Abstract: Alarge number of volatile organic compounds (VOCs), which cause serious harm to atmosphere and human health, are discharged into the environment by manufacturing industries. Their emissions have been strictly controlled by the state in recent years. Catalytic combustion realizes complete transformation of VOCs at low temperatures by significantly reducing the reaction activation energy and avoiding secondary pollution due to incomplete combustion. Therefore, it has become one of the most promising methods currently used to eliminate VOCs. The application of catalytic combustion technology depends on the use of high-performance catalysts. A monolithic catalyst with honeycomb ceramic structure can overcome the disadvantages of traditional particle catalysts, such as large drop in bed pressure, significant temperature gra-dient and uneven distribution of reactants on the surface. On the contrary, it has high mechanical strength, lower bed pressure and efficient mass transfer, playing a crucial role in achieving high airspeed, large flux and other harsh waste gas treatment. At present, the research on the monolithic catalysts for the catalytic combustion of VOCs is mainly focused on two aspects. I. Design of catalysts with good crystal structure by doping different metals to improve catalytic activity and reduce production costs. II. Development of a simple and efficient preparation process to ensure the binding strength of active components and substrate under harsh reaction conditions and enhance the wear resistance. Recent progress in research on ceramic-based monolithic catalysts for the catalytic combustion of VOCs and their preparation process are reviewed in this paper. Furthermore, the basic mechanism of the catalytic combustion of VOCs is explored. Based on the current state of research and shortcomings, the future development trend of the catalyst is prospected to provide reference for the synthesis of catalysts with high activity, good stability, strong universality and low cost for catalytic combustion of VOCs.
王博磊, 钟和香, 张晶, 李夺, 王鹤臻, 周广波, 赵思阳, 王新雨, 潘立卫. 陶瓷基整体式催化剂催化燃烧挥发性有机物的研究进展[J]. 材料导报, 2022, 36(14): 20120169-9.
WANG Bolei, ZHONG Hexiang, ZHANG Jing, LI Duo, WANG Hezhen, ZHOU Guangbo, ZHAO Siyang, WANG Xinyu, PAN Liwei. Research Progress of Ceramic-based Monolithic Catalysts for the Catalytic Combustion of VOCs. Materials Reports, 2022, 36(14): 20120169-9.
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