Hydrogen Resistance of X52 Pipeline Steel Under Hydrogen Environment
BAI Guangqian1, WANG Qiuyan2, DENG Haiquan2, LI Donglin2, LI Yun1
1 School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, China 2 Sinopec Petroleum Engineering Zhongyuan Corporation, Puyang 457001, China
Abstract: As a new technology for hydrogen transporting, hydrogen and compressed nature gas (HCNG) has significance on the realization of large-scale hydrogen transportationby pipeline network. However, the presence of hydrogen will lead to the mechanical properties degradation of pipeline metal, which seriously threatens the safe use of pipeline network. X52 pipeline steel was chosen as the research object. The influence of hydrogen charging current density on the tensile property of X52 was studied by simultaneous cathodic charging and slow straining rate test. The influence of electrolytic hydrogen environment on crack growth rate of X52 was studied through fatigue crack growth test. In addition, the fracture morphology of tensile and fatigue specimens was observed by means of SEM to analyze the mechanism of X52 hydrogen embrittlement fracture. Test results show that electrochemical hydrogen charging has effect on mechanical properties of X52. As charging current density elevates, the strength of materials enhances slightly but its plasticity decreases significantly. Changes in the microstructure of the tensile specimen section indicated that the fracture mode of material transforms from dimple ductile fracture to quasi-dissociative brittle fracture with elevated hydrogen charging current density. Electrolytic hydrogen environment will accelerate the crack growth rate of X52. Micro fractures indicate that hydrogen embrittlement mechanism dominates the crack propagation process.
白光乾, 王秋岩, 邓海全, 李冬林, 李云. 氢环境下X52管线钢的抗氢性能[J]. 材料导报, 2020, 34(22): 22130-22135.
BAI Guangqian, WANG Qiuyan, DENG Haiquan, LI Donglin, LI Yun. Hydrogen Resistance of X52 Pipeline Steel Under Hydrogen Environment. Materials Reports, 2020, 34(22): 22130-22135.
Barreto L, Makihira A, Riahi K.International Journal of Hydrogen Energy, 2003, 28(3),267.2 Ma D, Li X.Chemical Enterprise Management, 2015, 390(31),170(in Chinese).麻冬, 李昕.化工管理, 2015, 390(31),170.3 Yuan J Q, Wang L P.Heat Treatment of Metals, 2015, 40(12),56(in Chinese).原佳强, 王莉萍.金属热处理, 2015, 40(12),56.4 Meng B, Gu C, Zhang L, et al.International Journal of Hydrogen Energy, 2017, 42(11),7404.5 Zhu W Y.Hydrogen embrittlement and stress corrosion cracking, Science Press, China, 2013(in Chinese).褚武扬.氢脆和应力腐蚀, 科学出版社, 2013.6 Zhang X Q, Jiang Q M.Pressure Vessel Technology, 2015, 32(11),47(in Chinese).张小强, 蒋庆梅.压力容器, 2015, 32(11),47.7 Jiang Q M, Zhang X Q.Pressure Vessel Technology, 2015, 29(8),48(in Chinese).蒋庆梅, 张小强.压力容器, 2015, 29(8),48.8 Arafin M A, Szpunar J A.Materials Science and Engineering, A, 2011, 528(15),4927.9 Mohtadi-bonab M A, Szpunar J A, Razavi-tousi S S.International Journal of Hydrogen Energy, 2013, 38(31),13831.10 Jin T Y, Cheng Y F.Corrosion Science, 2011, 53(2),850.11 Hu L, Chen J, Wang B, et al.Materials for Mechanical Engineering, 2015, 39(9),25(in Chinese).胡亮, 陈健, 汪兵, 等.机械工程材料, 2015, 39(9),25.12 Fan Y W, Wu M, Chen X, et al.Hot Working Technology, 2017, 46(4),48(in Chinese).范裕文, 吴明, 陈旭,等. 热加工工艺, 2017, 46(4),48.13 Zhao Y.Journal of Chinese Society for Corrosion and Protection, 2004, 24(5),293(in Chinese).赵颖.中国腐蚀与防护学报, 2004, 24(5),293.14 Liu Y, Li Y, Li Q.Acta Metallurgica Sinica, 2013, 49(9),1089(in Chinese).刘玉, 李焰, 李强.金属学报, 2013, 49(9),1089.15 Gadala I M, Alfantazi A.Metallurgical and Materials Transactions A, 2015, 46(7),3104.16 Chatzidouros E V, Traidia A, Devarapalli R S, et al.International Journal of Hydrogen Energy, 2018, 43(11), 5747.17 Zhong Y, Shan Y Y, Huo C Y, et al.Materials Review, 2003, 17(8),11(in Chinese).钟勇, 单以银, 霍春勇,等. 材料导报, 2003, 17(8),11.18 Hu H J, Li K, Wu W, et al.Journal of Xi'an Jiaotong University, 2016, 50(7),89(in Chinese).胡海军, 李康, 武玮,等. 西安交通大学学报, 2016, 50(7),89.19 Wang H H, Feng Y J, Hou F.Pressure Vessel Technology, 2015, 25(12),1(in Chinese).王和慧, 冯亚娟, 侯峰.压力容器, 2015, 25(12),1.20 Shen K, Xia B, Xu L, et al.Transactions of Materials and Heat Treatment, 2017, 38(8),76(in Chinese).谌康, 夏彬, 徐乐,等. 材料热处理学报, 2017, 38(8),76.21 Duan L N, Chen J, Wang B, et al.Heat Treatment of Metals, 2017, 42(6),1(in Chinese).段琳娜, 陈健, 汪兵,等. 金属热处理, 2017, 42(6),1.22 Tan W Z, Du Y L, Fu C, et al.Materials Protection, 1988, 3(3),10(in Chinese).谭文志, 杜元龙, 傅超,等. 材料保护, 1988, 3(3),10.23 Kong D J, Wu Y Z, Long D.International, 2013, 20(1),40.24 Beachem C D.Metallurgical Transactions, DOI: 10.1007/BF02642048.25 Oriani R A.Berichte der Bunsengesellschaft für physikalische Chemie, 2010, 76(8),848.26 Fan L, Li X G, Du C W, et al.Corrosion and Protection, 2012, 33(11),990(in Chinese).范林, 李晓刚, 杜翠薇,等. 腐蚀与防护, 2012, 33(11),990.