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材料导报  2021, Vol. 35 Issue (4): 4023-4027    https://doi.org/10.11896/cldb.19080024
  无机非金属及其复合材料 |
亲水性PVDF/TiO2复合薄膜的制备及光催化性能
于翔1, 桂久青1, 宋子豪1, 张雪寅1, 董献辉1, 李玥1, 张雅琪2
1 河南工程学院材料工程学院,郑州 450007
2 天津工业大学材料科学与工程学院,天津 300387
Investigation of Preparation and Photocatalytic Properties of Hydrophilic PVDF/TiO2 Composite Membranes
YU Xiang1, GUI Jiuqing1, SONG Zihao1, ZHANG Xueyin1, DONG Xianhui1, LI Yue1, ZHANG Yaqi2
1 Department of Material Engineering, Henan University of Engineering, Zhengzhou 450007, China
2 College of Materials Science and Engineering, Tiangong University, Tianjin 300387, China
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摘要 本实验采用平板刮膜法制备PVDF/TiO2复合薄膜,再通过超声清洗致孔剂并改变其亲水性,然后对样品薄膜的微观形貌、力学性能、光催化性能等进行研究与分析。研究发现:PVDF/TiO2复合薄膜的拉伸强度和光催化降解能力均随着TiO2的加入呈现先增后减的趋势,在TiO2添加量为10%时,其复合薄膜的拉伸强度达到最大值,光催化降解能力最优,并且样品薄膜的光催化降解符合准一级动力学方程。随着超声时间的延长,样品薄膜的亲水性变差,但其仍为亲水性薄膜,光催化降解率先增后减,且当超声时间为3 h时,光催化降解率达到最大值。
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于翔
桂久青
宋子豪
张雪寅
董献辉
李玥
张雅琪
关键词:  复合薄膜  光催化  亲水性  聚偏氟乙烯(PVDF)    
Abstract: In this study, PVDF/TiO2 composite membranes were prepared via solution scraping method and ultrasonic cleaning which can drill and change its hydrophilic. Micromorphology, mechanical properties and photocatalytic properties of PVDF/TiO2 composite membranes were studied and analyzed. The results show that: the tensile strength and photocatalytic degradation ability of samples increase at first and then get worse with increasing of TiO2, and they simultaneously reach the maximum when addition of 10% TiO2. Furthermore, the photocatalytic degradation of samples conforms to the first-order kinetic models. Moreover, with the increment of ultrasonic time, the sample membranes are becoming less hydrophilic but they are still hydrophilic membranes, and their photocatalytic degradation rate increases first and then decreases. Further, when the ultrasonic time is 3 h, the photocatalytic degradation rate reaches the extreme value.
Key words:  composite membranes    photocatalysis    hydrophilicity    poly(vinylidenefluoride) (PVDF)
               出版日期:  2021-02-25      发布日期:  2021-02-23
ZTFLH:  TB324  
基金资助: 国家自然科学基金(51608175);河南省高校科技创新人才培养计划(20HASTIT016);河南省重点科技攻关项目(202102310605)
通讯作者:  yxpolymer@sina.com;liyue0128@163.com   
作者简介:  于翔,河南工程学院材料工程学院,副教授。2010年12月毕业于郑州大学,获高分子化学与物理专业博士学位。同年加入河南工程学院材料与化学工程学院工作至今,主要从事功能高分子复合材料、3D打印材料和光催化材料的开发、制备与表征等方面的研究。主持与参与国家自然科学基金、河南省科技厅、河南省教育厅及横向合作项目10余项,在国内外重要期刊发表论文70余篇,授权发明专利40余项。
李玥,河南工程学院化工与印染工程学院,副教授。2014年6月毕业于湖南大学,获得化学工程与技术专业博士学位。2019年6月至2020年8月在美国辛辛那提大学进行访学工作。主要从事环境能源功能材料的开发和利用、重金属离子无毒化处理等方面的研究。主持国家自然科学基金青年基金、河南省高校科技创新人才支持计划、河南省科技攻关、河南省教育厅高等学校重点科研等项目,累计发表学术论文40余篇,授权发明专利7项。
引用本文:    
于翔, 桂久青, 宋子豪, 张雪寅, 董献辉, 李玥, 张雅琪. 亲水性PVDF/TiO2复合薄膜的制备及光催化性能[J]. 材料导报, 2021, 35(4): 4023-4027.
YU Xiang, GUI Jiuqing, SONG Zihao, ZHANG Xueyin, DONG Xianhui, LI Yue, ZHANG Yaqi. Investigation of Preparation and Photocatalytic Properties of Hydrophilic PVDF/TiO2 Composite Membranes. Materials Reports, 2021, 35(4): 4023-4027.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19080024  或          http://www.mater-rep.com/CN/Y2021/V35/I4/4023
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