材料与可持续发展（三）--环境友好材料与环境修复材料*
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5B族(Nb,V和Ta)合金渗氢膜的研究进展
陈运灿1 , 闫二虎1,* , 狄翀博1 , 王金华1 , 黄浩然1,2 , 王豪1 , 刘威1 , 徐芬1 , 孙立贤1
1 桂林电子科技大学,广西信息材料重点实验室,桂林 541004;
Research Progress of Hydrogen Permeable Membrane of 5B Group (Nb,V and Ta) Alloys
CHEN Yuncan1 , YAN Erhu1,* , DI Chongbo1 , WANG Jinhua1 , HUANG Haoran1,2 , WANG Hao1 , LIU Wei1 , XU Fen1 , SUN Lixian1
1 Guangxi Key Laboratory of Information Laboratory, Guilin University of Electronic Technology, Guilin 541004, China
摘要 氢气是一种可持续发展的清洁能源载体,具有热值高、零污染等优点,近年来成为全球各国争相探索的焦点。传统氢制备技术(如天然气水蒸气重整制氢)制备的成品氢中均含有不同程度的杂质气体,因此,渗氢(或氢提纯)成为制取纯氢的一个重要环节。近30年,钯及其合金已被成功开发,但是其价格昂贵,亟待开发价格低廉且渗氢性能优异的新型金属膜材料。为了解决该问题,5B族金属(Nb、V和Ta)及其合金膜由于具有较低的价格和较高的渗氢性能而备受关注,各国学者对其开展了大量的研究工作。基于此,本文首先总结了上述合金膜近10年来的发展历程,并分别对各合金体系进行概括;其次,分析比较了上述合金膜的制备工艺,并结合其对合金渗氢性能的影响进行了阐述;最后,总结了影响上述合金膜氢渗透性能的关键因素,并展望其在未来氢分离研究中的发展趋势。
关键词:
5B族合金
制备工艺
成分优化
氢渗透性能
Abstract: Hydrogen is a clean energy carrier with sustainable development, which has the advantages of high calorific value and zero pollution, and has become the focus of global scramble to explore in recent years. The hydrogen produced by the traditional hydrogen preparation technology (e.g. Natural gas steam reforming to produce hydrogen) contains different levels of impurity gas. Therefore, hydrogen permeation (or hydrogen purification) technology has become an important part of the preparation of pure hydrogen. Palladium and its alloys have been successfully developed in the past 30 years, but they are too expensive. So it is urgent to develop some new type of hydrogen permeable membranes which are not only inexpensive but also possess an excellent hydrogen permeability. To resolve above problem, 5B group metals (Nb, V and Ta) and their alloy membranes have attracted much attention due to their low price and high hydrogen permeability. And scholars from various countries have carried out a lot of research work. In this paper, we firstly summarize the development process of the above alloy membranes in the past ten years, and different alloy systems are also discussed, respectively. Secondly, the preparation process of the alloy membranes is analyzed and compared, and its influence on the hydrogen permeation performance of these alloys is described. Finally, the key factors affecting the hydrogen permeability of the above alloy membranes are summarized, and the prosperous future of these alloys in hydrogen separation studies is expected.
Key words:
5B group metals
preparation process
composition optimization
hydrogen permeation performance
出版日期: 2020-11-10
发布日期: 2020-11-17
基金资助: 国家自然科学基金(51761009;51701048);桂林电子科技大学研究生教育创新计划项目(2019YCXS109);广西信息材料重点实验室基金项目(191021-Z)
作者简介: 陈运灿,2018年6月毕业于桂林电子科技大学,获得工学学士学位。现为桂林电子科技大学材料科学与工程学院硕士研究生,在闫二虎副教授的指导下进行研究,目前主要研究领域为新型渗氢合金/多元合金凝固理论。International Journal of Hydrogen Energy,Journal of Crystal Growth,International Journal of Materials Research ,《金属学报》等刊物上发表SCI文章40余篇。
引用本文:
陈运灿, 闫二虎, 狄翀博, 王金华, 黄浩然, 王豪, 刘威, 徐芬, 孙立贤. 5B族(Nb,V和Ta)合金渗氢膜的研究进展[J]. 材料导报, 2020, 34(21): 21001-21011.
链接本文:
http://www.mater-rep.com/CN/10.11896/cldb.19110013
或
http://www.mater-rep.com/CN/Y2020/V34/I21/21001
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2020, Vol. 34 
