球形气凝胶材料的研究进展

doi:10.11896/cldb.20040032

材料导报

2022, Vol. 36

Issue (8): 20040032-8 https://doi.org/10.11896/cldb.20040032

高分子与聚合物基复合材料

球形气凝胶材料的研究进展

江幸¹, 孔勇^1,2, 赵志扬¹, 沈晓冬^1,2

1 南京工业大学材料科学与工程学院,南京 210009
2 确成硅化学股份有限公司,江苏无锡 214196

Recent Advances in Spherical Aerogel Materials

JIANG Xing¹, KONG Yong^1,2, ZHAO Zhiyang¹, SHEN Xiaodong^1,2

1 College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China
2 Quecheng Silicon Chemical Co., Ltd., Wuxi 214196,Jiangsu, China

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摘要气凝胶具有纳米颗粒构成的三维纳米多孔网络结构,此结构赋予其低密度、大纳米孔体积和大比表面积等特性。气凝胶材料的典型形态有块体、薄膜、粉体、毡和板等,这些气凝胶材料可满足不同领域的应用需求。球形气凝胶作为一种新形态的气凝胶产品,表现出特殊的尺寸和形状特性,突破了其他形态气凝胶的应用局限,在催化、吸附、载药、储能等方面有良好的应用前景,近年来受到人们的广泛关注。本文综述了球形气凝胶材料的最新研究进展,重点介绍了球形二氧化硅、生物质、炭和石墨烯气凝胶材料的制备方法和性能,总结了球形气凝胶制备的一般方法和原则,展望了球形气凝胶的发展趋势和应用前景。

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	江幸
	孔勇
	赵志扬
	沈晓冬

关键词: 球形气凝胶乳液法球滴法吸附储能

Abstract: Aerogels have three-dimensional nanoporous network consisted of nanoparticles, which endows them with low densities, large pore volumes and specific surface areas. Aerogel products are usually in the form of monoliths, films, powders and sheets, which can meet the requirements of various applications. As a new form, the spherical aerogels exhibit special size and shape characteristics, which broaden the application of aerogel products. The spherical aerogels show promising applications in sorption, catalysis, drug delivery and energy storage, and have attracted intensively attention recently. In this paper, the latest research progresses of the spherical aerogels are reviewed. The preparation methods and properties of spherical silica, biomass, carbon and graphene aerogels are mainly introduced. The methodologies and principles to prepare the spherical aerogels are summarized. The developments and applications of the spherical aerogels are prospected.

Key words: spherical aerogel emulsion method ball dropping method sorption energy storage

出版日期: 2022-04-25 发布日期: 2022-04-27

ZTFLH:

TM911

基金资助: 中国博士后科学基金(2018T110490;2018M642228);江苏省自然科学基金(BK20211263)

通讯作者: ykong@njtech.edu.cn;xdshen@njtech.edu.cn

作者简介: 江幸,2018年6月毕业于湖北工程学院,获得工学学士学位。现为南京工业大学材料科学与工程学院硕士研究生,研究方向为球形二氧化硅气凝胶的制备与改性。
孔勇,副教授。2007年本科毕业于新疆大学化学化工学院,2014年博士毕业于南京工业大学材料科学与工程学院。2016年4月南京工业大学博士后出站后留校任教。主要从事气凝胶材料制备与应用研究,主持国家自然科学基金青年基金、江苏省自然科学基金青年基金、中国博士后基金(特别资助、面上项目)等项目8项。在Green Chemistry、Chemical Communications、Applied Energy、Chemical Engineering Journal等期刊发表论文30余篇,获授权发明专利10余项,获教育部技术发明奖二等奖1项。
沈晓冬,博士,教授,博士研究生导师,“973”项目首席科学家、“国家百千万人才工程”国家级人才,国务院特殊津贴获得者,现任南京工业大学材料科学与工程学院院长。兼任中国建材联合会科教委副主任、中国绝热节能材料协会副会长、首席专家、气凝胶分会会长,中国硅酸盐学会绝热分会副理事长、水泥分会副理事长,江苏省硅酸盐学会副理事长,南京硅酸盐学会理事长。在Advanced Materials、Energy & Environmental Science等期刊发表学术论文300余篇,授权中国发明专利40余项,美国、日本和欧洲等国际发明专利5项,主编专著5部。获得国家科技进步二等奖1项、中国建材科技一等奖1项、教育部技术发明、江苏省科学技术二等奖等7项。

引用本文:

江幸, 孔勇, 赵志扬, 沈晓冬. 球形气凝胶材料的研究进展[J]. 材料导报, 2022, 36(8): 20040032-8.
JIANG Xing, KONG Yong, ZHAO Zhiyang, SHEN Xiaodong. Recent Advances in Spherical Aerogel Materials. Materials Reports, 2022, 36(8): 20040032-8.

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http://www.mater-rep.com/CN/10.11896/cldb.20040032 或 http://www.mater-rep.com/CN/Y2022/V36/I8/20040032

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