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材料导报  2020, Vol. 34 Issue (24): 24160-24164    https://doi.org/10.11896/cldb.19110055
  高分子与聚合物基复合材料 |
离子液体在不同溶剂中对PVB静电纺丝的影响
陈雪微1,2, 刘巍1,2,3, 高洪达1
1 天津工业大学环境科学与工程学院,天津300387
2 天津工业大学省部共建分离膜与膜过程国家重点实验室,天津300387
3 天津市水质安全评价与保障技术工程中心,天津300387
The Effect of Ionic Liquid on the Electrospinning of PVB in Different Solvents
CHEN Xuewei1,2, LIU Wei1,2,3, GAO Hongda1
1 School of Environmental Science and Engineering, Tiangong University, Tianjin 300387, China
2 State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong University, Tianjin 300387, China
3 Tianjin Engineering Center for Safety Evaluation of Water Quality & Safeguards Technology, Tianjin 300387, China
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摘要 为了研究离子液体在不同溶剂中对溶液特性及产物的影响,以聚乙烯醇缩丁醛(PVB)为溶质,甲酸丙酯和乙酸异丁酯分别作溶剂,采用静电纺丝法制备PVB纳米纤维。将添加剂N-乙基吡啶六氟磷酸盐[EPy][PF6]分别添加到PVB/甲酸丙酯和PVB/乙酸异丁酯两种溶液中,研究离子液体在不同溶剂中对溶液电导率、粘度和表面张力的影响。结果表明: [EPy][PF6]对两种溶液性质的改变主要是电导率的增加,在0.1%~0.9%(质量分数,下同)范围内,溶液的电导率与离子液体添加量成正比,PVB/甲酸丙酯溶液的电导率增幅远高于PVB/乙酸异丁酯。使用甲酸丙酯作溶剂,离子液体可以有效减小纤维直径,被用于制备直径更小的纳米纤维。
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陈雪微
刘巍
高洪达
关键词:  静电纺丝  聚乙烯醇缩丁醛  离子液体  形貌控制    
Abstract: In order to study the effect of the addition of ionic liquids on solution properties and products in different solvents, PVB nanofibers were prepared by electrospinning method with PVB as solute and propyl formate and isobutyl acetate as the solvents, respectively. The same additive, N-ethylpyridinium hexafluorophosphate[EPy][PF6], was added to the PVB/propyl formate and PVB/isobutyl acetate solutions respectively to study the effects of the same ionic liquid on the conductivity, viscosity and surface tension of solutions in different solvents. The results show that the change of the properties of the two solutions by adding [EPy][PF6] is mainly due to the increase of conductivity. In the range of 0.1wt%—0.9wt%, the conductivity of the solutions are directly proportional to the amount of ionic liquid added, and the conductivity increase of PVB/propyl formate solution is much higher than that of PVB/isobutyl acetate. Using propyl formate as solvent, ionic liquid can effectively reduce the diameter of the fiber and be used to prepare nanofibers with smaller diameter.
Key words:  electrospinning    PVB    ionic liquid    morphology control
               出版日期:  2020-12-25      发布日期:  2020-12-24
ZTFLH:  TQ340.64  
基金资助: 天津市教委科研计划项目(2018KJ200)
通讯作者:  liuhuiwen217@yahoo.com   
作者简介:  陈雪微,天津工业大学硕士研究生,主要从事高分子纳米材料的研究。
刘巍,天津工业大学副教授,硕士研究生导师。2011年毕业于意大利都灵大学,获得理学博士学位,同年加入天津工业大学工作至今,研究方向为多孔高分子材料的合成与吸附应用、高分子负载金属纳米粒子的合成和催化应用、环境敏感JANUS粒子的制备与表征、多壳层聚合物微囊的制备与应用。在国内外重要期刊发表文章10 余篇,申报发明专利3项。
引用本文:    
陈雪微, 刘巍, 高洪达. 离子液体在不同溶剂中对PVB静电纺丝的影响[J]. 材料导报, 2020, 34(24): 24160-24164.
CHEN Xuewei, LIU Wei, GAO Hongda. The Effect of Ionic Liquid on the Electrospinning of PVB in Different Solvents. Materials Reports, 2020, 34(24): 24160-24164.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19110055  或          http://www.mater-rep.com/CN/Y2020/V34/I24/24160
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