基于金属有机框架材料的氧还原催化剂研究进展

doi:10.11896/cldb.20080238

材料导报

2022, Vol. 36

Issue (19): 20080238-9 https://doi.org/10.11896/cldb.20080238

金属与金属基复合材料

基于金属有机框架材料的氧还原催化剂研究进展

任雨峰, 栾伟玲, 姜滔

华东理工大学机械与动力工程学院,承压系统与安全教育部重点实验室, 上海 200237

Research Progress of Oxygen Reduction Catalysts Based on Metal-Organic Framework Materials

REN Yufeng, LUAN Weiling, JIANG Tao

Key Laboratory of Pressure Systems and Safety (MOE), School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai 200237, China

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摘要燃料电池具有发电效率高、污染噪音小、运行可靠等优势,能够作为新能源汽车的主要动力来源,因此受到各国的广泛关注。氧还原反应(ORR)作为燃料电池中重要的电化学反应,对催化剂有较高的要求,然而目前广泛使用的Pt催化剂存在高成本和低耐久性的问题,限制了新能源汽车的发展。采用非Pt催化剂或低Pt催化剂可以实现在性能不变的前提下降低成本,是推进燃料电池汽车商业化应用的关键。通过金属有机框架材料(MOF)研制的无金属催化剂和过渡金属催化剂可完全替代贵金属Pt催化剂,其中利用ZIF系列制备的MOF基Fe系和Co系催化剂是ORR研究的热点。受非贵金属催化剂的启发,低Pt催化剂通过MOF实现负载或合金化,进一步提升了低Pt催化剂的电化学活性及耐久性。本文就近期基于MOF材料的ORR催化剂研究进展进行综述,介绍了无金属催化剂、过渡金属催化剂和贵金属催化剂的研究现状及面临的挑战,为获得性能优越的ORR催化剂提供了技术支持。

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关键词: 氧还原反应催化剂金属有机框架材料燃料电池

Abstract: With the advantages of high power generation efficiency, low pollution and noise, and reliable operation, fuel cells have attracted widespread attention from various countries as they can be used as the main power source for new energy vehicles. Oxygen reduction reaction (ORR), as an important electrochemical reaction in fuel cells, has higher requirements on catalysts. However, the high cost and low durability of Pt catalyst used widely restrict the development of new energy vehicles. Non-Pt catalysts or low-Pt catalysts can reduce costs while maintaining the same performance, which is the key to promoting the commercial application of fuel cell vehicles. Metal-free catalysts and transition metal catalysts prepared by metal-organic framework materials (MOF) can completely replace precious metal Pt catalysts. Among them, the Fe-based and Co-based MOF catalysts developed using the ZIF series are the focus of ORR research. In addition, inspired by non-precious metal catalysts, low-Pt catalysts are supported or alloyed through MOF, which further improves low-Pt catalysts electrochemical activity and durability. This paper reviews the recent research progress of ORR catalysts based on MOF materials, introduces the research status and challenges of metal-free catalysts, transition metal catalysts and precious metal catalysts, and provides technical support for obtaining ORR catalysts with superior performance.

Key words: oxygen reduction reaction catalyst metal-organic framework material fuel cells

出版日期: 2022-10-10 发布日期: 2022-10-12

ZTFLH:

TM911.4

基金资助: 国家自然科学基金(51475166);上海汽车工业科技发展基金(1801)

通讯作者: luan@ecust.edu.cn

作者简介: 任雨峰,2018年6月毕业于辽宁石油化工大学,获得工学学士学位。现为华东理工大学机械与动力工程学院硕士研究生,在栾伟玲教授的指导下进行研究。目前主要研究领域为燃料电池氧还原反应催化剂。
栾伟玲,华东理工大学机械与动力工程学院教授、博士研究生导师。1998年7月于中国科学院上海硅酸盐研究所获得工学博士学位。1998年8月至2000年9月在中国科学院上海硅酸盐研究所高性能陶瓷与超微结构国家重点实验室工作。目前主要研究方向包括:新型能源与传感技术、纳米技术应用。在材料领域发表相关研究论文120余篇,包括Applied Energy、Nanoscale、Journal of Materials Che-mistry C等。

引用本文:

任雨峰, 栾伟玲, 姜滔. 基于金属有机框架材料的氧还原催化剂研究进展[J]. 材料导报, 2022, 36(19): 20080238-9.
REN Yufeng, LUAN Weiling, JIANG Tao. Research Progress of Oxygen Reduction Catalysts Based on Metal-Organic Framework Materials. Materials Reports, 2022, 36(19): 20080238-9.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.20080238 或 http://www.mater-rep.com/CN/Y2022/V36/I19/20080238

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