宽带隙金属氧化物材料光催化降解苯系物:反应机理和改性策略

doi:10.11896/cldb.21090250

材料导报

2021, Vol. 35

Issue (21): 21001-21011 https://doi.org/10.11896/cldb.21090250

环境催化材料

宽带隙金属氧化物材料光催化降解苯系物:反应机理和改性策略

陈侣存^1,2, 崔雯¹, 陈鹏¹, 李康璐¹, 董帆^1,2, 王法理³

1 电子科技大学环境与能源催化研究中心,成都 610000
2 电子科技大学长三角研究院(湖州),湖州 313000
3 重庆市万盛经济技术开发区生态环境监测站,重庆 400800

Photocatalytic Degradation for Benzene Series in Wide-band Gap Metal Oxide: Reaction Mechanism and Modification Strategies

CHEN Lyucun^1,2, CUI Wen¹, CHEN Peng¹, LI Kanglu¹, DONG Fan^1,2, WANG Fali³

1 Center of Environmental and Energy Catalysis, University of Electronic Science and Technology of China, Chengdu 610000, China
2 Yangtze Delta Region Institute (Huzhou),University of Electronic Science and Technology of China, Huzhou 313000, China
3 Ecological Environment Monitoring Station of Chongqing Wansheng Economic and Technological Development Zone, Chongqing 400800, China

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摘要苯系物广泛存在于水体和大气环境中,难降解和高毒性的特点使其对人体健康和生态环境产生严重威胁。光催化技术因具有反应条件温和、氧化还原能力强、绿色无二次污染等特点而备受关注,可用于污染物降解、能源转化,尤其对于难降解苯系物的治理具有显著优势。
宽带隙光催化剂具有价带位置更正、氧化能力强、光化学稳定性高和造价低等特性,在苯系物降解中发挥了重要作用,被广泛应用于苯系物等难降解污染物的治理。但宽带隙光催化剂光响应范围有限、表面电势高和光生电子空穴对难以分离等特点,限制了其在实际治理工艺中的应用。另外,苯系物种类繁多、结构复杂,以及当前原位表征技术尚未普及等因素,导致对苯系物的转化机理和开环机理的认识不足,制约了高效治理苯系物光催化剂的设计制备和光催化技术在治理苯系物方面的实际应用。
基于以上问题,本文围绕宽带隙光催化氧化技术在苯系物降解中的重要进展,介绍了光催化降解苯系物的反应机理、宽带隙半导体性能影响因素,总结了宽带隙光催化剂改性策略的最新进展并分析了其形成机制和促进光催化苯系物降解的作用机理,最后针对宽带隙光催化剂降解反应机理的研究、提高降解效率和实际应用等方面提出了展望。

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关键词: 苯系物光催化宽带隙反应机理改性策略

Abstract: Benzene compounds are widely present in water bodies and atmospheric environments, and their refractory and highly toxic characteristics pose a serious threat to human health and the ecological environment. Photocatalytic technology has attracted much attention in pollutant degradation and energy conversion because of mild reaction conditions, strong redox ability, and green and no secondary pollution, especially for the treatment of refractory benzene series.
The advantages of positive valence band position, strong oxidation ability, high photochemistry stability and lower cost on wide-band gap photocatalysts play important role in benzene series degradation. However, wide band gap photocatalysts have limited photo-response range, higher surface potential and difficult separation of photo-generated electron-hole pairs, which limit their application in actual treatment processes. In addition, the effects of wide variety of benzene series, complex structure, and the current in-situ characterization technology limited the understanding of the conversion and ring opening mechanism of benzene series. That restricts the design and preparation for efficient photocatalysts and photocatalytic technology for the practical application in benzene treatment.
This review focuses on the important progress about wide-band gap photocatalytic oxidation technology in the degradation of benzene series, and introduces the latest developments about the reaction mechanism of photocatalytic benzene series degradation, the performance influencing factors of wide-band gap semiconductors, and the modification strategies on wide-band gap semiconductors. Finally, the prospects in reaction mechanism research, degradation efficiency enhancement and practical application are put forward.

Key words: benzene series photocatalysis wide band gap reaction mechanism modification strategies

出版日期: 2021-11-10 发布日期: 2021-11-30

ZTFLH:

X511

基金资助: 国家自然科学基金(21822601;22006009);四川省科技创新苗子工程资助项目(2021077);重庆市科委基金(cstc2019jscx-msxmX0374)

通讯作者: dfctbu@126.com

作者简介: 陈侣存,2021年6月毕业于西南石油大学,获得工学博士学位。现为电子科技大学材料科学与工程博士后,在合作导师董帆教授的指导下开展研究工作。主要研究VOCs催化治理技术及反应机理。近年来,在光催化环境和能源领域发表论文11篇,包括Applied Catalysis B: Environmental, ACS Applied Mate-rials & Interface, Science Bulletin, Energy & Environmental Materials等。
董帆,电子科技大学基础与前沿研究院教授,博士研究生导师。2010年6月毕业于浙江大学,获得环境工程工学博士学位,香港理工大学访问学者。从事研究领域包括:环境与能源催化材料、光电催化与能源转化、气体传感材料与器件和材料模拟计算等。入选国家青年人才(2018年)、国家优秀青年科学基金获得者(2018年)、国务院政府特殊津贴专家(2019年)、四川省特聘专家(2019年)、四川省杰青青年科技人才(2020年)、科睿唯安“全球高被引科学家”和Elsevier“中国高被引学者” (2018—2020年)等。在ACS Nano、ACS Catalysis、Environmental Science & Technology、Materials Today、Nano Energy、Angewandte Chemie、Applied Catalysis B: Environmental、Journal of Catalysis、Science Bulletin、Advanced Materials和Advanced Functional Materials等期刊上发表SCI论文300余篇,被SCI引用22000余次,H index为78。有55篇论文入选全球ESI高被引用/热点论文,1篇论文入选2015年中国百篇最具影响力国际学术论文。申请国家发明专利30项,其中已获得发明专利授权20项。目前担任Chinese Chemical Letters副主编,Science Bulletin、Chinese Journal of Catalysis、 ACS ES&T Enginee-ring、《物理化学学报》等SCI期刊的编委和Frontiers in Environmental Chemistry专业主编。

引用本文:

陈侣存, 崔雯, 陈鹏, 李康璐, 董帆, 王法理. 宽带隙金属氧化物材料光催化降解苯系物:反应机理和改性策略[J]. 材料导报, 2021, 35(21): 21001-21011.
CHEN Lyucun, CUI Wen, CHEN Peng, LI Kanglu, DONG Fan, WANG Fali. Photocatalytic Degradation for Benzene Series in Wide-band Gap Metal Oxide: Reaction Mechanism and Modification Strategies. Materials Reports, 2021, 35(21): 21001-21011.

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http://www.mater-rep.com/CN/10.11896/cldb.21090250 或 http://www.mater-rep.com/CN/Y2021/V35/I21/21001

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