, 73(2), 256.
2 Liu J, Hou Q F, Hu R F, et al. Pioneering with Science & Technology Monthly, 2016, 29(11), 134 (in Chinese).
刘佳宁, 侯秋飞, 胡若飞, 等. 科技创业月刊, 2016, 29(11), 134.
3 Nair C P R. Progress in Polymer Science, 2004, 29(5), 401.
4 Nair C P R. Polymer Degradation and Stability,2001, 73(2), 251.
5 Lei Z X, Wang J, Zhang C, et al. Composites Science and Technology, 2021, 210, 108810.
6 Lei Z X, Wang J, Zhang C, et al. Composites Part A: Applied Science and Manufacturing, 2022, 152, 106701.
7 Ye Y H, Tian M F, Wang L, et al. China Adhesives, 2014, 23(2), 51 (in Chinese).
叶燕慧, 田谋锋, 王雷, 等.中国胶粘剂, 2014, 23(2), 51.
8 Nechausov S S, Bulgakov B A, Solopchenko A V, et al. Journal of Polymer Research, 2016, 23(6), 1.
9 Luo Z H, Yang M, Zhao T. Acta Materiae Compositae Sinica, 2009, 26(1), 13 (in Chinese).
罗振华, 杨明, 赵彤. 复合材料学报, 2009, 26(1), 13.
10 Li M L, Qi S H, Li C H, et al. Chemistry and Adhesion, 2010, 32(5), 31 (in Chinese).
李美玲, 齐暑华, 李春华,等. 化学与黏合, 2010, 32(5), 31.
11 Liu N L, Li S S, Li M L, et al. China Plastics, 2015, 29(1), 75 (in Chinese).
刘乃亮, 理莎莎, 李美玲,等. 中国塑料, 2015, 29(1), 75.
12 Li M L, Qi S H, Qi H Y, et al.China Adhesives, 2010, 29(1), 55 (in Chinese).
李美玲, 齐署华, 齐海元, 等. 中国胶粘剂, 2010, 29(1), 55.
13 Gong Y L, Deng Z H, Wu Q P, et al. Materials Reports, 2013, 27(11), 83 (in Chinese).
龚艳丽, 邓朝晖, 伍俏平,等. 材料导报, 2013, 27(11), 83.
14 Cao P, Qi S H, Li S S, et al. China Adhesives, 2011, 20(12), 16 (in Chinese).
曹鹏, 齐署华, 理莎莎, 等. 中国胶粘剂, 2011, 20(12), 16.
15 Yan Y Y. Studies on bismaleimide-allylated novolac resin systems. Ph.D.Thesis, Institute of Chemistry Chinese Academy of Sciences, China, 2002.
闫业海. 双马来酰亚胺-烯丙基线型酚醛树脂体系的研究. 博士学位论文, 中国科学院化学研究所, 2002.
16 Ye X C, Zeng L M, Liu T, et al. Journal of Wuhan University of Techno-logy, 2009, 31(20), 4 (in Chinese).
叶晓川, 曾黎明, 刘涛, 等.武汉理工大学学报,2009, 31(20), 4.
17 Zhong Z X, Geng L Y, Zhu J J, et al. Chemistry and Adhesion, 2018, 40(5), 357 (in Chinese).
钟镇祥,耿立艳, 祝晶晶, 等. 化学与粘合, 2018, 40(5), 357.
18 Bindu R L, Nair C P R, Ninan K N. Polymer International, 2001, 50(6), 651.
19 Nair C P R, Bindu R L, Krishnan K, et al.European Polymer Journal, 1999, 35(2), 235.
20 Wang M C, Zhao T.Aerospace Materials & Technology, 2005(1), 30 (in Chinese).
王明存, 赵彤.宇航材料工艺, 2005(1), 30 .
21 Tan D X, Wang Y L, et al.Journal of Functional Materials, 2015, 46(13),13111.
谭德新, 王艳丽, 等. 功能材料, 2015, 46(13), 13111.
22 Chen S F. Synthesis, characterization of propargyl resin and their compo-sites. Ph.D.Thesis, Heifei University of Technology, China, 2013(in Chinese).
陈苏锋. 含炔基树脂的合成、表征及其复合材料的研究.博士学位论文, 合肥工业大学, 2013.
23 Ye L Y, Wan L Q, Ma M M, et al. Acta Materiae Compositae Sinica, 2018, 35(7), 1762 (in Chinese).
叶绿原, 万里强, 马明明, 等.复合材料学报, 2018, 35(7), 1762.
24 Luo Z H, Zhao X Z, Zhao T, et al. Polymer Materials Science & Engineering, 2011, 27(10), 85.
罗振华, 赵绪泽, 赵彤, 等.高分子材料科学与工程, 2011, 27(10), 85 (in Chinese).
25 Li Z H, Peng Q Y, Li J J, et al.Journal of Central South University, 2018, 49(7), 1620 (in Chinese).
李芝华, 彭倩玉, 李珺杰,等. 中南大学学报,2018, 49(7), 1620.
26 Liu F S, Ling H, Zhang H, et al. Polymer Materials Science & Enginee-ring, 2009(10), 84 (in Chinese).
刘富双, 凌鸿, 张华, 等.高分子材料科学与工程, 2009(10), 84.
27 Ishida H, Low H Y. Macromolecules, 1997, 30(4), 1099.
28 Jin L, Agag T, Ishida H. European Polymer Journal, 2010, 46(2), 354.
29 Kiskan B, Yagci Y. Polymer, 2008, 49(10), 2455.
30 Wang Z, Zhao J, Ran Q, et al. Reactive and Functional Polymers, 2013, 73(4), 668.
31 Kimura H, Matsumoto A, Ohtsuka K. Journal of Applied Polymer Science, 2008, 109(2), 1248.
32 Cao G P, Chen W J, Wei J J, et al. Express Polym Letters, 2007, 1, 512.
33 Kawauchi T, Osawa T, Matsumura S, et al. Macromolecular Chemistry and Physics, 2019, 220(1), 1800317.
34 Li Dan, Zhong T J, Xu R W. In: 2016 National Symposium on Polymer Materials Science and Engineering. Guangxi, 2016.
李丹, 钟廷家, 徐日炜. 2016 年全国高分子材料科学与工程研讨会,广西, 2016.
35 Gu Y. In: 2013 National Polymer Academic Paper Conference. Shanghai, 2013.
顾宜. 2013年全国高分子学术论文报告会,上海, 2013.
36 Rimdusit S, Pirstpindvong S, Tanthapanichakoon W, et al. Polymer Engineering & Science, 2005, 45(3), 288.
37 Rao B S, Rajavardhana R K, Pathak S K, et al. Polymer International, 2005, 54(10), 1371.
38 Ishida H, Allen D J.Polymer, 1996, 37(20), 4487.
39 Wu M, Shi H S. Building Energy Efficiency, 2006, 34(2), 15 (in Chinese).
吴敏, 施惠生.房材与应用, 2006, 34(2), 15.
40 Zheng Y A, Yang Y, Li K. Materials Protection, 2005, 38(12), 51 (in Chinese).
郑易安, 杨瑛, 李柯.材料保护, 2005, 38(12), 51.
41 Ma A L, Xiao X Y, Liu B Y, et al.China Adhesives, 2020, 29(1), 37 (in Chinese).
马艾丽, 肖翔云, 刘柏言, 等.中国胶粘剂, 2020, 29(1), 37.
42 Pan G Y, Liu H P, Du Z J, et al. Polymer Materials Science & Enginee-ring, 2008 (10), 41 (in Chinese).
潘国元,刘和平,杜中杰,等.高分子材料科学与工程, 2008 (10), 41.
43 Xia T, Wang Z, Huang Y, et al. New Chemical Materials, 2020, 47(12), 66 (in Chinese).
夏涛, 汪壮, 黄莺, 等.化工新型材料, 2020, 47(12), 66.
44 Zhao Y Y, Zhou Y L, Gou H L, et al.Thermosetting Resin, 2020 (3), 28 (in Chinese).
赵影影,周洋龙,苟浩澜. 热固性树脂,2020, 35(3), 28.
45 Chalamet Y, Taha M. Journal of Polymer Science Part A: Polymer Che-mistry, 1997, 35(17), 3697.
46 Culbertson B M, Tiba O, Deviney M L, et al. Tomorrow's Materials: Today, 1989, 34, 2483.
47 Culbertson B M, Tiba O, Deviney M L. In: 20th International SAMPE Technical Conference Minneapolis. MN, USA, 1988, pp. 590.
48 Janković B. Thermochimica Acta, 2011, 519(1-2), 114.
49 Lu S H, Zhou Z W, Fang L, et al. Journal of Applied Polymer Science, 2007, 103(5), 3150.
50 Sreelal N, Sunitha K, Sreenivas N, et al. Materials Chemistry and Phy-sics, 2023,305, 128005.
51 Su J H, Liu R L. Copper Clad Laminate Information, 2019(4), 9 (in Chinese).
粟俊华, 刘人龙. 覆铜板资讯, 2019(4), 9.
52 Li H F. Study on integrated structure and function of modified cyanate ester resin with high temperature resistance and its adhesive film.Ph.D.Thesis, Northeast Forestry University, China, 2017 (in Chinese).
李洪峰. 结构-功能一体化耐高温氰酸酯树脂改性及胶膜的研究.博士学位论文, 东北林业大学, 2017.
53 Marvel C S, Rassweiler J H. Journal of the American Chemical Society, 1958, 80(5), 1197 .
54 Keller T M, Griffith J R. In: Abstracts of Papers of the American Chemical Society. Washington, 1978, pp. 105.
55 Sreelal N, Balachandran N, Vijayalekshmi K P. Journal of Polymer Research, 2022, 29(9), 1.
56 Yang Y, Zhang M, Lei Y. Aerospace Materials & Technology, 2006(2), 33 (in Chinese).
杨洋, 张敏, 雷毅.宇航材料工艺, 2006(2), 33.
57 Wang G, Ying G, Zheng L, et al. Journal of Applied Polymer Science, 2018, 135(34), 46606.
58 Zhou H, Liu F, Zhao T, et al.Aerospace Materials & Technology, 2010, 40(2), 45 (in Chinese).
周恒,刘锋,赵彤,等.宇航材料工艺, 2010, 40(2), 45.
59 周恒, 郭颖, 赵彤, 等. 中国专利, CN113637227A, 2021.
60 Luo Z H, Zhang B X, Han J W, et al. Aerospace Materials & Technology, 2011, 41(4), 20 (in Chinese).
罗振华, 张勃兴, 韩伟健, 等.宇航材料工艺, 2011, 41(4), 20.
61 Song Y Y. Research high-temperature performance of novel hybrid composites bearing phthalonitrile resins. Master's Thesis, Dalian University of Technology, China, 2018 (in Chinese).
宋媛媛. 邻苯二甲腈树脂基杂化耐高温复合材料的研究.硕士学位论文, 大连理工大学, 2018.
22050233-962 Liu X B, Wei J J, J K, et al.Journal of University of Electronic Science and Technology of China, 2009, 38(5), 603 (in Chinese).
刘孝波, 魏俊基, 贾坤, 等.电子科技大学学报, 2009, 38(5), 603.
63 罗振华, 王传开, 张勃兴, 等. 中国专利, CN106957403A, 2017.
64 赵彤, 李姗, 李昊. 中国专利, CN105968705B. 2017.
65 Liu Y H. High performance studies on hyperbranched polyborates modified phenolic resins. Ph.D.Thesis, Xi'an Jiaotong University, China, 2008 (in Chinese).
刘育红. 超支化硼酸酯改性酚醛树脂的高性能化研究.博士学位论文, 西安交通大学, 2008.
66 Bian C, Wang S, Liu Y, et al. Industrial & Engineering Chemistry Research, 2016, 55(35), 9440.
67 Bian C, Wang S, Liu Y, et al. RSC Advances, 2016, 6(60), 55007.
68 Bian C, Wang Y, Wang S, et al. Polymer Degradation and Stability, 2015, 119, 190.
69 Chen X X, He H, Jia D M, et al. Insulating Materials, 2006, 39(1), 59 (in Chinese).
陈献新, 何慧, 贾德民, 等.绝缘材料, 2006, 39(1), 59.
70 李昊, 李珊, 赵彤,等. 中国专利, CN106496473A. 2017.
71 Zhang W X. Research on preparation and high temperature interface pro-perties of silicone modified phenolic resin and composite thereof. Master's Thesis, Harbin Institute of Technology, China, 2019 (in Chinese).
张文轩. 有机硅改性酚醛树脂的制备及复合材料高温界面性能研究.硕士学位论文, 哈尔滨工业大学, 2019.
72 Yin R, Cheng H, Hong C, et al. Composites Part A: Applied Science and Manufacturing, 2017, 101, 500.
73 Li B, He C, Cao M, et al. Journal of Applied Polymer Science, 2020, 137(6), 48353.
74 Phillips S H, Haddad T S, Tomczak S J. Current Opinion in Solid State and Materials Science, 2004, 8(1), 21.
75 Gupta R, Kandasubramanian B. RSC Advances, 2015, 5(12), 8757.
76 Koo J H, Pilato L A, Wissler G E. Journal of Spacecraft and Rockets, 2007, 44(6), 1250.
77 Lei Z X, Ji J R, Wu Q Q, et al. Polymer, 2019, 178, 121587.
78 Yi T H. Chemical Industry and Engineering Progress, 2001, 20(9), 13 (in Chinese).
伊廷会.化工进展, 2001, 20(9), 13.
79 Zhang S Q, Qiang M, Lin H S, et al. Journal of Wuhan University of Science and Technology, 2003, 26(4), 370 (in Chinese).
张双庆, 强敏, 林慧珊, 等.武汉科技大学学报: 自然科学版, 2003, 26(4), 370.
80 Hua Y Q, Wu Y X, Zhang G F, et al.Polymer Materials Science & Engineering, 1990 (5), 37 (in Chinese).
华幼卿, 吴一弦, 张光复, 等.高分子材料科学与工程, 1990 (5), 37.
81 Liu X H, Gou X H. Chemical World, 1998, 39(6), 314 (in Chinese).
刘晓洪, 苟筱辉.化学世界, 1998, 39(6), 314.
82 Hua Y Q, Rao G Y. Journal of Beijing University of Chemical Technology(Natural Science Edition), 1989(2), 43 (in Chinese).
华幼卿, 饶国英.北京化工学院学报(自然科学版), 1989(2), 43.
83 Li Y L, Yin Y H, Xue Q H, et al. Bulletin of the Chinese Ceramic Society, 2016, 35(2), 665 (in Chinese).
李燕琳, 尹育航, 薛群虎, 等.硅酸盐通报, 2016, 35(2), 665.
84 Zhang M M. Research on polyphosphazene thermal-protective materials and phosphazene-modified phenolic resin. Master's Thesis, Beijing University of Chemical Technology, China, 2018 (in Chinese).
张明明. 聚磷腈热防护材料及磷腈改性酚醛探索研究.硕士学位论文, 北京化工大学, 2018.

[1]	吴伟喆, 刘阳, 张艺欣, 黄建山, 闫国威. 冻融环境下FRCC孔隙结构与力学性能研究综述[J]. 材料导报, 2023, 37(S1): 23010108-12.
[2]	刘海韬, 姜如, 孙逊, 陈晓菲, 马昕, 杨方. 多孔Al₂O_3f/Al₂O₃复合材料研究进展[J]. 材料导报, 2023, 37(9): 22070158-10.
[3]	邵慧龙, 费志方, 李肖华, 赵爽, 李昆锋, 杨自春. 玻璃微珠/PI气凝胶复合材料的制备与吸声性能研究[J]. 材料导报, 2023, 37(9): 21090097-6.
[4]	刘云福, 刘峰, 姚初清, 蒋丹枫, 韩文敏, 戴耀东. 基于泡沫陶瓷三维互穿网络负压浸渍法制备新型耐高温中子屏蔽材料[J]. 材料导报, 2023, 37(8): 21090118-9.
[5]	何承绪, 高洁, 毛航银, 马光, 陈新, 祝志祥, 张一航, 胡卓超. 退火温度对耐热型取向硅钢组织与磁性能的影响[J]. 材料导报, 2023, 37(8): 21090231-5.
[6]	杨赟, 刘璇, 崔益华, 余彤, 武康乐, 潘蕾. 植物纤维增强树脂基复合材料界面纳米化改性的研究进展及应用[J]. 材料导报, 2023, 37(8): 21100069-11.
[7]	张曦挚, 崔红, 胡杨, 邓红兵. 利用等离子喷涂制备C/C复合材料表面耐烧蚀抗氧化涂层的研究进展[J]. 材料导报, 2023, 37(6): 21050162-7.
[8]	陶正凯, 荆肇乾, 王郑. 纳米纤维素材料在重金属废水治理中的应用[J]. 材料导报, 2023, 37(6): 21030120-8.
[9]	盛蕊, 唐婷婷, 田敏, 袁舒慧, 张苏, 范壮军. 耐热酚醛树脂基活性炭的制备及其超级电容器性能研究[J]. 材料导报, 2023, 37(4): 21040224-7.
[10]	杨湘杰, 杨颜, 刘军, 史坤, 郑彬. 半固态等温热处理对Zr基非晶复合材料塑性变形机制的影响[J]. 材料导报, 2023, 37(4): 21080252-7.
[11]	刘洋, 庄蔚敏. 金属-聚合物及金属-复合材料薄壁结构压印连接技术的研究进展[J]. 材料导报, 2023, 37(3): 21110241-12.
[12]	谢发之, 宋恒帅, 张道德, 杨少华, 张梦, 方亮, 邵永刚. 铅炭电池负极添加剂研究进展[J]. 材料导报, 2023, 37(22): 22030203-8.
[13]	潘星辰, 郜红合, 陈旭辉, 朱子兴. 乘用车座椅材料加工工艺与结构设计[J]. 材料导报, 2023, 37(22): 22090290-7.
[14]	满世甲, 杜雪岩, 申永前, 龙建. 镍渣衍生Fe₃O₄/聚苯胺复合材料的制备及微波吸收性能研究[J]. 材料导报, 2023, 37(22): 22030093-6.
[15]	程爱华, 谢倩祎. 基于油菜花粉模板制备Fe基复合材料及其催化特性[J]. 材料导报, 2023, 37(21): 22040339-6.

[1]	Wei ZHOU, Xixi WANG, Yinlong ZHU, Jie DAI, Yanping ZHU, Zongping SHAO. A Complete Review of Cobalt-based Electrocatalysts Applying to Metal-Air Batteries and Intermediate-Low Temperature Solid Oxide Fuel Cells[J]. Materials Reports, 2018, 32(3): 337 -356 .
[2]	Dongyong SI, Guangxu HUANG, Chuanxiang ZHANG, Baolin XING, Zehua CHEN, Liwei CHEN, Haoran ZHANG. Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials[J]. Materials Reports, 2018, 32(3): 368 -372 .
[3]	Yunzi LIU,Wei ZHANG,Zhanyong SONG. Technological Advances in Preparation and Posterior Treatment of Metal Nanoparticles-based Conductive Inks[J]. Materials Reports, 2018, 32(3): 391 -397 .
[4]	Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[5]	Yingke WU,Jianzhong MA,Yan BAO. Advances in Interfacial Interaction Within Polymer Matrix Nanocomposites[J]. Materials Reports, 2018, 32(3): 434 -442 .
[6]	Zhengrong FU,Xiuchang WANG,Qinglin JIN,Jun TAN. A Review of the Preparation Techniques for Porous Amorphous Alloys and Their Composites[J]. Materials Reports, 2018, 32(3): 473 -482 .
[7]	Fangyuan DONG,Shansuo ZHENG,Mingchen SONG,Yixin ZHANG,Jie ZHENG,Qing QIN. Research Progress of High Performance ConcreteⅡ: Durability and Life Prediction Model[J]. Materials Reports, 2018, 32(3): 496 -502 .
[8]	Lixiong GAO,Ruqian DING,Yan YAO,Hui RONG,Hailiang WANG,Lei ZHANG. Microbial-induced Corrosion of Concrete: Mechanism, Influencing Factors,Evaluation Indices, and Proventive Techniques[J]. Materials Reports, 2018, 32(3): 503 -509 .
[9]	Ningning HE,Chenxi HOU,Xiaoyan SHU,Dengsheng MA,Xirui LU. Application of SHS Technique for the High-level Radioactive Waste Disposal[J]. Materials Reports, 2018, 32(3): 510 -514 .
[10]	Haoran CHEN, Yingdong XIA, Yonghua CHEN, Wei HUANG. Low-dimensional Perovskites: a Novel Candidate Light-harvesting Material for Solar Cells that Combines High Efficiency and Stability[J]. Materials Reports, 2018, 32(1): 1 -11 .

Viewed

Full text

Abstract

Cited

Shared

Discussed