多糖/金属有机框架(MOFs)复合气凝胶的制备及应用进展

doi:10.11896/cldb.20080197

材料导报

2022, Vol. 36

Issue (4): 20080197-10 https://doi.org/10.11896/cldb.20080197

高分子与聚合物基复合材料

多糖/金属有机框架(MOFs)复合气凝胶的制备及应用进展

王杨鑫^*, 邓强, 李成贵, 温永宇

南京工业大学材料科学与工程学院,南京 211816

Research Progress on Preparation and Application of Polysaccharides-Metal Organic Frameworks Hybrid Aerogels

WANG Yangxin^*, DENG Qiang, LI Chenggui, WEN Yongyu

College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China

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摘要气凝胶材料是一类具有三维纳米结构的多孔材料,在航空航天、石油化工、环保工程、建筑工程、化学催化、医药卫生等领域表现出广泛的应用价值,自问世以来一直深受人们的关注。由纤维素、壳聚糖、海藻酸等多糖制备得到的气凝胶材料不仅能够保持传统气凝胶高孔隙率、大比表面积、低密度的特点,还具备了天然高分子可再生、可降解、生物兼容性好的优点,成为了当前的热门材料之一。金属有机框架(MOFs)是一类由金属节点以及有机配体通过配位作用组装形成的多孔框架材料,在吸附、催化、传感、载药等领域都表现出巨大的应用潜力。随着对材料应用功能、加工性能、循环使用性能等要求的提升,近年来人们对多糖/MOFs复合气凝胶材料的研究兴趣逐渐高涨。自2016年第一例纤维素纳米晶/MOFs复合气凝胶材料被报道以来,研究人员尝试了多种不同的多糖以及MOFs组合,制备了不同类型的多糖/MOFs复合气凝胶材料,并探索了它们在不同领域的应用。
本文首先总结了多糖/MOFs复合气凝胶材料的三种常见制备策略:(1)将预先制备好的MOFs与多糖直接混合制备复合气凝胶;(2)在多糖分子表面原位生成MOFs之后再制备复合气凝胶;(3)在已制备好的多糖气凝胶中原位生成MOFs再制备复合气凝胶。通过相应的实例详细介绍了这些制备方法的特点,然后分别介绍了多糖/MOFs复合气凝胶材料在不同领域中的应用情况,最后针对当前该领域研究存在的不足以及面临的问题提出了解决方法并展望了未来可能的发展方向。

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	王杨鑫
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关键词: 多糖金属有机框架(MOFs) 气凝胶多孔材料复合材料

Abstract: Aerogel, a type of three-dimensional nano-structured porous material, has attracted extensive attention since it was developed, which has comprehensive applications in fields of aeronautics and astronautics, petrochemical engineering, environmental protection, architectural engineering, chemical catalysis, and medical and health. Aerogels made from polysaccharides, including cellulose, chitosan, alginate, etc., have been recognized as a type of emerging materials, because they not only show high porosity, high specific surface area, and extremely low density similar to the conventional aerogels, but also feature with renewability, biodegradability and excellent biocompatibility. Metal organic frameworks (MOFs), which are constructed through coordination between metal ions and organic linkers, have shown great application potential in fields of adsorption, catalysis, sensing, drug delivery and so on. Along with the increasing requirement for capability, processability and reusability of materials, growing attention has been paid to polysaccharide/MOFs hybrid aerogels. Since the first report about cellulose-nanocrystals/MOFs hybrid aerogel was published in 2016, different polysaccharides and MOFs have been composited for constructing polysaccharide/MOFs aerogels, and their applications in variou fields have been explored.
In this review, three commonly used strategies for preparing polysaccharide-MOFs hybrid aerogels are summarized: (1) direct mixing of pre-prepared MOFs with polysaccharides to make hybrid aerogels; (2) MOFs formed on the surface of polysaccharides before self-assembly and drying to form hybrid aerogels; (3) MOFs formed on the surface of pre-formed polysaccharide aerogels to make hybrid aerogels. The characteristics of these different strategies are introduced and compared in combination with corresponding recent examples. Afterwards, the applications of these hybrid aerogels in different fields are also reviewed. In the end, the possible challenges and the outlook regarding polysaccharide/MOFs hybrid aerogels are illustrated.

Key words: polysaccharide metal organic frameworks (MOFs) aerogel porous material composite material

出版日期: 2022-02-25 发布日期: 2022-02-28

ZTFLH:

O636

基金资助: 南京工业大学引进人才科研启动专项经费(39803155)

通讯作者: yangxin.wang@njtech.edu.cn

作者简介: 王杨鑫,南京工业大学材料科学与工程学院副教授。2011年6月毕业于南京大学化学化工学院,获理学学士学位;2016年7月在中国科学院福建物质结构研究所获博士学位;2016年9月至2019年12月于西北工业大学生命学院从事博士后研究工作,期间以访问学者身份分别于德国德累斯顿工业大学(2016年10月至2018年6月)以及卡尔斯鲁厄理工学院(2018年11月至2019年11月)进行科研工作;2020年4月入职南京工业大学材料科学与工程学院。主要研究方向为多孔有机框架材料、生物大分子基复合材料、智能响应性高分子材料,迄今发表SCI论文20余篇。

引用本文:

王杨鑫, 邓强, 李成贵, 温永宇. 多糖/金属有机框架(MOFs)复合气凝胶的制备及应用进展[J]. 材料导报, 2022, 36(4): 20080197-10.
WANG Yangxin, DENG Qiang, LI Chenggui, WEN Yongyu. Research Progress on Preparation and Application of Polysaccharides-Metal Organic Frameworks Hybrid Aerogels. Materials Reports, 2022, 36(4): 20080197-10.

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http://www.mater-rep.com/CN/10.11896/cldb.20080197 或 http://www.mater-rep.com/CN/Y2022/V36/I4/20080197

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