Study on the Preparation, Mechanical Properties and Application in Aluminum-Air Battery of ZnO@PAN Anti-corrosion Film
WANG Jiale1, ZUO Yuxin2, WANG Yuefeng1, CHEN Hongli1, LIU Yisheng1, HU Yuliang3, YU Ying3,*, ZUO Chuncheng3,*
1 Faculty of Mechanical Engineering & Automation, Zhejiang Sci-Tech University, Hangzhou 310018, China 2 College of Fashion Design, Jiaxing Nanhu University, Jiaxing 314000, Zhejiang, China 3 College of Information Science and Engineering, Jiaxing University, Jiaxing 314000,Zhejiang, China
Abstract: Aiming at the self-corrosion problem of the metal-air battery anode, the ZnO@PAN anti-corrosion film was prepared by electrospinning. The film can effectively inhibit the anode self-corrosion of metal-air batteries with alkaline electrolyte, and the corrosion inhibition rate is as high as 85.7%. At the same time, the film has good mechanical properties and could be applied to flexible energy devices. The electrochemical and mechanical tests show that the ZnO@PAN anti-corrosion film still has excellent corrosion inhibition after fatigue bending. With the increase of PAN content in the ZnO@PAN anti-corrosion film,the corrosion inhibition was weakened, but its mechanical tensile properties were enhanced. In order to apply the anti-corrosion film to the flexible metal-air battery, it is necessary to consider the application scenarios and select the anti-corrosion film with the appropriate proportion of PAN content comprehensively. The ZnO@PAN anti-corrosion film prepared in this experiment can provide effective protection for metal electrodes, and has excellent mechanical properties, which has broad application prospects in the field of flexible wearable electronic products.
王嘉乐, 左雨欣, 王越锋, 陈洪立, 刘宜胜, 胡雨倞, 于影, 左春柽. ZnO@PAN抗腐蚀薄膜的制备、力学性能分析及在铝-空气电池中的应用研究[J]. 材料导报, 2023, 37(6): 21080088-6.
WANG Jiale, ZUO Yuxin, WANG Yuefeng, CHEN Hongli, LIU Yisheng, HU Yuliang, YU Ying, ZUO Chuncheng. Study on the Preparation, Mechanical Properties and Application in Aluminum-Air Battery of ZnO@PAN Anti-corrosion Film. Materials Reports, 2023, 37(6): 21080088-6.
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