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材料导报  2023, Vol. 37 Issue (16): 21080120-5    https://doi.org/10.11896/cldb.21080120
  高分子与聚合物基复合材料 |
石墨烯/卟啉复合气凝胶的制备与性能研究
王健阳, 马颖*, 李思仪, 李天微, 王秀梅, 万晔, 郜思同, 郭惠琳, 韦杰
沈阳建筑大学材料科学与工程学院,沈阳 110168
Preparation and Properties of Graphene/Porphyrin Composite Aerogels
WANG Jianyang, MA Ying*, LI Siyi, LI Tianwei, WANG Xiumei, WAN Ye, GAO Sitong, GUO Huilin, WEI Jie
School of Materials Science and Engineering, Shenyang Jianzhu University, Shenyang 110168, China
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摘要 石墨烯气凝胶既有石墨烯材料固有的柔性及优异的电学、力学性能,同时又具有高比表面积、低密度、大孔隙率等特点,其独特的三维结构有利于引入其他功能材料,从而赋予复合材料更为优异的性能。原卟啉分子具有高度共轭结构,并且与金属离子配位结合后可发挥催化功能。鉴于此,本工作利用原卟啉分子与石墨烯片层的π-π相互作用,在石墨烯气凝胶上组装一定浓度的原卟啉分子,从而制备了石墨烯/卟啉复合气凝胶材料。该方法工艺简单,容易操作。本工作分析了复合气凝胶材料的微观形貌和成分组成,研究了原卟啉分子的组装对石墨烯气凝胶导电性能的影响,以及石墨烯/卟啉复合气凝胶对硝酸根离子(NO3-)的检测作用。研究结果表明所制备的复合材料具有均匀的三维多孔结构,原卟啉分子的引入可以显著降低石墨烯气凝胶的电阻,而三维气凝胶结构可以有效地实现原卟啉与石墨烯的复合并实现对NO3-的灵敏检测。
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王健阳
马颖
李思仪
李天微
王秀梅
万晔
郜思同
郭惠琳
韦杰
关键词:  直写打印技术  石墨烯气凝胶  原卟啉  复合材料  硝酸根离子检测    
Abstract: Graphene aerogel not only has the inherent flexibility, excellent electrical and mechanical properties of graphene, but also has the characteristics of high specific surface area, low density, and large porosity. Its unique three-dimensional structure is very conducive to the introduction of other functional materials, thus giving the composite materials more excellent performance. Protoporphyrin possesses a highly conjugated structure and can make full use of the catalytic function after combining with the metal ions. Based on this, the π-π interaction between graphene and protoporphyrin was used in this work. The protoporphyrin with a certain concentration was assembled on the graphene aerogel, which contributed to the fabrication of the graphene/porphyrin composite aerogel materials. The process is simple and easy to operate. The micro-morphology and composition of the composites were analyzed in this work. The effect of the assembly of protoporphyrin on the conductivity of graphene aerogel and the detection function for NO3- of the graphene/porphyrin composite aerogel materials were studied. The results show that the prepared composites have a uniform three-dimensional porous structure, and the resistance of the graphene aerogel is reduced obviously after the introduction of protoporphyrin molecules. The three-dimensional aerogel structure can effectively realize the composite of protoporphyrin with graphene and achieve the sensitive detection of NO3-.
Key words:  direct write printing technology    graphene aerogel    protoporphyrin    composite materials    NO3- detection
出版日期:  2023-08-25      发布日期:  2023-08-14
ZTFLH:  TB333  
基金资助: 辽宁省教育厅项目(lnzd201905;lnzd202006;lnjc202016);辽宁省科技厅项目(20180510017)
通讯作者:  *马颖,沈阳建筑大学材料科学与工程学院副教授、硕士研究生导师。2004年渤海大学化学化工学院化学专业本科毕业,2007年东北师范大学无机化学专业硕士毕业,2010年中国科学院化学研究所物理化学专业博士毕业后到沈阳建筑大学工作至今。目前主要从事功能化石墨烯材料、有机光电功能材料等方面的研究工作。发表论文40余篇文,包括Advanced Functional Materials、Journal of Materials Chemistry、Chemical Communication等。may171@iccas.ac.cn   
作者简介:  王健阳,2019年6月30日于沈阳建筑大学获得工学学士学位。现为沈阳建筑大学材料科学与工程学院硕士研究生,在马颖副教授的指导下进行研究。目前主要的研究领域为石墨烯传感器。
引用本文:    
王健阳, 马颖, 李思仪, 李天微, 王秀梅, 万晔, 郜思同, 郭惠琳, 韦杰. 石墨烯/卟啉复合气凝胶的制备与性能研究[J]. 材料导报, 2023, 37(16): 21080120-5.
WANG Jianyang, MA Ying, LI Siyi, LI Tianwei, WANG Xiumei, WAN Ye, GAO Sitong, GUO Huilin, WEI Jie. Preparation and Properties of Graphene/Porphyrin Composite Aerogels. Materials Reports, 2023, 37(16): 21080120-5.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21080120  或          http://www.mater-rep.com/CN/Y2023/V37/I16/21080120
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