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材料导报  2023, Vol. 37 Issue (10): 22080168-7    https://doi.org/10.11896/cldb.22080168
  城市固废材料高效处理及资源化利用 |
氮掺杂再生活性炭的制备及电催化氧还原反应性能研究
叶嘉鸿1,2,3,4, 李德念2,3,4, 阳济章2,3,4, 赵悦2,3,4, 袁浩然2,3,4,*, 陈勇1,2,3,4
1 华南农业大学生物质工程研究院,广州 510642
2 中国科学院广州能源研究所,广州 510640
3 南方海洋科学与工程广东省实验室(广州),广州 511458
4 广东省新能源和可再生能源研究开发与应用重点实验室,广州 510640
Preparation and Electrocatalytic Oxygen Reduction Performance of Nitrogen Doped Regenerated Activated Carbon
YE Jiahong1,2,3,4, LI Denian2,3,4, YANG Jizhang2,3,4, ZHAO Yue2,3,4, YUAN Haoran2,3,4,*, CHEN Yong1,2,3,4
1 School of Biomass Engineering Research, South China Agricultral University, Guangzhou 510642, China
2 Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
3 Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou), Guangzhou 511458, China
4 Guangdong Provincial Key Laboratory of New Energy and Renewable Energy Research, Development and Application, Guangzhou 510640, China
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摘要 为解决危废活性炭传统回收方式带来的资源浪费和环境污染等问题,本工作以抗生素脱色废活性炭为原料、氨气为氮源,采用高温热解再生法将氮元素通过sp2杂化键合进入到活性炭骨架中,制备了氮掺杂再生废活性炭氧还原反应(ORR)催化剂,分析了氮掺杂再生活性炭的物相组成、微观形貌、电化学性能。结果表明,当温度为1 000 ℃、退火时间为1 h时,所制备的N-RWAC-1000-1氧还原电催化性能最佳。N-RWAC-1000-1具有丰富的微孔和介孔结构,比表面积可达908 m2/g,在碱性介质中的起始电位为0.92 V(vs.RHE),半波电位为0.82 V(vs.RHE),均接近商业20%(质量分数)的铂碳催化剂。此外,氮掺杂再生炭拥有优于商业化铂碳的循环稳定性和甲醇耐受性,有望成为新的氧还原催化剂以期为抗生素脱色废活性炭的高值化利用提供了新的方向。
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叶嘉鸿
李德念
阳济章
赵悦
袁浩然
陈勇
关键词:  废活性炭  高温热再生  氮掺杂碳  氧还原反应    
Abstract: In order to solve the problems of resource waste and environmental pollution caused by the traditional recycling of hazardous waste activated carbon, this work prepared a nitrogen-doped regenerated waste activated carbon oxygen reduction reaction (ORR) catalyst by using anti-biotic decolorization waste activated carbon as raw material and ammonia gas as nitrogen source, and the nitrogen element was bonded into the activated carbon skeleton through sp2 hybridization by high temperature pyrolysis regeneration. The physical composition, microscopic morphology and electrochemical properties of the nitrogen-doped regenerated activated carbon were analyzed. The results showed that the best perfor-mance of the prepared N-RWAC-1000-1 oxygen reduction electrocatalyst was achieved when the temperature was 1 000 ℃ and the annealing time was 1 h. The N-RWAC-1000-1 had abundant microporous and mesoporous structures with a specific surface area up to 908 m2/g. The starting potential in alkaline medium was 0.92 V (vs.RHE), the half-wave potential was 0.82 V (vs.vs.RHE), both close to commercial 20wt% platinum carbon catalysts. In addition, the nitrogen-doped regenerated carbon possesses better cycling stability and methanol tolerance than commercial platinum carbon and is expected to be a new oxygen reduction catalyst. It also provides a new direction for the high-value utilization of antibiotic decolorization waste activated carbon.
Key words:  waste activated carbon    high temperature thermal regeneration    nitrogen doped carbon    oxygen reduction reaction
出版日期:  2023-05-25      发布日期:  2023-05-23
ZTFLH:  TM911.4  
  O643.36  
基金资助: 国家重点研发计划(2019YFC1906605);广州市科技计划项目(202201010687);广东省基础与应用基础研究基金(2022A1515011653)
通讯作者:  袁浩然,研究员。2003年毕业于合肥工业大学热能工程专业,获学士学位;2010年毕业于中国科学院广州能源研究所,获博士学位;2011年访问日本名古屋大学生物化学工程系,现任中国科学院广州能源研究所城乡矿山集成技术研究室副主任。致力于有机固废能源化与资源化高效清洁利用基础理论研究及技术开发。发表SCI/EI论文120余篇(第一或通信作者)。yuanhr@ms.giec.ac.cn   
作者简介:  叶嘉鸿,2021年6月在华南农业大学获得工学学士学位,现为华南农业大学材料与能源学院硕士研究生,于2021年9月在中科院广州能源研究所联合培养学习,主要从事固体废弃物高值化利用研究。
引用本文:    
叶嘉鸿, 李德念, 阳济章, 赵悦, 袁浩然, 陈勇. 氮掺杂再生活性炭的制备及电催化氧还原反应性能研究[J]. 材料导报, 2023, 37(10): 22080168-7.
YE Jiahong, LI Denian, YANG Jizhang, ZHAO Yue, YUAN Haoran, CHEN Yong. Preparation and Electrocatalytic Oxygen Reduction Performance of Nitrogen Doped Regenerated Activated Carbon. Materials Reports, 2023, 37(10): 22080168-7.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22080168  或          http://www.mater-rep.com/CN/Y2023/V37/I10/22080168
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