Research Status and Prospect of Organic-Inorganic Compound Modified Fast-growing Wood
SUN Zhenyu1, ZHANG Yuan1, ZUO Yingfeng1, WU Yiqiang1, WANG Zhangheng1, LYU Jianxiong1,2
1 College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China 2 Research Institute of Wood Industry, Chinese Academy of Forest, Beijing 100091, China
Abstract: Wood as a natural renewable resource is widely used in various fields. In recent years, with the increasing demand for wood and the shortage of natural forest resources, fast-growing wood as a substitute for hard wood has attracted more and more attention. However, due to its shortcomings such as low density, loose texture and poor mechanical properties, which is difficult to be used in high value-added products, so it needs to be modified and reinforce to increase the basic performance. Based on the large number of pores and active functional groups of fast-growing wood, the impregnation modification can not only improve the density and mechanical strength, but also add the new functions, so as to enhance the use value. According to the difference of impregnating liquid, traditional impregnation can be divided into organic and inorganic methods, but both of them have some shortcomings. The organic resin used in organic modified liquid impregnation can occur a cross-linking with the active functional groups of wood to form a compact structure, but most of the organic resin contains volatile toxic substances such as free formaldehyde, which will cause harm to the environment and human health. Although inorganic modifier is non-toxic and environment-friendly, most of them are difficult to form a stable structure in the wood, easy to occur the phenomenon of loss and moisture absorption, which affects the use function. Organic-inorganic composite modification is a new material composite technology, which combines the advantages of organic and inorganic materials. While reducing the amount of organic resin, the covering action (or bonding) of the organic resin was used to fix the inorganic modifier to reduce the loss. In addition, the organic resin can form a stable bond with the wood. Therefore, under the synergetic effects of organic and inorganic materials, the properties of the modified wood can be greatly improved, and the practical value and application fields can be expanded. In this paper, the research status of organic-inorganic compound modification fast-growing wood is taken as the theme, and the inorganic components such as silicon, boron, copper, calcium and montmorillonite are used as the main line, the research progress is described in detail, and the modification mechanism is also summarized. Meanwhile, the development trend is put forward from the aspects of basic theories, preparation technologies, basic properties and economic costs, and the aim is to promote the application of organic-inorganic compound ways in the modification of fast-growing wood.
1 National Forestry and Grassland Administration. China forest resources report(2014-2018), China,2019(in Chinese). 国家林业和草原局.中国森林资源报告(2014-2018),2019. 2 Lang Q. Research on properties and mechanism of fast-growingpoplar and ailanthus treated by multi-functional modifier. Ph.D. Thesis, Beijing Forestry University,China,2016(in Chinese). 郎倩.复合改性剂对速生杨木和椿木改性效应及机理研究.博士学位论文,北京林业大学,2016. 3 Huang Y,Li G. Wood Science and Technology,2019,53,1051. 4 Dong Y M, Yan Y T, Zhang Y, et al. Wood Science and Technology,2016,50(3),503. 5 Gong M X, Cheng R X, Song Y T, et al. Forest Engineering,2013,29(1),65(in Chinese). 龚明星,程瑞香,宋羿彤,等.森林工程,2013,29(1),65. 6 Li Y F. Study of wood-organic-inorganic hybrid nanocomposites. Ph.D. Thesis, Northeast Forestry University, China,2012(in Chinese). 李永峰.木材-有机-无机杂化纳米复合材料研究.博士学位论文,东北林业大学,2012. 7 Rahman M R, Hamdan S. Wood Polymer Nanocomposites, Engineering Materials,2018,6,37. 8 Li M L, Li N L, Shan J C, et al. China Wood-Based Panels,2019,26(5),1. 李美玲,李南,单家成,等.中国人造板,2019,26(5),1. 9 Dong Y M, Zhang S F, Li J Z. Journal of Forestry Engineering,2017,2(4),34(in Chinese). 董友明,张世锋,李建章.林业工程学报,2017,2(4),34. 10 Wang Z, Wang X M. Scientia SilvaeSinicae,2014,50(10),123(in Chinese). 王哲,王喜明.林业科学,2014,50(10),123. 11 Jang E S, Kang C W. Journal of Wood Science,2019,65(1),1. 12 Zhou Y, Li P, Zuo Y F, et al. Maerials Report A: Review Papers,2019,33(9),2989(in Chinese). 周亚,李萍,左迎峰,等.材料导报:综述篇,2019,33(9),2989. 13 Ding Z, Li H, Wei J. Materials Science and Engineering: C,2018,87(1),104. 14 Samir E H, Mosto B, Abdelkrim E K. Progress in Materials Science,2019,106(12),100579. 15 Papadopoulos A N, Bikiaris D N, Mitropoulos A C. Nanomaterials,2019,9(4),607. 16 Hadi A, Omid S. The European Physical Journal Plus,2019,134,459. 17 Abdurrahman K, Mehmet N Y, Sekip S Y. Turkish Journal of Forestry,2019,20(1),50. 18 Wang Q, Guo H X,Li Y Q, et al. Chemical Research and Application,2006,18(8),939(in Chinese). 王群,郭红霞,李永卿,等.化学研究与应用,2006,18(8),939. 19 Yan Y T,Dong Y M,Li J Z,et al. RSC Advances,2015,5(67),54148. 20 Wang Z H. Research and application of hydrophobic wood for bathroomfurniture. Master’s Thesis,Central South University of Forestry and Technology, China,201(in Chinese). 王张恒.面向卫浴家具的疏水木材研究.硕士学位论文,中南林业科技大学,2019. 21 Wang J X. Journal of Liaoning Forestry Science & Technology,2017(2),1(in Chinese). 王敬贤.辽宁林业科技,2017(2),1. 22 Dong Y M, Yan Y T, Zhang S F, et al. European Journal of Wood and Wood Products,2015,73(4),457. 23 Shi Y, Liu J L, Lv W H, et al. China Wood Industry,2019,33(1),21(in Chinese). 石媛,刘君良,吕文华,等.木材工业,2019,33(1),21. 24 Chou H B. Study on in-situ enhancement of plantation poplar wood with water soluble monomers. Ph.D. Thesis, Chinese Academy Forestry, China,2018(in Chinese). 仇洪波.水溶性单体原位增强速生杨木及其机制研究.博士学位论文,中国林业科学研究院,2018. 25 Xu J J. Study on combustion properties of themromoset resins and silica sols modified wood. Master’s Thesis, Northeast Forestry University, China,2016(in Chinese). 徐杰杰.热固性树脂和硅溶胶处理木材的燃烧性能研究.硕士学位论文,东北林业大学,2016. 26 Sun K, Xu Z H, Zhang H, et al. Journal of Green Science and Technology,2019(12),224(in Chinese). 孙珂,徐子涵,张贺,等.绿色科技,2019(12),224. 27 He S, Wu W, Zhang M. Journal of Thermal Analysis and Calorimetry,2011,11,825. 28 Zhang Y J, Lin L Y, Fu F. China Wood Industry,2015,29(4),36(in Chinese). 张彦娟,林兰英,傅峰.木材工业,2015,29(4),36. 29 Tan H F, Guo H X, Du W L, et al. China Wood Industry,2009,23(4),40(in Chinese). 谭惠芬,郭红霞,杜万里,等.木材工业,2009,23(4),40. 30 Sun Z Q. Ceramic Wood Prepared by silica sol/styr-ene-acrylic emulsion system. Master’s Thesis,Beijing University of Technology,China,2004(in Chinese). 孙正强.硅溶胶/苯丙乳液改性体系的陶瓷复合木材.硕士学位论文,北京工业大学,2004. 31 Wang W. Fast-growing poplar wood modified with silica sol/VAE. Master’s Thesis,Central South University of Forestry and Technology, China,2014(in Chinese). 王薇.硅溶胶-VAE改性速生杨木的研究.硕士学位论文,中南林业科技大学,2014. 32 Wang F Q, Sui F, Liao H, et al. Fire Science and Technology,2014,6,688(in Chinese). 王奉强,隋芳,廖恒,等.消防科学与技术,2014,6,688. 33 Wang F, Chai Y B, Liu J L. Wood Processing Machinery,2016,27(4),33(in Chinese). 王飞,柴宇博,刘君良.木材加工机械,2016,27(4),33. 34 Xu C L, Guo H X,Lin L Y, et al. Chemical Research and Application,2010,22(2),240(in Chinese). 徐春利,郭红霞,林兰英,等.化学研究与应用,2010,22(2),240. 35 Chen H Y, Lang Q, Bi Z, et al. Holzforschung,2014,4,1. 36 Nguyen T T, Xiao Z, Che W, et al. Journal of Wood Science,2019,65,2. 37 MihaelaP, Alexander P. Fire and Materials,2019,10,1. 38 Yu L P. Selection of anti-leaching boron-based preservative formulas and properties of wood treated with optimized formulas. Ph.D. Thesis, Beijing Forestry University, China,2009(in Chinese). 余丽萍.抗流失硼基木材防腐剂配方遴选及优选配方处理材的性能.博士学位论文,北京林业大学,2009. 39 Chai Y B, Liu J L, Sun B L, et al. China Wood Industry,2015,29(3),5(in Chinese). 柴宇博,刘君良,孙柏玲,等.木材工业,2015,29(3),5. 40 Chai Y B, Liu J L, Zhen X. Advanced Materials Research,2011,341,80. 41 Wang F, Liu J L,Lv W H. Fire and Materials,2017,41(8),1051. 42 Wang F. Properties and mechanism of Chinese fir modified by phenol melamine urea formaldehyde resin and borates. Ph.D. Thesis, Chinese Academy of Forestry, China,2018(in Chinese). 王飞.PMUF树脂复配硼化物改性杉木及其机理研究.博士学位论文,中国林业科学研究院,2018. 43 Yue K, Chen Z J, Construction and Building Materials,2017,154,956. 44 Yue K, Wu G H, Xu L Q, et al. Construction and Building Materials,2020,241,118101. 45 Jiang H, Kamdem D. Wood Science and Technology,2007,41(8),637. 46 Dong W R, Xu M. Journal of Forestry Engineering,2019,4(1),39(in Chinese). 东婉茹,许民.林业工程学报,2019,4(1),39. 47 Peng Y, Ma K, Long G, et al. Materials,2019,12,5298. 48 Zhang N N. The structural characterization and mechanism analysis of nanoCaCO3/common Chinese fir composites. Master’s Thesis,Central South University of Forestry and Technology, China,2012(in Chinese). 张南南.杉木-纳米碳酸钙复合材料结构表征及机理分析.硕士学位论文,中南林业科技大学,2012. 49 Jia Z. The study of nano-CaCO3/fast-growing poplar composite and preparing building templates. Ph.D. Thesis, Northeast Forestry University, China,2012(in Chinese). 贾贞.纳米碳酸钙/速生杨木复合材料及制作建筑模板的研究.博士学位论文,东北林业大学,2012. 50 ChenG Z, Gao Z X, Ma H, et al. Journal of Northeast Forestry University,2013,41(4),108(in Chinese). 陈公哲,高正鑫,马骅,等.东北林业大学学报,2013,41(4),108. 51 Jiang J, Mei C, Pan M, et al. PolyerComposits,2019,10,1. 52 Moya R, Rodríguez Z A, Vega B, et al. International Journal of Adhesion & Adhesives,2015,59,62. 53 Antonios N P, Dimitrios N B, Athanasios C M. Nanomaterials,2019,9,607. 54 Hong X H,Cao J Z,Luo G Q. Chemistry and Industry of Forest Products,2011,31(1),41(in Chinese). 姜卸宏,曹金珍,罗冠群.林产化学与工业,2011,31(1),41. 55 Zhang J, Zhu C X, Wang K H. China Wood-Based Panels,2010,9,16(in Chinese). 张建,朱长庆,汪奎宏.中国人造板,2010,9,16. 56 Yu X C, Sun D L, Li X S. The Japan Wood Research Society,2011,57,501. 57 Yu X C, Sun D L, Li X S. Journal of Central South University of Forestry ＆ Technology,2011,31(1),109(in Chinese). 余先纯,孙德林,李湘苏.中南林业大学学报,2011,31(1),109. 58 Yu X C, Li X S, Gong Z W. New Chemical Materials,2011,39(9),125(in Chinese). 余先纯,李湘苏,龚铮午.化工新型材料,2011,39(9),125. 59 Wang W. Properties and characterization of thermally-modifies wood in combination with water repellent treatment. Ph.D. Thesis,Beijing Forestry University, China,2015(in Chinese). 王望.防水剂/高温热处理复合改性木材的性能与表征.博士学位论文,北京林业大学,2015.
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