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材料导报  2023, Vol. 37 Issue (2): 20100198-14    https://doi.org/10.11896/cldb.20100198
  无机非金属及其复合材料 |
挥发性有机污染物光催化降解催化剂的研究进展
王紫莎1, 刘俊2,3,*, 刘晓庆1,2,*
1 中北大学环境与安全工程学院,太原 030051
2 清华大学环境学院,北京 100084
3 太原理工大学化学化工学院,太原 030024
Photocatalytic Degradation of Volatile Organic Pollutants: Advances in Catalysts
WANG Zisha1, LIU Jun2,3,*, LIU Xiaoqing1,2,*
1 School of Environmental and Safety Engineering, North University of China, Taiyuan 030051, China
2 School of Environmental, Tsinghua University, Beijing 100084, China
3 School of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024,China
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摘要 随着工业的发展,挥发性有机污染物(VOCs)的治理迫在眉睫。在众多消除VOCs的方法中,光催化技术一直备受关注,它能够将VOCs催化氧化生成二氧化碳(CO2)和水(H2O)等无污染产物,不会产生二次污染。但光催化剂存在电导率低、过电位高、光诱导电荷高复合以及带隙不匹配等缺点,从而抑制了光催化性能的提升,进而限制了其实际应用。因此,提高光催化剂的催化活性和选择性,并且清楚了解光催化机理至关重要。目前文献报道中光催化剂催化性能提升的方法包括掺杂、染料敏化、贵金属负载、半导体复合等,不同的方法实现了能带结构调控、缺陷调控、形貌调控等,旨在增强半导体中光生载流子的流动能力以及增加可见光吸收,进而提升光催化性能。本文将文献报道的光催化剂分类,从贵金属催化剂、非贵金属催化剂、非金属催化剂以及金属有机框架(MOFs)催化剂出发进行综述,分别论述了国内外不同种类催化剂去除VOCs的研究进展。不同种类光催化剂的研究进展为开发高效光催化剂奠定了基础。
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王紫莎
刘俊
刘晓庆
关键词:  光催化  挥发性有机污染物(VOCs)  金属催化剂  非金属催化剂  金属有机框架(MOFs)    
Abstract: The increasing concentration of volatile organic pollutants (VOCs) in the atmosphere caused mainly by industrial activities and their threat to human development have attracted wide attention. In many methods to eliminate VOCs, photocatalytic technology is regarded as a robust method to solve environmental pollution owing to its green, safe, efficient and utilization of sunlight. However, catalyst possesses a series of limitations, such as the inborn deficiency in visible light absorption, poor conductivity, high overpotential and fast recombination of electrons and holes, which greatly limits their further applications. Therefore, various strategies have been proposed to improve the photocatalytic activity and selectivity, such as the doping of metal and nonmetal, dye sensitization, adjusting the crystal faces, the formation of heterojunctions with other semiconductors and so on. This article summarizes the classification of photocatalysts reported in the literature, starting from precious metal catalysts, non-precious metal catalysts, non-metal catalysts and metal organic framework (MOFs) catalysts, and discusses the research progress of different types of catalysts at home and abroad to remove VOCs. The research progress of different kinds of photocatalysts lays the foundation for the development of high-efficiency photocatalysts.
Key words:  photocatalysis    volatile organic compounds    metal catalyst    non-metal catalyst    metal-organic frameworks
发布日期:  2023-02-08
ZTFLH:  X511  
通讯作者:  *刘俊,太原理工大学化学化工学院讲师。2010年7月毕业于忻州师范学院,取得学士学位。2017年7月毕业于太原理工大学化学化工学院,取得博士学位(硕博连读)。清华大学博士后。主要研究方向为煤的清洁高效利用技术、烟气脱硫脱硝催化剂的开发与应用和VOCs的催化氧化技术。在Applied Surface Science和Fuel Processing Technology等国际著名期刊中发表SCI论文10余篇。
刘晓庆,中北大学环境与安全工程学院副教授、硕士研究生导师。2010年7月毕业于忻州师范学院,取得学士学位。2015年7月毕业于内蒙古大学化学化工学院,取得博士学位(硕博连读)。2019年进入清华大学环境学院进行博士后研究工作。主要从事光解水制氢、光催化去除环境中污染物、理论计算、固定源烟气脱硫脱硝的研究工作。主持国家自然科学基金1项。发表SCI收录论文10余篇,包括Journal of Hazardous Materials和Journal of Alloys and Compounds等。申请发明专利2项。   
作者简介:  王紫莎,2018年6月毕业于哈尔滨师范大学,获得理学学士学位。现为中北大学环境与安全工程学院硕士研究生,在刘晓庆副教授的指导下进行研究。目前主要研究领域为光催化去除VOCs和光催化CO2还原。
引用本文:    
王紫莎, 刘俊, 刘晓庆. 挥发性有机污染物光催化降解催化剂的研究进展[J]. 材料导报, 2023, 37(2): 20100198-14.
WANG Zisha, LIU Jun, LIU Xiaoqing. Photocatalytic Degradation of Volatile Organic Pollutants: Advances in Catalysts. Materials Reports, 2023, 37(2): 20100198-14.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.20100198  或          http://www.mater-rep.com/CN/Y2023/V37/I2/20100198
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