金属有机框架材料在光催化还原CO2中的应用

doi:10.11896/cldb.20070204

材料导报

2021, Vol. 35

Issue (21): 21058-21070 https://doi.org/10.11896/cldb.20070204

环境催化材料

金属有机框架材料在光催化还原CO₂中的应用

张中伟¹, 郭瑞堂^1,2,3, 秦阳¹, 郭德宇¹, 潘卫国^1,2,3

1 上海电力大学能源与机械工程学院,上海 200090
2 上海发电环保工程技术研究中心,上海200090
3 机械工业清洁发电环保技术重点实验室,上海 200090

Application of Metal-Organic Framework in CO₂ Photocatalytic Reduction

ZHANG Zhongwei¹, GUO Ruitang^1,2,3, QIN Yang¹, GUO Deyu¹, PAN Weiguo^1,2,3

1 College of Energy and Mechanical Engineering, Shanghai University of Electric Power, Shanghai 200090, China
2 Shanghai Engineering Research Center of Power Generation Environment Protection, Shanghai 200090, China
3 Key Laboratory of Environmental Protection Technology for Clean Power Generation in Machinery Industry, Shanghai 200090, China

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摘要人类依靠化石燃料来加速现代社会的发展,但化石燃料的过度消耗引发了一系列问题,如严峻的能源危机和环境恶化。例如化石燃料的大量使用导致大气中二氧化碳的含量逐年增加,成为全球温室效应的主要原因。在众多CO₂减排的技术中,光催化还原CO₂技术不仅可以减少大气中的CO₂含量,而且还能通过太阳能将CO₂光催化转化为有价值的化学物质,被认为是最有发展前景的技术之一。
金属有机框架材料(Metal-organic frameworks, MOFs),也称为多孔配位聚合物,是具有周期性网状结构的三维多孔材料,由无机金属离子(或金属簇)和有机配体组成。MOFs具有大的比表面积、可调节的结构、丰富的催化活性位点、独特的电子能带结构,这些优点使其在光催化还原CO₂反应中受到越来越多科研工作者的青睐,应用前景令人看好。目前,用于光催化还原CO₂的MOFs材料主要包括单一MOFs光催化剂与基于MOFs的复合光催化剂两类。文章列举了具体实例来说明MOF基光催化材料在还原二氧化碳中的优势和独特性以及提高光催化活性的改进方法。
本文归纳了近年来MOF基光催化剂在光催化还原CO₂方面的研究进展,讨论了提高MOF基光催化剂(MOFs功能化、半导体/MOFs、光敏剂/MOFs、贵金属/MOFs)用于CO₂还原性能的合理方法,探讨了基于MOFs的光催化剂用于CO₂还原的挑战和展望。

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关键词: 催化剂金属有机框架光催化还原复合材料二氧化碳

Abstract: Although human beings rely on fossil fuels to accelerate the development of modern society, the over-use of fossil fuels has raised a series of problems such as tough energy crisis and environmental exacerbation. Excessive depletion of fossil fuels leads to the sharp increase of CO₂ content in the atmosphere, which is the main cause of the global greenhouse effect. Among the abundant technologies for reducing CO₂ emissions, the photocatalytic reduction of CO₂ technology not only reduces the CO₂ content in the atmosphere, but also converts CO₂ into valuable chemicals through solar energy, which is considered to be one of the most promising technologies.
Metal-organic frameworks (MOFs), also known as porous coordination polymers, are three-dimensional porous materials with a periodic network structure composed of inorganic metal ions (or metal clusters) and organic ligands. MOFs are particularly promising materials due to large surface area, adjustable structure, unique electronic band structures and abundant catalytic active sites, which make it more and more favored by researchers in the photocatalytic reduction of CO₂. At present, MOFs used for photocatalytic reduction of CO₂ mainly include single MOFs photocatalyst and composite photocatalyst based on MOFs. The article lists specific examples to illustrate the advantages and uniqueness of MOF-based photocatalytic materials in the reduction of CO₂ and modified methods to improve photocatalytic activity.
This review summarizes recent research progresses in MOF-based photocatalysts for photocatalytic reduction of CO₂. Besides, it discusses strategies in rational design of MOF-based photocatalysts (MOFs functionalization, semiconductor/MOFs, photosensitizer/MOFs and noble me-tal/MOFs) with enhanced performance on CO₂ reduction. Moreover, challenges and outlook on using MOFs-based photocatalysts for CO₂ reduction are also put forward.

Key words: catalyst metal-organic framework photocatalytic reduction composite materials carbon dioxide

出版日期: 2021-11-10 发布日期: 2021-11-30

ZTFLH:	O643.36
	O644.1

基金资助: 国家重点研发计划(2018YFB0605002);国家自然科学基金(21546014;50616114)

通讯作者: grta@zju.edu.cn;pweiguo@163.com

作者简介: 张中伟,2018年6月毕业于济南大学,获得工学学士学位。现为上海电力大学能源与机械工程学院硕士研究生,在郭瑞堂教授与潘卫国教授的指导下进行研究。目前主要研究领域为光催化还原二氧化碳。
郭瑞堂于浙江大学获得学士学位和博士学位。2015年,他在上海电力大学担任教授。他目前的主要研究方向是光催化还原二氧化碳、光
催化制氢和光催化有机污染物降解以及选择性催化还原脱硝技术。以第一作者和通讯作者身份公开发表学术论文90余篇,其中SCI检索60余篇。
潘卫国1997年于浙江大学取得博士学位,目前任能源与机械工程学院党委书记,兼任中国动力工程学会环保专委会主任委员。目前主要研究方向为能源清洁高效利用和光催化过程的能源转化与环境保护。主持并参与了国家“973”“863”、科技支撑计划、重点研发计划、国家自然科学基金。发表含ESI高被引论文、SCI论文在内的国内外学术论文160余篇,申请发明专利60余项。

引用本文:

张中伟, 郭瑞堂, 秦阳, 郭德宇, 潘卫国. 金属有机框架材料在光催化还原CO₂中的应用[J]. 材料导报, 2021, 35(21): 21058-21070.
ZHANG Zhongwei, GUO Ruitang, QIN Yang, GUO Deyu, PAN Weiguo. Application of Metal-Organic Framework in CO₂ Photocatalytic Reduction. Materials Reports, 2021, 35(21): 21058-21070.

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http://www.mater-rep.com/CN/10.11896/cldb.20070204 或 http://www.mater-rep.com/CN/Y2021/V35/I21/21058

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