Photocatalytic Degradation of Volatile Organic Pollutants: Advances in Catalysts
WANG Zisha1, LIU Jun2,3,*, LIU Xiaoqing1,2,*
1 School of Environmental and Safety Engineering, North University of China, Taiyuan 030051, China 2 School of Environmental, Tsinghua University, Beijing 100084, China 3 School of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024,China
Abstract: The increasing concentration of volatile organic pollutants (VOCs) in the atmosphere caused mainly by industrial activities and their threat to human development have attracted wide attention. In many methods to eliminate VOCs, photocatalytic technology is regarded as a robust method to solve environmental pollution owing to its green, safe, efficient and utilization of sunlight. However, catalyst possesses a series of limitations, such as the inborn deficiency in visible light absorption, poor conductivity, high overpotential and fast recombination of electrons and holes, which greatly limits their further applications. Therefore, various strategies have been proposed to improve the photocatalytic activity and selectivity, such as the doping of metal and nonmetal, dye sensitization, adjusting the crystal faces, the formation of heterojunctions with other semiconductors and so on. This article summarizes the classification of photocatalysts reported in the literature, starting from precious metal catalysts, non-precious metal catalysts, non-metal catalysts and metal organic framework (MOFs) catalysts, and discusses the research progress of different types of catalysts at home and abroad to remove VOCs. The research progress of different kinds of photocatalysts lays the foundation for the development of high-efficiency photocatalysts.
通讯作者:
*刘俊,太原理工大学化学化工学院讲师。2010年7月毕业于忻州师范学院,取得学士学位。2017年7月毕业于太原理工大学化学化工学院,取得博士学位(硕博连读)。清华大学博士后。主要研究方向为煤的清洁高效利用技术、烟气脱硫脱硝催化剂的开发与应用和VOCs的催化氧化技术。在Applied Surface Science和Fuel Processing Technology等国际著名期刊中发表SCI论文10余篇。 刘晓庆,中北大学环境与安全工程学院副教授、硕士研究生导师。2010年7月毕业于忻州师范学院,取得学士学位。2015年7月毕业于内蒙古大学化学化工学院,取得博士学位(硕博连读)。2019年进入清华大学环境学院进行博士后研究工作。主要从事光解水制氢、光催化去除环境中污染物、理论计算、固定源烟气脱硫脱硝的研究工作。主持国家自然科学基金1项。发表SCI收录论文10余篇,包括Journal of Hazardous Materials和Journal of Alloys and Compounds等。申请发明专利2项。
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