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材料导报  2023, Vol. 37 Issue (6): 21080088-6    https://doi.org/10.11896/cldb.21080088
  高分子与聚合物基复合材料 |
ZnO@PAN抗腐蚀薄膜的制备、力学性能分析及在铝-空气电池中的应用研究
王嘉乐1, 左雨欣2, 王越锋1, 陈洪立1, 刘宜胜1, 胡雨倞3, 于影3,*, 左春柽3,*
1 浙江理工大学机械与自动控制学院,杭州 310018
2 嘉兴南湖学院时尚设计学院,浙江 嘉兴 314000
3 嘉兴学院信息科学与工程学院,浙江 嘉兴 314000
Study on the Preparation, Mechanical Properties and Application in Aluminum-Air Battery of ZnO@PAN Anti-corrosion Film
WANG Jiale1, ZUO Yuxin2, WANG Yuefeng1, CHEN Hongli1, LIU Yisheng1, HU Yuliang3, YU Ying3,*,
ZUO Chuncheng3,*
1 Faculty of Mechanical Engineering & Automation, Zhejiang Sci-Tech University, Hangzhou 310018, China
2 College of Fashion Design, Jiaxing Nanhu University, Jiaxing 314000, Zhejiang, China
3 College of Information Science and Engineering, Jiaxing University, Jiaxing 314000,Zhejiang, China
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摘要 针对金属空气电池阳极自腐蚀问题,采用静电纺丝方法制备了ZnO@PAN抗腐蚀薄膜。该薄膜能够有效抑制碱性电解质条件下金属空气电池的阳极自腐蚀,腐蚀抑制率高达85.7%。同时,该薄膜兼具良好的力学特性,可适用于柔性能源器件。电化学和力学测试结果表明,ZnO@PAN抗腐蚀薄膜在疲劳拉伸后依然具备良好的腐蚀抑制性。随ZnO@PAN抗腐蚀薄膜中PAN含量的增加,其腐蚀抑制性减弱,但力学拉伸性能增强。将抗腐蚀薄膜应用于柔性金属空气电池时,需综合考虑应用场景,选用合适PAN含量的抗腐蚀薄膜。本实验所制备的ZnO@PAN抗腐蚀薄膜能够为金属电极提供有效保护,且具有优良的力学性能,在柔性可穿戴电子产品领域具有广阔的应用前景。
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王嘉乐
左雨欣
王越锋
陈洪立
刘宜胜
胡雨倞
于影
左春柽
关键词:  ZnO@PAN抗腐蚀薄膜  力学性能  柔性金属空气电池  静电纺丝    
Abstract: Aiming at the self-corrosion problem of the metal-air battery anode, the ZnO@PAN anti-corrosion film was prepared by electrospinning. The film can effectively inhibit the anode self-corrosion of metal-air batteries with alkaline electrolyte, and the corrosion inhibition rate is as high as 85.7%. At the same time, the film has good mechanical properties and could be applied to flexible energy devices. The electrochemical and mechanical tests show that the ZnO@PAN anti-corrosion film still has excellent corrosion inhibition after fatigue bending. With the increase of PAN content in the ZnO@PAN anti-corrosion film,the corrosion inhibition was weakened, but its mechanical tensile properties were enhanced. In order to apply the anti-corrosion film to the flexible metal-air battery, it is necessary to consider the application scenarios and select the anti-corrosion film with the appropriate proportion of PAN content comprehensively. The ZnO@PAN anti-corrosion film prepared in this experiment can provide effective protection for metal electrodes, and has excellent mechanical properties, which has broad application prospects in the field of flexible wearable electronic products.
Key words:  ZnO@PAN anti-corrosion film    mechanical property    flexible metal-air battery    electrospinning
发布日期:  2023-03-27
ZTFLH:  TG178  
基金资助: 国家自然科学基金(11802102;51775242);浙江省自然科学基金(LGG21E050021;LQ20E040007);嘉兴市应用性基础研究专项(2019AY11019;2020AY10015)
通讯作者:  *于影,嘉兴学院信息科学与工程学院副教授、硕士研究生导师。2011年6月获得吉林大学工学学士学位,2016年6月获得工学博士学位(硕博连读)。目前主要从事电流体动力学、增材制造、可穿戴电子器件的研究工作。以第一或通信作者发表SCI论文10余篇,出版个人专著1部。主持国家自然科学基金项目1项。yingyu@zjxu.edu.cn;zuocc@mail.zjxu.edu.cn   
作者简介:  王嘉乐,2019年6月毕业于浙江理工大学机械与自动控制学院,获得工学学士学位。现为浙江理工大学机械与自动控制学院与嘉兴学院信息科学与工程学院联合培养硕士研究生,在左春柽教授和于影副教授的指导下进行研究。目前主要研究领域为复合材料薄膜的制备。
引用本文:    
王嘉乐, 左雨欣, 王越锋, 陈洪立, 刘宜胜, 胡雨倞, 于影, 左春柽. ZnO@PAN抗腐蚀薄膜的制备、力学性能分析及在铝-空气电池中的应用研究[J]. 材料导报, 2023, 37(6): 21080088-6.
WANG Jiale, ZUO Yuxin, WANG Yuefeng, CHEN Hongli, LIU Yisheng, HU Yuliang, YU Ying,
ZUO Chuncheng. Study on the Preparation, Mechanical Properties and Application in Aluminum-Air Battery of ZnO@PAN Anti-corrosion Film. Materials Reports, 2023, 37(6): 21080088-6.
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http://www.mater-rep.com/CN/10.11896/cldb.21080088  或          http://www.mater-rep.com/CN/Y2023/V37/I6/21080088
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