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材料导报  2021, Vol. 35 Issue (3): 3050-3056    https://doi.org/10.11896/cldb.19120251
  无机非金属及其复合材料 |
SiCf/SiC复合材料制备研究进展
杨博, 余金山, 顾全超, 王洪磊, 周新贵
国防科技大学新型陶瓷纤维及其复合材料重点实验室,长沙 410073
Research Progress on Preparation of SiCf/SiC Composite
YANG Bo, YU Jinshan, GU Quanchao, WANG Honglei, ZHOU Xingui
Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, National University of Defense Technology, Changsha 410073, China
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摘要 随着科学技术的不断发展,人类对极端条件下应用的材料的需求持续上升。 SiCf/SiC复合材料具有耐高温、高强高韧、耐氧化等优点,成为航空航天领域热端部件的理想候选材料;同时,SiCf/SiC复合材料还具有低活化、抗辐照、高温化学稳定性好等优异性能,在核电领域结构材料的应用具有广阔的前景。
常用的SiCf/SiC复合材料的制备方法有化学气相渗透法、先驱体浸渍裂解法、热压烧结工艺和熔融浸渍法,其中化学气相渗透法和先驱体浸渍裂解法两种工艺已经应用于航空发动机静载热端部件的生产,但是这些工艺自身固有的不足在材料制备中依然无法较好地解决,于是近年来出现了混合采用多种工艺来制备SiCf/SiC复合材料的尝试。SiC纤维和基体间需要有一层界面层来偏转裂纹、保护纤维,目前常用的界面材料有热解炭和六方氮化硼涂层,由于单一涂层较难满足材料在多种复杂条件下的应用需求,针对涂层改进的新方法和新思路层出不穷。相对于传统烧结工艺,新型烧结方式如微波烧结和放电等离子烧结等在烧结速度、温度均匀性等方面展示出巨大的优势,为陶瓷基复合材料的制备提供了新的选择。
为了进一步提升SiCf/SiC复合材料的性能,近年的研究工作主要集中在对SiCf/SiC复合材料的制备方法的优化、纤维/基体界面层的创新和对烧结技术的选择等方面。本文从这些方面对SiCf/SiC复合材料的研究进展进行了详细的归纳和介绍。
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杨博
余金山
顾全超
王洪磊
周新贵
关键词:  SiCf/SiC复合材料  混合制备工艺  纤维涂层  放电等离子烧结  微波烧结    
Abstract: With the development of science and technology, the demand for materials applied in extreme environment has increasing continuously. SiCf/SiC composite, with the advantages of high temperature resistance, high strength, high toughness, and oxidation resistance, can meet the performance requirements of thermal structural materials in high-tech fields such as aerospace. Meanwhile, the excellent properties of SiCf/SiC composite such as low activation, anti-radiation, and high-temperature chemical stability offer this material wide application prospects as nuclear structural materials
The SiCf/SiC composites are commonly prepared by chemical vapor infiltration(CVI), polymer infiltration and pyrolysis(PIP), hot-pressing sintering(HP) and melt infiltration(MI). Among of these methods, CVI and PIP have been applied in aircraft engines hot components. For these single preparation methods, the inherent shortcomings cannot be solved well during the material preparation processes, thus, a variety of new met-hods have been attempted to prepare SiCf/SiC composites in recent years. For SiCf/SiC composites, an interfacial layer is needed between the SiC fiber and the substrate interface to deflect cracks and protect the fiber. The currently used interface materials are pyrolytic carbon and hexagonal boron nitride. Usually a single coating is difficult to meet the application of the material under a variety of complex conditions, new methods of preparation interfacial layer are studied widely. Compared with the traditional sintering process, new sintering technologies such as microwave sintering and spark plasma sintering have shown great advantages in sintering speed and thermal uniformity, providing new options for the preparation of ceramic matrix composite materials.
In order to further improving the performance of SiCf/SiC composites, recent research works have focused on the optimization of SiCf/SiC composites preparation methods, innovation of fiber/matrix interface layers, and study of new sintering technologies. In this paper, the research progress of SiCf/SiC composites preparation is summarized in detail.
Key words:  SiCf/SiC composites    hybrid preparation process    fiber coating    spark plasma sintering    microwave sintering
               出版日期:  2021-02-10      发布日期:  2021-02-19
ZTFLH:  TB332  
基金资助: 国家自然科学基金(51372274)
作者简介:  杨博,2018年6月毕业于中国地质大学(武汉),获得工学学士学位。现为国防科技大学空天科学学院硕士研究生,在余金山导师的指导下进行研究。目前研究领域为纤维增强碳化硅基陶瓷的制备。
余金山,2006年毕业于上海交通大学并获得材料学博士学位,随后在日本东北大学从事3年博士后研究工作,2009年回国后在国防科技大学任副研究员,从事陶瓷基复合材料制备工艺研究及材料分析测试方面的工作,发表学术论文50余篇,申请专利10多项。
引用本文:    
杨博, 余金山, 顾全超, 王洪磊, 周新贵. SiCf/SiC复合材料制备研究进展[J]. 材料导报, 2021, 35(3): 3050-3056.
YANG Bo, YU Jinshan, GU Quanchao, WANG Honglei, ZHOU Xingui. Research Progress on Preparation of SiCf/SiC Composite. Materials Reports, 2021, 35(3): 3050-3056.
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http://www.mater-rep.com/CN/10.11896/cldb.19120251  或          http://www.mater-rep.com/CN/Y2021/V35/I3/3050
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