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材料导报  2019, Vol. 33 Issue (20): 3372-3376    https://doi.org/10.11896/cldb.18080178
  无机非金属及其复合材料 |
Ni3S2微纳米结构超疏水表面的制备及耐蚀性能
尹晓丽, 于思荣, 胡锦辉
中国石油大学(华东)材料科学与工程学院,青岛 266580
Fabrication of Ni3S2 Micro-nanostructure Superhydrophobic Surface with Anti-corrosion Property
YIN Xiaoli, YU Sirong, HU Jinhui
School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580
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摘要 随着表面科学和仿生学的迅速发展,超疏水材料的制备和研究已成为当下研究的热点,其性能优异,具有十分广阔的应用前景。本工作采用水热反应法在泡沫镍基体上直接生长Ni3S2微纳米复合结构,经过十四酸修饰后获得性能优良的超疏水表面。实验探究了水热反应温度和反应时间对水滴在超疏水表面接触角的影响。研究发现,水热反应温度为180 ℃、反应时间为6 h的条件下获得的水热反应层表面的水滴接触角达到最大值160.28°。采用扫描电子显微镜观察超疏水试样表面的微观结构,发现在基体表面生长了一层交错排列的锥状结构。利用X射线衍射仪和能谱仪对水热反应层表面进行物相及表面化学成分分析发现,与泡沫镍基体相比,水热反应层表面除了存在Ni相外还形成了新的Ni3S2相。对获得的超疏水试样进行性能测试,发现利用该方法制备的超疏水材料具有良好的耐酸碱性和耐电化学腐蚀特性。
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尹晓丽
于思荣
胡锦辉
关键词:  超疏水表面  Ni3S2微纳米结构  水热反应  耐酸碱性  电化学腐蚀特性    
Abstract: With the rapid development of surface science and bionics, superhydrophobic materials have become a hot issue in current research, and their excellent properties have a very broad application prospect. In this paper, a Ni3S2 micro-nano composite structure was grew directly on the nickel foam by hydrothermal reaction, then the superhydrophobic surface with excellent properties was obtained after modification by tetradecanoic acid. The effects of reaction temperature and time on the water contact angles were investigated. It was found that the properties of the superhydrophobic surface were optimal while the reaction temperature was 180 ℃ and the reaction time was 6 h so that the static contact angle was up to 160.28°. Scanning electron microscopy was used to observe the microstructure of the superhydrophobic surface, and the interleaved cone arrays were found on the substrates. The chemical compositions of the superhydrophobic surface were analyzed by X-ray diffractometer and energy dispersive spectrometer. It was worth noting that a new Ni3S2 phase was formed compared to the nickel foam. The properties of the superhydrophobic surface were tested, finding that the surface had good acid and alkali resistance and corrosion resistance.
Key words:  superhydrophobic surface    Ni3S2 micro-nanostructure    hydrothermal reaction    acid and alkali resistance    electrochemical corrosion characteristics
               出版日期:  2019-10-25      发布日期:  2019-08-29
ZTFLH:  TB34  
基金资助: 中央高校基本科研业务费专项资金资助(17CX06051)
作者简介:  尹晓丽,中国石油大学(华东)博士研究生,2017年本科毕业于中国石油大学(华东)并获得硕博连读资格。发表论文1篇,实用新型专利2项,主要研究方向为材料复合与界面。于思荣,中国石油大学(华东)教授,博士研究生导师,长期从事金属基复合材料、铸造合金材料、材料摩擦学、表面工程等方面的研究工作,先后完成和承担了国家自然科学基金、省部级及企业产学研科研项目40余项。在国内外著名刊物及学术会议上共发表论文300余篇。获国家发明专利8项、实用新型专利8项。被评为“吉林省有突出贡献的中青年专业人才”、入选教育部“新世纪优秀人才支持计划”、荣获国务院政府特殊津贴。yusr@upc.edu.cn
引用本文:    
尹晓丽, 于思荣, 胡锦辉. Ni3S2微纳米结构超疏水表面的制备及耐蚀性能[J]. 材料导报, 2019, 33(20): 3372-3376.
YIN Xiaoli, YU Sirong, HU Jinhui. Fabrication of Ni3S2 Micro-nanostructure Superhydrophobic Surface with Anti-corrosion Property. Materials Reports, 2019, 33(20): 3372-3376.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.18080178  或          http://www.mater-rep.com/CN/Y2019/V33/I20/3372
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