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材料导报  2024, Vol. 38 Issue (1): 22050236-5    https://doi.org/10.11896/cldb.22050236
  金属与金属基复合材料 |
太阳能电池用球形银颗粒的液相法制备研究
叶慧, 沈天成, 陈远志, 徐进*
厦门大学材料学院,福建 厦门 361000
A Facile Solution Method for the Preparation of Spherical Silver Particles for the Applications of Solar Cells
YE Hui, SHEN Tiancheng, CHEN Yuanzhi, XU Jin*
College of Materials, Xiamen University, Xiamen 361000, Fujian, China
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摘要 本工作以硝酸银为银前驱体,抗坏血酸为还原剂,结合表面活性剂的作用,制备了平均粒径为 (1.88±0.25) μm 的球形银颗粒,同时,研究了还原体系中表面活性剂对银颗粒形貌及尺寸分布的影响,结果表明,柠檬酸三钠能够促进片状纳米银的形成。片状纳米银在长链表面活性剂(阿拉伯树胶、聚乙烯吡咯烷酮、聚乙二醇 4000 的质量比为 4∶1∶1)存在时能够发生有序的自组装,得到表面相对光滑、粒径分布均匀的高球形度银颗粒。抗坏血酸的还原能力随着 pH 值的增加而逐渐增强。此外,本工作将所得银颗粒与有机载体及玻璃粉混合,通过丝网印刷于硅基底上,850 ℃烧结后,得到电阻率为 3.11 μΩ·cm 的导电厚膜。
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叶慧
沈天成
陈远志
徐进
关键词:  银颗粒  协同作用  晶体生长  导电膜    
Abstract: Spherical silver particles with an average diameter of (1.88±0.25) μm were prepared by a chemical solution approach using silver nitrate as precursor and ascorbic acid as reducing agent in the assistance of several surfactants. The effects of the surfactants on the morphology and size distribution were investigated. The results showed that tri-sodium citrate could promote the formation of silver nanoflakes. When the mass ratio of Arabic gum, polyvinylpyrrolidenone and polyethylene glycol 4000 was 4∶1∶1, the silver nanoflakes could be self-assembled to micron-sized silver particles with smooth surface and uniform particle size distribution. The reducing ability of ascorbic acid increased with increasing pH value. The as-prepared silver particles were mixed with organic carrier and glass powders to form a paste which was then screen-printed on a silicon substrate and sintered at 850 ℃ to form a conductive thick film with a resistivity of 3.11 μΩ·cm.
Key words:  silver particles    synergistic effect    crystal growth    conductive film
发布日期:  2024-01-16
ZTFLH:  O643  
基金资助: 国家自然科学基金(50902116)
通讯作者:  徐进,厦门大学材料学院副教授、硕士研究生导师。1999年南昌大学材料科学与工程学院学士毕业,2004年浙江大学材料与化学工程学院博士毕业,2004年9月到2005 年9月在德国Freiberg工业大学实验物理研究所从事博士后研究工作。主要从事半导体硅材料以及太阳电池相关材料的研究。近年来在材料研究领域发表学术论文50余篇,获得国家专利2项。xujinmse@xmu.edu.cn   
作者简介:  叶慧,2019 年于中国计量大学获得工学学士学位。现为厦门大学材料学院硕士研究生,在徐进副教授和陈远志教授的指导下进行研究。目前主要研究领域是晶体硅太阳能电池导电浆料和锂离子电池硅负极。
引用本文:    
叶慧, 沈天成, 陈远志, 徐进. 太阳能电池用球形银颗粒的液相法制备研究[J]. 材料导报, 2024, 38(1): 22050236-5.
YE Hui, SHEN Tiancheng, CHEN Yuanzhi, XU Jin. A Facile Solution Method for the Preparation of Spherical Silver Particles for the Applications of Solar Cells. Materials Reports, 2024, 38(1): 22050236-5.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22050236  或          http://www.mater-rep.com/CN/Y2024/V38/I1/22050236
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