基于HDTMS的一步法构筑棉织物超疏水表面

材料导报

2020, Vol. 34

Issue (Z1): 542-547

高分子与聚合物基复合材料

基于HDTMS的一步法构筑棉织物超疏水表面

杨雪^1,2, 苏静^1,2, 王鸿博^1,2

1 江苏省功能纺织品工程技术研究中心,无锡 214122;
2 生态纺织教育部重点实验室(江南大学),无锡 214122

Preparation of Superhydrophobic Surface of Cotton Fabric via One StepHDTMS Treatment

YANG Xue^1,2, SU Jing^1,2, WANG Hongbo^1,2

1 Jiangsu Engineering Technology Research Center for Functional Textiles, Wuxi 214122, China;
2 Key Laboratory of Eco-Textiles of Ministry of Education (Jiangnan University), Wuxi 214122, China

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摘要采用一步法对棉织物进行超疏水整理。利用十六烷基三甲氧基硅烷(HDTMS)降低织物表面能,采用纳米二氧化硅粒子(SNP)提高织物表面粗糙结构,并引入乙二胺四乙酸(EDTA)提高超疏水织物的耐久性。通过单因素优化实验和正交优化实验确定三种物质的最优用量,SNP为1.0%(质量分数,下同),EDTA为1.0%,HDTMS为4.0%。改性后的棉织物具有超疏水性和良好的疏油性,对水和油的静态接触角分别为160.5°、155.5°。耐水洗性测试表明低浓度EDTA的加入可提高织物的疏水耐洗性能。

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关键词: 超疏水纳米二氧化硅乙二胺四乙酸十六烷基三甲氧基硅烷棉织物

Abstract: Cotton fabric was finished in a simple one-step process to prepare superhydrophobic cotton fabric. Cetyltrimethoxysilane (HDTMS) was adop-ted to reduce surface energy of cotton fabric due to its long alkane chain, the nano-silica particles (SNP) were used to improve the surface roughness of the fabric. The ethylene diamine tetraacetic acid (EDTA) was applied to improve the treatment durability. The effects of SNP, EDTA and HDTMS concentration on the hydrophobicity of finished cotton fabric were studied. The results showed that the optimized conditions could be obtained when the concentration of SNP, EDTA and HDTMS were 1.0wt%, 1.0wt% and 4.0wt%, separately. The superhydrophobic cotton fabrics exhibited superhydrophobicity with an average water contact angle of 160.5°, and oleophobicity with an average oil contact angle of 155.5°. Furthermore, the durability efficiency of samples was quantitatively evaluated using standard washing test and the result showed the enhancement of EDTA.

Key words: superhydrophobicity silica nanoparticles ethylenediaminetetraacetic acid hexadecyltrimethoxysilane cotton

发布日期: 2020-07-01

ZTFLH:

TB34

基金资助: 国家重点研发计划(2017YFB0309100)

作者简介: 杨雪,自2018年9月于江南大学纺织科学与工程学院攻读纺织工程硕士学位,目前主要研究纺织材料的改性及功能纺织品的制备;王鸿博,教授,博士研究生导师。2007年毕业于江南大学,获得纺织科学与工程博士学位。主要研究功能性纺织材料制备理论与技术、功能纺织品设计、开发纤维制品现代加工技术和新型织造技术。并主持江苏省重大科技成果转化、江苏省科技攻关、省部级重点实验室等项目10项,主要参与国家十三五重大科技专项、国家自然科学基金等。发表学术论文180多篇,其中SCI源期刊论文40余篇,CSCD论文100余篇,授权发明专利15件。

引用本文:

杨雪, 苏静, 王鸿博. 基于HDTMS的一步法构筑棉织物超疏水表面[J]. 材料导报, 2020, 34(Z1): 542-547.
YANG Xue, SU Jing, WANG Hongbo. Preparation of Superhydrophobic Surface of Cotton Fabric via One StepHDTMS Treatment. Materials Reports, 2020, 34(Z1): 542-547.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2020/V34/IZ1/542

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