合金化对Mg-Ni系合金储氢性能的影响:综述

doi:10.11896/cldb.19110205

材料导报

2021, Vol. 35

Issue (9): 9033-9040 https://doi.org/10.11896/cldb.19110205

轻质合金

合金化对Mg-Ni系合金储氢性能的影响:综述

卢祺, 黄锋^*, 郭逊

武汉理工大学现代汽车零部件技术湖北省重点实验室,武汉 430070

Effect of Alloying on Hydrogen Storage Properties of Mg-Ni System Alloys: a Review

LU Qi, HUANG Feng^*, GUO Xun

Hubei Key Laboratory of Advanced Technology for Automotive Components, Wuhan University of Technology, Wuhan 430070, China

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摘要 Mg基合金具有储氢量大、质量轻、资源丰富、价格低廉等特点,但其较高的放氢温度和较慢的吸放氢速率是限制其应用的关键问题。合金化是改善Mg基储氢合金吸放氢热力学和动力学的有效方法,在纯Mg中添加Ni会形成Mg₂Ni,其吸放氢热力学与动力学均会得到明显改善,但仍不够理想,有待进一步提高。本文就合金化对Mg-Ni系合金储氢性能的影响进行了综述,整理了各合金元素的添加对Mg-Ni系合金吸放氢热力学与动力学的影响,最后对Mg-Ni系合金的发展进行了展望。

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关键词: Mg-Ni系合金合金化储氢性能

Abstract: Mg-based alloys have the characteristics of high hydrogen storage capacity, light weight, abundant resources and low price, but their high hydrogen release temperature and slow hydrogen absorption and desorption rate are the key issues that limit their application. Alloying is an effective method to improve the thermodynamics and kinetics of hydrogen absorption and desorption of Mg-based alloys. The addition of Ni to pure Mg will form Mg₂Ni, and the thermodynamics and kinetics of hydrogen absorption and desorption will be significantly improved, but it is still not ideal and needs to be further improved. In this paper, the effects of alloying on the hydrogen storage performance of Mg-Ni alloys are reviewed. The effects of the addition of various alloying elements on the thermodynamics and kinetics of hydrogen absorption and desorption of Mg-Ni alloys are discussed. Finally, the prospect of research on Mg-Ni alloys is presented.

Key words: Mg-Ni system alloys alloying hydrogen storage property

出版日期: 2021-05-10 发布日期: 2021-05-31

ZTFLH:

TG139+.7

基金资助: 国家自然科学基金(51501136)

通讯作者: huangfeng@whut.edu.cn

作者简介: 卢祺,2018年6月毕业于武汉理工大学汽车工程学院,获得工学学士学位。现为武汉理工大学汽车工程学院硕士研究生,在黄锋副教授的指导下进行研究。目前主要研究领域为镁基储氢合金。
黄锋,武汉理工大学汽车工程学院副教授,硕士研究生导师。获东北大学冶金工程学士学位,哈尔滨工业大学材料加工工程硕士、博士学位,武钢博士后,南洋理工大学访问学者。Modern Materials Science and Technology编委。主持国家自然科学基金青年基金1项,国家重点实验室开放课题2项,事业单位横向委托2项,企业横向委托1项,参与国家自然基金、重大研发计划、校企合作等项目多项。在International Journal of Heat and Mass Transfer、Separation and Purification Technology、Materials Science in Semiconductor Processing、Journal of Crystal Growth、Vacuum等重要学术期刊上共发表学术论文30余篇,其中SCI论文20余篇。授权国家发明专利5项,受理6项。

引用本文:

卢祺, 黄锋, 郭逊. 合金化对Mg-Ni系合金储氢性能的影响:综述[J]. 材料导报, 2021, 35(9): 9033-9040.
LU Qi, HUANG Feng, GUO Xun. Effect of Alloying on Hydrogen Storage Properties of Mg-Ni System Alloys: a Review. Materials Reports, 2021, 35(9): 9033-9040.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.19110205 或 http://www.mater-rep.com/CN/Y2021/V35/I9/9033

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