利用碳纳米纤维/Pt纳米片构建柔性电极用于葡萄糖检测

doi:10.11896/cldb.21010143

材料导报

2022, Vol. 36

Issue (9): 21010143-6 https://doi.org/10.11896/cldb.21010143

无机非金属及其复合材料

利用碳纳米纤维/Pt纳米片构建柔性电极用于葡萄糖检测

张姣娇¹, 王晓君^2,*, 张卓雅¹

1 太原理工大学生物医学工程学院,山西晋中 030600
2 太原理工大学机械与运载工程学院,太原 030024

Construction of Flexible Electrode Using Carbon Nanofibers/Pt Nanosheets for Glucose Detection

ZHANG Jiaojiao¹, WANG Xiaojun^2,*, ZHANG Zhuoya¹

1 College of Biomedical Engineering, Taiyuan University of Technology, Jinzhong 030600, Shanxi, China
2 College of Mechanical and Vehicle Engineering, Taiyuan University of Technology, Taiyuan 030024, China

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摘要糖尿病是一种以高血糖为特征的代谢性疾病,严重威胁人类健康。血糖指标的监测在糖尿病的预防、诊断及治疗中发挥着重要作用。以聚丙烯腈为碳源,通过静电纺丝与热处理工艺制备了柔性碳纳米纤维膜,并利用恒电位电沉积法在自支撑碳纳米纤维膜上负载Pt纳米片构建柔性无酶葡萄糖传感器。结果表明,碳纳米纤维表面光滑,Pt纳米片逐渐生长并填满纳米纤维间隙,单个纳米片长100~200 nm,宽约100 nm。构建的柔性无酶葡萄糖传感器对葡萄糖的线性检测范围为7.5~87.5 mmol/L,灵敏度为6.41 μA·(mmol/L)^-1·cm^-2,最低检测限为14.04 μmol/L,同时传感器表现出良好的抗干扰性、重复性和稳定性。该柔性电极材料制备方法简单,结合柔性电极和无酶传感器的优势,避免传统酶传感器重复性、稳定性及抗干扰性能差的问题,为柔性葡萄糖传感器的构建提供了可能。

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关键词: 柔性无酶传感器碳纳米纤维静电纺丝葡萄糖铂纳米片

Abstract: Diabetes is a metabolic disease characterized by hyperglycemia, which seriously threatens human health. Blood glucose monitoring plays an important role in the prevention, diagnosis and treatment of diabetes. The flexible carbon nanofibers were prepared by combination of electrospinning and heat treatment using polyacrylonitrile as the carbon source. Subsequently, the nonenzyme glucose sensor was constructed by loading Pt nanosheets directly on the surface of self-supporting carbon nanofibers by potentiostatic electrodeposition method. The results indicated that the surface of the nanofibers was smooth, and the Pt nanosheets gradually grew to fill the gap of carbon nanofibers. The length of single nanosheet was 100—200 nm, and the width was about 100 nm. The electrochemical results indicated that the linear detection range of the nonenzyme glucose biosensor electrode was 7.5—87.5 mmol/L with a low detection limit of 14.04 μmol/L and a sensitivity of 6.41 μA·(mmol/L)^-1·cm^-2. In addition, the sensor showed the excellent anti-interference ability, high repeatability and excellent storage stability. The fabricated sensor can combine the advantages of flexible electrode and nonenzyme sensor, and provides the possibility for the construction of flexible glucose sensor.

Key words: flexible nonenzymatic sensor carbon nanofibers electrospinning glucose platinum nanosheets

出版日期: 2022-05-10 发布日期: 2022-05-09

ZTFLH:

O657

基金资助: 山西省重点研发计划项目(201703D421019); 山西省应用基础研究项目(201801D121281)

通讯作者: wangxiaojun@tyut.edu.cn

作者简介: 张姣娇,1996年生,太原理工大学生物医学工程学院研究生。主要研究方向为导电纳米碳纤维材料的制备及应用。
王晓君,太原理工大学机械与运载工程学院教授、硕士研究生导师。1997年获太原理工大学工程力学专业学士学位,2010年获太原理工大学生物医学工程专业博士学位。1997年参加工作以来一直从事基础力学的教学工作。主要从事生物力学、一般力学及生物传感器的研究。在国内外核心期刊以及学术会议发表论文30余篇,其中SCI及EI收录10余篇,撰写专著1部,授权专利5项。主持并完成国家自然科学基金青年基金1项,并作为主要成员参与了多项国家自然科学基金重点项目及面上项目。

引用本文:

张姣娇, 王晓君, 张卓雅. 利用碳纳米纤维/Pt纳米片构建柔性电极用于葡萄糖检测[J]. 材料导报, 2022, 36(9): 21010143-6.
ZHANG Jiaojiao, WANG Xiaojun, ZHANG Zhuoya. Construction of Flexible Electrode Using Carbon Nanofibers/Pt Nanosheets for Glucose Detection. Materials Reports, 2022, 36(9): 21010143-6.

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http://www.mater-rep.com/CN/10.11896/cldb.21010143 或 http://www.mater-rep.com/CN/Y2022/V36/I9/21010143

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