Abstract: Currently, blast furnace ironmaking process and direct reduction method are the most mainstream ironmaking technologies. Blast furnace ironmaking has large capacity and high efficiency, whereas the contradiction between high coke ratio and high energy consumption of blast furnace and the green development of the environment has become increasingly prominent. The innovative research and development of coal-based, gas-based direct reduction or smelting reduction technology continuously develop into efficiency improvement and cost reduction. However, the technology with the high-efficiency utilization of carbon as the core under the existing process is constantly approaching the potential limit of carbon reduction. With the purpose of carbon neutrality and carbon peaks, the steel manufacturing industry is actively developing and exploring alternative reduction technologies for iron ore. The rational use of H2 in the ironmaking process has become more and more significant in energy reducing and CO2 emissions. This article discusses the basic research of hydrogen reduction of iron ore, the technical advantages of hydrogen metallurgy and the problems of my country's hydrogen metallurgical technology achievements and development. It was proposed and verified that the microwave irradiation method could obtain iron powder by hydrogen-rich or pure hydrogen smelting. In the comparative experiment, microwave heating has a better reduction effect than conventional heating methods and H2 had a better reduction rate (78.6%) than that of CO(3.1%) at 1 100 ℃ on iron.
周美洁, 艾立群, 洪陆阔, 孙彩娇, 周玉青, 孟凡峻. 氢冶金基础研究和新工艺探索[J]. 材料导报, 2023, 37(13): 21080052-6.
ZHOU Meijie, AI Liqun, HONG Lukuo, SUN Caijiao, ZHOU Yuqing, MENG Fanjun. Basic Research on Hydrogen Metallurgy and Exploration of New Technology. Materials Reports, 2023, 37(13): 21080052-6.
1 Åhman M, Nilsson L J, Johansson B. Climate Policy, 2017, 17(5), 634. 2 Åhman M, Nilsson L J, Johansson B. Climate Policy, 2016, 6(13), 1. 3 Carlos D J, Henrique N J, Marques K H. In:5th International Confe-rence on Science and Technology of Ironmaking. Shanghai, China, 2009, pp.14. 4 Zhang S R. In:Proceedings of 6th ECIC. Dusseldorf, Germany, 2011, pp.1. 5 Zhang S R, Yin H. Iron Steel , 2007(9), 1 (in Chinese). 张寿荣, 银汉. 钢铁, 2007(9), 1. 6 Cavaliere P. Springer Nature Switzerland, 2019, 183, 478. 7 Longbottom RJ, Kolbeinsen L. Faculty of Engineering-Papers, 2008, 4, 1260 8 Bruggeman P J, Sadeghi N, Schram D C, et al. Plasma Sources Science and Technology, 2014, 23(2), 1. 9 Bogdandy L V, Engell H J. The Reduction of Iron Ores, DOI:10. 1007/978-3-662-10400-2. 10 McKewan W M. Transactions of the Metallurgical Society of Aimee, 1962, 224, 2. 11 Turkdogan E T, Olsson R G, Vinters J V. Metallurgical and Materials Transactions B, 1971, 2B, 96. 12 Jun S, Zhang H, Bechhoefer J. Physical Review E, 2005, 71, 011908. 13 Spreitzer D, Schenk J. Metallurgical and Materials Transactions B, 2019, 50(10), 2471. 14 Farjas J, Roura P. Acta Materialia, 2006, 54(20), 5573. 15 Chen H, Zheng Z, Chen Z, Bi T. Powder Technology, 2017, 316, 20. 16 Munteanu G, Ilieva L, Andreeva D. Thermochimica Acta 1997, 291, 77. 17 Shimokawabe M, Furuichi R, Ishii T. Thermochimica Acta, 1979, 28, 287. 18 Zhong Y W, Wang Z, Gao J T, et al. Powder Technology, 2016, 301(11), 1144. 19 Guo X G, Yasushi S, Yoshiaki K, et al. Metallurgical and Materials Transactions B, 2004, 35B, 517. 20 Pineau A, Kanari N. Thermochimica Acta, 2006, 447(1), 89. 21 Pineau A, Kanari N, Gaballah I. Thermochimica Acta, 2007, 456(2), 75. 22 Sabat K C, Paramguru R K, Pradhan S, et al. Plasma Chemistry and Plasma Processing, 2014, 34 (1), 1. 23 Rajput P, Sabat K C, Paramguru R K, et al. Ironmaking & Steelma-king, 2014, 41(10), 31. 24 Rajput P, Bhoi B, Sahoo S, et al. Ironmaking & Steelmaking, 2013, 40(1), 61. 25 Sohn H Y, Olivas-Martinez M. Journal of Metals, 2014, 66 (9), 64. 26 Liu W, Lim J Y, Saucedo M A, et al. Chemical Engineering Science, 2014, 120, 149. 27 Ferrari A, Hunt J, Lita A. The Journal of Physical Chemistry C, 2014, 118 (18), 9346. 28 Yukiaki H, Mitsuhiro S, Shinichi K. Iron and Steel, 1976, 62(3), 315. 29 Masanori Tokuda. Blast furnace in reaction(II). Japan steel association 116117th nishiyama memorial technology lecture, Nishiyama, 1987. 30 Murakami T, Kamiya Y, Kodaira T, et al. ISIJ International, 2012, 52(8), 1447. 31 Liu D H, Wang X Z, Zhang J L, et al. Metallurgical Research & Technology, 2017, 114(6), 1. 32 Moujahid S E, Rist. AMetallurgical Transactions B, 1988, 19(5), 787. 33 Guo L, Gao H, Yu J T, et al. International Journal of Minerals Metallurgy and Materials, 2015, 1, 12. 34 Plaul J F, Hiebler H. Metalurgija, 2004, 3, 155. 35 Sabat K C, Murphy A B. Metallurgical and Materials Transactions B, 2017, 48(3), 1561. 36 Sabat K C, Rajput P, Paramguru R K, et al. Plasma Chem. Plasma Process. , 2014, 34 (1), 1 37 Xing L Y, Qu Y X, Wang C S, et al. Metallurgical and Materials Tran-sactions B, 2019, 12, 1 38 Yousef M, Chen F, Mohamed E, et. al. Process the Minerals, Metals & Materials Society, 2016, 2, 221. 39 Sohn H Y, Fan D Q. Metals, 2021, 11, 332. 40 Qu Y X, Xing L Y, Wang C S. International Journal of Hydrogen Energy, 2020, 45, 31481 41 Gold R G, Sandall W R, Cheplick P G, et al. Ironmaking & Steelmaking, 1977, 4 (10), 10. 42 Tang J, Chu M S, L F, et al. Hebei Metallurgy, 2020(8), 1(in Chinese). 唐珏, 储满生, 李峰, 等. 河北冶金, 2020(8), 1. 43 Barreto L, Makihira A, Riahi K. International Journal of Hydrogen Energy, 2003, 28(3), 267. 44 Wang S, Lu A L, Zhong C J. Nano Converg, 2021, 8, 2196. 45 Walters L, Wade D, Lewis D. Nuclear Energy, 2002, 42(1), 55. 46 Ogden J M. Annual Review of Energy and the Environment, 1999, 24, 227. 47 Forsberg C W. International Journal of Hydrogen Energy, 2007, 32, 9. 48 Lee S Y, Park S J. International Journal of Hydrogen Energy, 2015, 23, 1. 49 Dutcher B, Fan M, Russell A G. ACS Applied Materials & Interfaces, 2015, 7(4), 2137. 50 Lewis D. Progress in Nuclear Energy, 2008, 50, 394. 51 Cheng J, Roy R, Agrawal D. Materials Research Innovations, 2002, 5, 170. 52 Roy R, Peelamedu R, Hurtt L, et al. Materials Research Innovations, 2002, 6, 128. 53 Chen J, Liu L, Zeng J Q, et al. Journal of Iron and Steel research International, 2005, 12, 16. 54 Zhong S, Geotzman H E, Bleifuss R L. Mining Metallurgy & Exploration, 1996 (300), 174. 55 Mourao MB, Parreiras I, Carvalho J, Takano C. ISIJ International, 2001 (41), S27. 56 Chen J, Liu L, Zeng J Q, et al. Iron Steel, 2004, 39 (6), 1(in Chinese). 陈津, 刘浏, 曾加庆, 等. 钢铁, 2004, 39 (6), 1. 57 Ishizaki K, Nagata K, Hayashi T. ISIJ International, 2006, 46(10), 1403.