双原子催化剂在电催化领域的应用研究进展

材料导报

2021, Vol. 35

Issue (Z1): 481-484

金属与金属基复合材料

双原子催化剂在电催化领域的应用研究进展

齐美丽^1,2, 李勉拓¹, 张梦娟¹, 吴艳玲¹

1 山东交通学院交通土建工程学院,济南 250357
2 山东百多安医疗器械股份有限公司,德州 251100

Progress in the Application of Dual-atom Catalysts in Electrocatalytic Field

QI Meili^1,2, LI Miantuo¹, ZHANG Mengjuan¹, WU Yanling¹

1 School of Transportation and Civil Engineering, Shandong Jiaotong University, Ji'nan 250357, China
2 China Shandong Branden Medical Devices Co., Ltd, Dezhou 251100, China

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摘要单原子催化剂具有高选择性、最大的金属利用率、独特的电子结构等优点,成为电催化领域研究的热点。然而,在单原子催化剂的制备过程中,金属原子因具有较高的表面自由能而易发生团聚,造成催化活性位点数量和金属负载量降低,此种情况严重制约了单原子催化剂的进一步发展与应用。为进一步增加单原子活性位点数量和金属负载量,作为单原子催化剂的创新性扩展,双原子催化剂近年来开始走入学者的视野,两种金属原子之间的相互作用赋予了双原子催化剂卓越的催化性能。本文基于当前最新的研究工作,综述了同核/异核双原子催化剂的制备方法和表征及在电催化领域中的应用,并对其在电催化领域中所存在的挑战和未来的发展方向进行了简要展望。

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	齐美丽
	李勉拓
	张梦娟
	吴艳玲

关键词: 单原子催化剂双原子催化剂同核/异核电催化

Abstract: Single-atom catalysts (SACs) have been a hot topic in the field of electrocatalysis because of their advantages of high selectivity, maximum metal utilization and unique electronic structure. However, the metal atoms are often agglomerated during SACs preparation due to their high surface free energy, resulting in a decrease in the number of catalytic active sites and the metal load, which seriously hinders the further development of SACs. In order to solve the problems of small number of single metal active sites and low metal loading capacity, the innovative development of dual-atom catalysts (DACs) as SACs has been studied in depth in recent years. Recently, dual-atom catalysts (DACs) have attracted considerable research interest since they exhibit higher metal atom loading and more flexible active sites compared to SACs. In this work, the application of homonuclear/heteronuclear DACs in electrocatalysis was summarized by introducing the preparation methods and characterization methods of homonuclear/heteronuclear DACs, and the challenges and future development directions in the field of electrocatalysis were briefly prospected.

Key words: single-atom catalysts dual-atom catalysts homonuclear/heteronuclear electric catalytic

发布日期: 2021-07-16

ZTFLH:

TQ172

基金资助: 山东交通学院博士科研启动基金项目(BS50004919;BS50004952);山东交通学院科研基金项目(Z201910;Z201918)

通讯作者: wuyanling621@163.com

作者简介: 齐美丽,山东交通学院讲师,2018年6月毕业于山东大学,获得工学博士学位。2020年1月起在山东大学和山东百多安医疗器械股份有限公司开展博士后研究,主要从事纳米材料领域的研究。在国内外学术期刊上发表论文20余篇,申请国家发明专利3项,其中授权1项,主持山东省自然科学基金青年基金项目、山东交通学院博士科研启动基金项目和山东交通学院科研基金项目等。吴艳玲,山东交通学院交通土建工程学院讲师。2019年在中国石油大学(华东)获得博士学位。目前主要从事能源材料领域的研究,其中包括纳米改性电催化剂和光催化剂,以及有机薄膜晶体管(OFET)。在国内外学术期刊上发表论文10余篇,申请国家发明专利2项,其中授权1项,主持山东交通学院博士科研启动基金项目和山东交通学院科研基金项目等。

引用本文:

齐美丽, 李勉拓, 张梦娟, 吴艳玲. 双原子催化剂在电催化领域的应用研究进展[J]. 材料导报, 2021, 35(Z1): 481-484.
QI Meili, LI Miantuo, ZHANG Mengjuan, WU Yanling. Progress in the Application of Dual-atom Catalysts in Electrocatalytic Field. Materials Reports, 2021, 35(Z1): 481-484.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2021/V35/IZ1/481

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