多孔腔骰子形和六足形氧化亚铜的水热合成

材料导报

2020, Vol. 34

Issue (Z1): 148-152

无机非金属及其复合材料

多孔腔骰子形和六足形氧化亚铜的水热合成

莫若飞

广西中医药大学,南宁 530200

Hydrothermal Synthesis of Dice-like and Hex-pod-like Cuprous Oxide withMulti-cavities

MO Ruofei

Guangxi University of Chinese Medicine, Nanning 530200, China

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摘要本工作通过水热法,采用油酸作包覆剂、乙二胺四乙酸二钠(EDTA)作配位剂、在水-乙醇碱性溶液中用葡萄糖还原醋酸铜制备出多孔腔骰子形和六足形氧化亚铜(Cu₂O)微米晶。通过控制NaOH加入量、油酸和NaOH的加入量、醋酸铜和葡萄糖的加入量和水/乙醇体积比,可以分别控制Cu₂O的形貌,从而得到骰子形和六足形的氧化亚铜。

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关键词: 氧化亚铜多孔腔骰子形六足形水热法

Abstract: In this work, hydrothermal method was adopted to prepare dice-like and hex-pod-like cuprous oxide(Cu₂O) microncrystals with multi-cavities via reduction of copper(II) acetate with glucose in water-ethanol alkaline solution, using oleic acid as capping agent and EDTA as chelating agent. Through controlling the dosage of NaOH, oleic acid and NaOH, Cu(OAc)₂ and glucose, water/ethanol volume ratio, the morphology of Cu₂O can be controlled respectively. Thus, cuprous oxide with dice or hexapod shape can be obtained.

Key words: cuprous oxide multi-cavity dice shape hexapod shape hydrothermal method

发布日期: 2020-07-01

ZTFLH:	TB321
	O649.4

基金资助: 广西中医药大学博士科研启动基金(2018BS027)

作者简介: 莫若飞,广西中医药大学副教授。2004年至2007年在中科院山西煤炭化学研究所获得物理化学专业理学博士学位。发表SCI论文5篇,获得中国发明专利授权2项。研究方向为无机纳米材料及其应用。近年来参与国家自然科学基金项目2项,主持广西科技开发项目1项,参与广西科技计划项目3项。

引用本文:

莫若飞. 多孔腔骰子形和六足形氧化亚铜的水热合成[J]. 材料导报, 2020, 34(Z1): 148-152.
MO Ruofei. Hydrothermal Synthesis of Dice-like and Hex-pod-like Cuprous Oxide withMulti-cavities. Materials Reports, 2020, 34(Z1): 148-152.

链接本文:

http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2020/V34/IZ1/148

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