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材料导报  2022, Vol. 36 Issue (20): 22070231-9    https://doi.org/10.11896/cldb.22070231
  新型环境功能材料 |
MIL-53(Al)基功能材料的制备及在水处理中的应用
孙雪梓1,2, 王崇臣1,2,*, 李渝航1,2
1 北京建筑大学建筑结构与环境修复功能材料北京市重点实验室,北京 100044
2 北京建筑大学环境与能源工程学院,北京 100044
Fabrication and Water Purification Applications of MIL-53(Al)-based Functional Materials: a Review
SUN Xuezi1,2, WANG Chongchen1,2,*, LI Yuhang1,2
1 Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation,Beijing University of Civil Engineering and Architecture, Beijing 100044, China
2 School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, Beijing 100044, China
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摘要 本文综述了MIL-53(Al)、NH2-MIL-53(Al)及其复合物的合成方法、形貌调控及作为荧光传感器、吸附剂和催化剂等在水体污染物传感检测、吸附和催化降解领域的应用的研究进展,系统介绍了利用水/溶剂热法、微波辅助法及室温搅拌法制备MIL-53(Al)、NH2-MIL-53(Al)及其复合物的反应条件、形貌调控及相关方法。MIL-53(Al)和NH2-MIL-53(Al)因在荧光传感检测过程中响应时间快、灵敏度高等特点,被广泛应用于各种污染物的传感检测。MIL-53(Al)和NH2-MIL-53(Al)因具有独特的“呼吸效应”,且具有较大的表面积、丰富的活性位点等特点而在吸附去除污染物方面具有良好的发展潜力。为进一步扩展其应用范围,引入第二组分与MIL-53(Al)、NH2-MIL-53(Al)复合,可加强MIL-53(Al)基功能材料对水体污染物传感检测、吸附和催化的性能。总之,MIL-53(Al)和NH2-MIL-53(Al)作为环境友好型环境功能材料将在水污染控制和修复领域展现出巨大的应用潜力。
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孙雪梓
王崇臣
李渝航
关键词:  MIL-53(Al)  水处理  传感  吸附  高级氧化  污染物    
Abstract: This paper reviews the fabrication strategies, morphology regulations and application (fluorescence sensors, adsorbents and photocatalysts for detecting and eliminating pollutants from water) of MIL-53(Al), NH2-MIL-53(Al) and their composites. The fabrication approaches like hydro/solvothermal methods, microwave-assisted synthesis and homogeneous phase direct synthesis along with the reaction conditions are introduced. MIL-53(Al) and NH2-MIL-53(Al) show excellent performance in detecting pollutants in water, with the characteristics of fast response time and high sensitivity. MIL-53(Al) and NH2-MIL-53(Al) can achieve adsorptive removal toward pollutants in water due to their ‘respiratory effect’, large surface area and rich active sites. The performance of MIL-53(Al) in adsorption, advanced oxidation degradation, sensing detection can be improved by compositing with other functional materials. In a word, MIL-53(Al) and NH2-MIL-53(Al), as environment-friendly environmental functional materials, show great application potential in water purification field.
Key words:  MIL-53(Al)    water purification    sensing    adsorption    advanced oxidation    pollutant
发布日期:  2022-10-26
ZTFLH:  X523  
基金资助: 国家自然科学基金(51878023);北京自然科学基金(8202016);北京市属高等学校长城学者培养计划 (CIT&TCD20180323);北京市百千万人才工程(2020A27)
通讯作者:  *chongchenwang@126.com   
作者简介:  孙雪梓,2021年6月于河北农业大学获得工学学士学位。现为北京建筑大学环境与能源工程学院研究生,在王崇臣教授的指导下进行研究。目前主要从事金属-有机骨架材料及衍生物/复合物的设计与可控制备及其环境应用研究。
王崇臣,北京建筑大学教授、博士研究生导师。于2000年在中南林学院获得学士学位,于2004年和2012年在北京化工大学获得硕士学位和博士学位。主要研究领域为环境功能材料。以金属-有机骨架(MOFs)材料为主开展水污染控制方面的研究工作。发表代表性论文100余篇,其中多篇ESI高被引论文和热点论文。
引用本文:    
孙雪梓, 王崇臣, 李渝航. MIL-53(Al)基功能材料的制备及在水处理中的应用[J]. 材料导报, 2022, 36(20): 22070231-9.
SUN Xuezi, WANG Chongchen, LI Yuhang. Fabrication and Water Purification Applications of MIL-53(Al)-based Functional Materials: a Review. Materials Reports, 2022, 36(20): 22070231-9.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22070231  或          http://www.mater-rep.com/CN/Y2022/V36/I20/22070231
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