Abstract: Environmental pollution and energy shortage are the two major problems that need to be solved urgently in the 21st century. Solar energy is inexhaustible energy, how to use solar energy to control environmental pollution and alleviate energy shortage has become the focus. Bismuth vanadate (BiVO4) is a promising solar-driven semiconductor photocatalyst due to its low cost, non-toxicity, high photostability, narrow band gap, good response to visible light, and has become a hotspot in photocatalyst field. Among the three crystal types of BiVO4, the monoclinic phase BiVO4 exhibits the best photoactivity due to the smaller band gap and special electronic structure. However, the fast recombination of photoinduced carriers of pure BiVO4 as a result of narrow energy gap, coupled with its low adsorption and small specific surface area, limit the improvement of photocatalytic performance and practical application. In order to improve the visible light photocatalytic activity of BiVO4, researchers mainly focus on modifying BiVO4 from two aspects including the controlled synthesis of BiVO4 micro/nanostructure so as to improve the specific surface area and adsorption, as well as the conductivity of photogenerated carriers or constructing composite materials to promote the separation of photogenerated electron-hole pairs, thus reduce their recombination probability, further broaden the visible light response range and improve the adsorption and stability of materials, etc. The research has achieved encouraging results. At present, the photocatalytic efficiency of bismuth vanadate material has been improved greatly. This article provides a review on the recent advances of bismuth vanadate photocatalytic materials based on different modification methods, including the controlled synthesis of BiVO4 micro/nanostructure, noble metal deposition, element doping, semiconductor coupling, and BiVO4 loa-ding, which mainly focus on the application of the materials in the degradation of toxic organic pollutants in wastewater, hydrogen production from water splitting, CO2 reduction and organic synthesis, etc. Finally, some problems that need to be solved and the future development direction are pointed out, so as to provide a reference for the development of stable and efficient BiVO4 photocatalytic materials.
刘景景, 张泽兰, 李诗, 刘宇, 杨佩佩, 李兴. 钒酸铋可见光催化材料的改性研究进展[J]. 材料导报, 2021, 35(17): 17163-17177.
LIU Jingjing, ZHANG Zelan, LI Shi, LIU Yu, YANG Peipei, LI Xing. Research Progress on Modification of Bismuth Vanadate Visible Light Photocatalytic Materials. Materials Reports, 2021, 35(17): 17163-17177.
1 Fujishima A, Honda K.Nature, 1972, 238(5358), 37. 2 Carey J H, Lawrence J, Tosine H M.Bulletin of Environmental Contamination and Toxicology, 1976, 16(6), 697. 3 Koe W S, Lee J W, Chong W C, et al.Environmental Science and Pollution Research, 2020, 27, 2522. 4 Liu S X, Liu H.Foundation and application of photocatalysis and photoelectric catalysis, Chemical Industry Press, China, 2006(in Chinese). 刘守新, 刘鸿.光催化及光电催化基础与应用, 化学工业出版社, 2006. 5 Monfort O, Plesch G.Environmental Science and Pollution Research, 2018, 25, 19362. 6 Tahir M, Tasleem S, Tahir B.International Journal of Hydrogen Energy, 2020, 45(32), 15985. 7 Malathi A, Madhavan J, Ashokkumar M, et al.Applied Catalysis A: Ge-neral, 2018, 555, 47. 8 Chen S, Huang D L, Xu P, et al.ACS Catalysis, 2020, 10(2), 1024. 9 Wang Z L, Huang X L, Wang X S. Catalysis Today, 2019, 335,31. 10 Tayebi M, Lee B K.Renewable and Sustainable Energy Reviews, 2019, 111, 332. 11 Liu X T, Gu S N, Zhao Y J, et al.Journal of Materials Science & Technology, 2020, 56, 45. 12 Matavos-Aramyan S, Soukhakian S, Jazebizadeh M H, et al.Applied Materials Today, 2020, 18, 100499. 13 KudoA, Ueda H K, Mikami I. Catalysis Letters, 1998, 53(3-4), 229. 14 Kudo A, Omori K, Kato H. Journal of the American Chemical Society, 1999, 121(49), 11459. 15 Tokunaga S, Kato H, Kudo A.Chemistry of Materials, 2001, 13(12), 4624. 16 Roth R S, Waring J L.American Mineralogist, 1963, 48, 1348. 17 Wu Z S, Xue Y T, He X F, et al.Journal of Hazardous Materials, 2020, 387, 122019. 18 Lin Y, Lu C, Wei C Y.Journal of Alloys and Compounds, 2019, 781, 56. 19 Dabodiya T S, Selvarasu P, Murugan A V.Inorganic Chemistry, 2019, 58(8), 5096. 20 Deshpande N G, Ahn C H, Koli R R, et al.Applied Surface Science, 2020, 514, 146075. 21 Khan I,Khan A Z, Sufyan A, et al. Ultrasonics-Sonochemistry, 2020, 68, 105233. 22 Samsudin M F R, Bashiri R N, Mohamed M, et al.Applied Surface Science, 2020, 504, 144417. 23 Corradini P G, Brito J F D, Zanoni M V B, et al.Journal of CO2 Utilization, 2020, 36, 187. 24 Shi C J, Dong X L, Wang X Y, et al.Chinese Journal of Catalysis, 2018, 39, 128. 25 Souza J S, Hirata F T H, Corio P.Journal of Nanoparticle Research, 2019, 21, 35. 26 Wang L Y, Bian Z Y. Chemosphere, 2020, 239, 124815. 27 Teng H H, Qin L L, Gao Z, et al.Liaoning Chemical Industry, 2019, 48(4), 328(in Chinese). 滕洪辉, 秦丽丽, 高泽, 等.辽宁化工, 2019, 48(4), 328. 28 Regmi C, Kshetri Y K, Pandey R P, et al.Journal of Environmental Sciences, 2019, 75, 84. 29 Zhu Z, Yang C X, Hwang Y T, et al.Materials Research Bulletin, 2020, 130, 110955. 30 Nguyen T D, Bui Q T P, Le T B, et al.RSC Advances, 2019, 9, 23526. 31 Tian X, Zhu Y, Zhang W, et al.Journal of Materials Science: Materials in Electronics, 2019, 30, 19335. 32 Chen Y S, Lin L Y, Lin H Y.International Journal of Hydrogen Energy, 2020, 45, 667. 33 Chen Y S, Lin LY, Ma J S.Electrochimica Acta, 2020, 329, 135171. 34 Saxena S, Verma A, Asha K, et al.International Journal of Hydrogen Energy, 2020, 45(51), 26746. 35 Pei Z Z, Jia H, Zhang Y L, et al.Journal of Nanoscience and Nanotech-nology, 2020, 20, 3053. 36 Regmi C, Kshetri Y K, Kim T H, et al.Molecular Catalysis, 2019, 470, 8. 37 Sudrajat H, Hartuti S.Research on Chemical Intermediates, 2019, 45, 2179. 38 Qin C, Liao H R, Rao F Y, et al.Solid State Sciences, 2020, 105, 106285. 39 Yang R J, Fan Y Y, Zhu R S.Materials Research Bulletin, 2020, 124, 110756. 40 Liu T, Tan G, Zhao C, et al.Applied Catalysis B: Environmental, 2017, 213, 87. 41 Zhang K F, Liu Y X, Deng J G, et al.Applied Catalysis B: Environmental, 2018, 224, 350. 42 Tayebi M, Lee B K.Catalysis Today, 2021, 361,183. 43 Xue S, He H, Wu Z et al. Journal of Alloys and Compounds, 2017, 694, 989. 44 Lv Y R, Liu C J, He R K, et al. Materials Research Bulletin, 2019, 117, 35. 45 Ma C Q, Wei M Z.Materials Letters, 2020, 259, 126849. 46 Li Z L, Jin C Y, Wang M, et al.Separation and Purification Technology, 2020, 232, 115937. 47 Lu M F, Li Q Q, Zhang C L, et al.Carbon, 2020, 160, 342. 48 Li S Y, Jiang Y, Jiang W C, et al.Applied Surface Science, 2020, 523, 146441. 49 Liu Y, Yuan A L, Xiao Y F, et al.Ceramics International, 2020, 46(10), Part B, 16157. 50 Ng L K S, Tan E J C, Goh T W, et al.Applied Materials Today, 2019, 15, 192. 51 Ye Z H, Xiao X Y, Chen J Y, et al.Journal of Photochemistry and Photobiology A: Chemistry, 2019, 368, 153. 52 Singh G, Vaish R.Materials Chemistry and Physics, 2020, 240, 122238. 53 Baral B, Reddy K H, Parida K M.Journal of Colloid and Interface Science, 2019, 554, 278. 54 Zhao W, Feng Y, Huang H B, et al.Applied Catalysis B: Environmental, 2019, 245, 448. 55 Lai C, Zhang M M, Li B S, et al.Chemical Engineering Journal, 2019, 358, 891. 56 Soltani T, Tayyebi A, Lee B K.Catalysis Today, 2020, 340, 188. 57 Huang J W, Liu T T, Wang R F, et al. Journal of Colloid and Interface Science, 2020, 570, 89. 58 Xu D B, Xia T, Xu H M, et al.Chemical Engineering Journal, 2020, 392, 124838. 59 Li F, Leung D Y C.Chemical Engineering Science, 2020, 211, 115266. 60 Zhao H, Zalfani M, Li C F, et al.Journal of Colloid and Interface Science, 2019, 539, 585. 61 Li H L, Chen Y J, Zhou W, et al.Journal of Alloys and Compounds, 2019, 802, 76. 62 Omrani N, Nezamzadeh-Ejhieh A.Journal of Photochemistry and Photo-biology A: Chemistry, 2020, 389, 112223. 63 Wang D D, Li J, Xu Z F, et al.Journal of Colloid and Interface Science, 2019, 533, 344. 64 Wang Y L, Yu D, Wang W, et al.Separation and Purification Technology, 2020, 239, 116562. 65 Fakhravar S, Farhadian M, Tangestaninejad S.Applied Surface Science, 2020, 505, 144599. 66 Chen S, Huang D L, Zeng G M, et al.Chemical Engineering Journal, 2020, 382, 122840. 67 Zhao W, Zhang J, Zhu F X, et al.Chemical Engineering Journal, 2019, 361, 1352. 68 Chen F F, Wu C Y, Wang J N, et al.Applied Catalysis B: Environmental, 2019, 250, 31. 69 Zou L, Wang H R, Wu C, et al.Applied Surface Science, 2019, 498, 143900. 70 Xue Y T, Wu Z S, He X F, et al.Journal of Colloid and Interface Science, 2019, 548, 293. 71 Mandari K K, Do J Y, Pandey S, et al.Materials Research Bulletin, 2020, 122, 110695. 72 Li M, Xu G H, Guan Z Y.Science of The Total Environment, 2019, 664, 230. 73 Garza-Galván M D L, Zambrano-Robledo P, Vazquez-Arenas J.Applied Surface Science, 2019, 487, 743. 74 Song M T, Wu Y H, Zheng G P, et al.Applied Surface Science, 2019, 498, 143808. 75 Zhang G C, Zhong J L, Xu M, et al.Chemical Engineering Journal, 2019, 375, 122093. 76 Shi Q J, Li Z J, Chen Lu, et al.Applied Catalysis B Environmental, 2019, 244, 641. 77 Samsudin M F R, Jayabalan P J, Ong W J, et al.Journal of Photochemistry and Photobiology A: Chemistry, 2019, 378, 46. 78 Zhang M, Piao C C, Wang D, et al.Separation and Purification Techno-logy, 2020, 231, 115890. 79 Liang M J, Deng N, Xiang X Y, et al.Chinese Journal of Inorganic Chemistry, 2019, 35(2), 263(in Chinese). 梁梦君, 邓楠, 向心怡, 等.无机化学学报, 2019, 35(2), 263. 80 Claudino C H, Kuznetsova M, Rodrigues B S, et al.Materials Research Bulletin, 2020, 125, 110783. 81 Wang Y L, Ding K, Xu R, et al.Journal of Cleaner Production, 2020, 247, 119108. 82 Li Y, Xiao X Y, Ye Z H.Applied Surface Science, 2019, 467-468, 902. 83 Huang Z Y, Dai X D, Huang Z J, et al.Chemosphere, 2019, 221, 824. 84 Raja A, Rajasekaran P, Selvakuma K.Separation and Purification Technology, 2020, 233, 115996. 85 Li J L, Wang Q M, Zhang Y J, et al.Solid State Sciences, 2020, 104, 106200. 86 Samsudin M F R, Sufian S.Journal of Molecular Liquids, 2020, 314, 113530. 87 Liu C, Zhang X, Li W, et al.Materials Research Bulletin, 2020, 122, 110640. 88 Lin X, Liu C, Wang J B, et al.Separation and Purification Technology, 2019, 226, 117. 89 Yuan X Z, Zhang J, Yan M.Journal of Colloid and Interface Science, 2019, 541, 123. 90 Zhou T, Chen S, Wang J, et al.Chemical Engineering Journal, 2021, 403, 126350. 91 Samsudin M F R, Bacho N, Sufian S, et al. Journal of Molecular Liquids, 2019, 277, 977. 92 Gangu K K, Maddila Suresh, Jonnalagadda S B.Science of The Total Environment, 2019, 646, 1398. 93 Ran J H, Bi S G, Jiang H Y, et al.Cellulose, 2019, 26, 6259.94 Ran J H, Chen H B, Bai X, et al.Applied Surface Science, 2019, 493, 1167. 95 Han N, Zhao S, Chen Z L, et al.Journal of the Chinese Ceramic Society, 2019, 47(7), 924(in Chinese). 韩娜, 赵帅, 陈政利, 等.硅酸盐学报, 2019, 47(7), 924. 96 Wang T, Liu X Q, Han D L, et al.International Journal of Hydrogen Energy, 2019, 44, 31969. 97 Tavker N, Gaur U, Sharma M.Journal of Environmental Chemical Engineering, 2020, 8, 104027.