Please wait a minute...
材料导报  2020, Vol. 34 Issue (18): 18019-18024    https://doi.org/10.11896/cldb.19080079
  机非金属及其复合材料 |
[BMIM]PF6离子液体中GO/CuO/CeO2催化剂的制备及可见光活性
郦雪, 张燕, 张玉琰, 宋凤娟, 赵晓涵, Akanyange Stephen Nyabire, 曹晓强, 吕宪俊
山东科技大学化学与环境工程学院,青岛 266590
Preparation and Visible-light Photocatalytic Activity of GO/CuO/CeO2 Photocatalysts in [BMIM]PF6
LI Xue, ZHANG Yan, ZHANG Yuyan, SONG Fengjuan, ZHAO Xiaohan, Akanyange Stephen Nyabire, CAO Xiaoqiang, LYU Xianjun
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China
下载:  全 文 ( PDF ) ( 5440KB )     补充信息
输出:  BibTeX | EndNote (RIS)      
摘要 在[BMIM]PF6离子液体辅助下制备了纯CeO2和一系列GO/CuO/CeO2可见光催化剂,并采用X射线衍射仪(XRD)、场发射扫描电镜(SEM)、比表面积及孔隙度分析仪(BET)以及紫外可见漫反射仪(UV-Vis DRS)对样品进行表征及分析。研究了可见光照射下,不同GO和CuO掺杂量对GO/CuO/CeO2复合催化剂产氢活性的影响规律。实验结果表明,复合样品产氢效率明显优于纯CeO2,当GO负载量为2%(质量分数)、CuO负载量为3%(质量分数)时,复合样品的产氢速率可达111.23 μmol·h-1·g-1(为纯CeO2的2.5倍),量子效率为15.67%。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
郦雪
张燕
张玉琰
宋凤娟
赵晓涵
Akanyange Stephen Nyabire
曹晓强
吕宪俊
关键词:  离子液体  可见光  光催化产氢  二氧化铈    
Abstract: Pure CeO2 and a series of GO/CuO/CeO2 photocatalysts were prepared with the assist of [BMIM]PF6 ionic liquid. X-ray diffraction, scanning electron microscopy, accelerated surface area and porosimetry system, and UV-Visible diffuse reflectance spectra were used to characterize and analyze the samples. The influence of different GO and CuO doping amounts on the hydrogen production activity of GO/CuO/CeO2 composite catalyst under the irradiation of visible light was studied. The experimental results showed that the hydrogen production efficiency of composite samples was significantly better than that of pure CeO2, and the hydrogen production rate reached 111.23 μmol·h-1·g-1 when the GO load was 2wt% and the CuO load was 3wt%, which was 2.5 times of the pure CeO2, the quantum yields of the composite sample was 15.67%.
Key words:  ionic liquid    visible-light    photocatalytic hydrogen production    CeO2
               出版日期:  2020-09-25      发布日期:  2020-09-12
ZTFLH:  O643  
基金资助: 国家自然科学基金(51674161);山东省政府公派留学项目
通讯作者:  tougaoktz@163.com   
作者简介:  郦雪,2018年6月毕业于沈阳理工大学,获得工学学士学位。2018年9月至今在山东科技大学攻读硕士研究生,研究方向为环境功能材料。
张燕,山东科技大学,副教授。2009年毕业于东华大学与澳大利亚联邦科工研究院(CSIRO),获环境工程博士学位。主要从事环境功能材料和废水处理方面的研究。在国内外重要期刊发表学术文章30余篇,申报发明专利5项。
引用本文:    
郦雪, 张燕, 张玉琰, 宋凤娟, 赵晓涵, Akanyange Stephen Nyabire, 曹晓强, 吕宪俊. [BMIM]PF6离子液体中GO/CuO/CeO2催化剂的制备及可见光活性[J]. 材料导报, 2020, 34(18): 18019-18024.
LI Xue, ZHANG Yan, ZHANG Yuyan, SONG Fengjuan, ZHAO Xiaohan, Akanyange Stephen Nyabire, CAO Xiaoqiang, LYU Xianjun. Preparation and Visible-light Photocatalytic Activity of GO/CuO/CeO2 Photocatalysts in [BMIM]PF6. Materials Reports, 2020, 34(18): 18019-18024.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19080079  或          http://www.mater-rep.com/CN/Y2020/V34/I18/18019
1 Biswas M R, Ali A, Cho K Y, et al. Ultrasonics-Sonochemistry, 2018, 42, 738.
2 Zhang F, Ding T, Zhang Y C, et al. Materials Letters, 2017, 192, 149.
3 Zhu L, Nguyen D C T, Woo J H, et al. Scientific Reports, 2018, 8, 12759.
4 Wen X J, Niu C G, Ruan M, et al. Journal of Colloid and Interface Scie-nce, 2017, 497, 368.
5 Watanabe S, Ma X L, Song C S. The Journal of Physical Chemistry C, 2009, 113(32), 14249.
6 Zong X, Yan H J, Wu G P, et al. Journal of the American Chemical Society, 2008, 130(23), 7176.
7 Hossain S T, Azeeva E, Zhang K F, et al. Applied Surface Science, 2018, 455, 132.
8 Zhang X D, Zhang X L, Song L, et al. International Journal of Hydrogen Energy, 2018, 43(39), 18279.
9 Yang S Q, Zhou F, Liu Y J, et al. International Journal of Hydrogen Energy, 2019, 44(14), 7252.
10 Liu Z M, He C X, Chen B H, et al. Catalysis Today, 2017, 297, 78.
11 Liang H Y, Xiao K, Wei L Y, et al. Journal of Hazardous Materials, 2019, 374, 167.
12 Yin J Y, Cai J J, Yin C, et al. Journal of Environmental Chemical Engineering, 2016, 4(1), 958.
13 Pal D B, Lavania R, Srivastava P, et al. Journal of Environmental Che-mical Engineering, 2018, 6(2), 2577.
14 Priyadharsan A, Vasanthakumar V, Karthikeyan S, et al. Journal of Photochemistry and Photobiology A: Chemistry, 2017, 346, 32.
15 Huang T F, Wu J, Zhao Z, et al. Materials Letters, 2016, 185, 503.
16 Kumar S, Ojha A K, Patrice D, et al. Physical Chemistry Chemical Physics, 2015, 18(18), 13126.
17 Wasserscheid P, Keim W. Angewandte Chemie International Edition, 2000, 39, 3772.
18 Chen H X, Zeng J, Chen M D, et al. Chinese Journal of Catalysis, 2019, 40(5), 744.
19 Kim T, Li H B, Lian J B, et al. Crystal Research and Technology, 2010, 45(7), 767.
20 Zhang G S, Zhang W, Wang P, et al. International Journal of Hydrogen Energy, 2013, 38(3), 1286.
21 Zhang G S, Zhang W, Minakata D, et al. International Journal of Energy Research, 2014, 38(12), 1513.
22 Meng D J, Wang B W, Liu Z, et al. Journal of Energy Chemistry, 2017, 26(3), 368.
23 Chen F J, Ho P L, Ran R, et al. Journal of Alloys and Compounds, 2017, 714, 560.
24 Tu S H, Xu C, Dai C, et al. Materials Reports B:Research Papers, 2019, 33(8), 2633(in Chinese).
涂盛辉, 徐翀, 戴策, 等. 材料导报:研究篇, 2019, 33(8), 2633.
25 Song C D, Zhang J, Gao Y, et al. Acta Physico-Chimica Sinica, 2017, 33(9), 1891(in Chinese).
宋春冬, 张静, 高莹, 等. 物理化学学报, 2017, 33(9), 1891.
26 Liu S L, Wang X J. Applied Chemical Industry, 2018, 47(10), 2184(in Chinese).
刘淑玲, 王小剑. 应用化工, 2018, 47(10), 2184.
27 Ma X J, Lu P, Wu P. Ceramics International, 2018, 44(5), 5284.
28 Johns R W, Blemker M A, Azzaro M S, et al. Journal of Materials Chemistry C, 2017, 5(23), 1039.
29 Wang N, Pan Y, Lu T, et al. Applied Surface Science, 2017, 403, 699.
30 Pan H, Hu Y, Wu X W, et al. Materials Reports B:Research Papers, 2018, 32(12), 4224(in Chinese).
潘会, 胡轶, 兀晓文, 等. 材料导报:研究篇, 2018, 32(12), 4224.
[1] 黄青武, 吴越, 宋武林, 丁雨葵. 碳纤维的电纺制备及结构表征[J]. 材料导报, 2020, 34(Z1): 164-168.
[2] 李绘, 张燕, 张玉琰, 宋风娟, 郦雪, 王浩宇, 曹晓强, 吕宪俊. [BMIM][BF4]-MnO2@SS阳极的制备及对氧氟沙星废水的降解[J]. 材料导报, 2020, 34(6): 6029-6032.
[3] 陈雪微, 刘巍, 高洪达. 离子液体在不同溶剂中对PVB静电纺丝的影响[J]. 材料导报, 2020, 34(24): 24160-24164.
[4] 王薇, 刘竟成, 霍旺晨, 王均, 王芊卉. C掺杂纳米硅藻土@TiO2催化剂吸附-光催化降解油田废水[J]. 材料导报, 2020, 34(23): 23027-23032.
[5] 张先桂, 刘小磐, 高朋召, 廖明雅, 周仁宸. CeO2含量对SiO2-B2O3-ZnO-K2O-BaO系彩釉玻璃基料性能的影响[J]. 材料导报, 2020, 34(22): 22042-22046.
[6] 李靖, 刘天宝, 朱亚鑫, 王鹏, 堵锡华, 张永才. 溶剂热合成可见光响应硫氮共掺杂TiO2光催化剂及其催化还原水中Cr(Ⅵ)[J]. 材料导报, 2020, 34(21): 21045-21051.
[7] 肖洒, 谈恒, 吴珊妮, 曾敏, 熊春荣. CuO/Er-Yb-TiO2的制备及在模拟可见光下催化CO2合成甲醇[J]. 材料导报, 2020, 34(2): 2005-2009.
[8] 栗思琪, 鲁浈浈, 张琪. 碱金属及碱土金属掺杂石墨相-C3N4光催化材料研究进展[J]. 材料导报, 2020, 34(15): 15039-15046.
[9] 周婉秋, 赵玉明, 刘晓安, 杨佳宇, 姜文印, 辛士刚, 康艳红. 1-乙基-3-甲基咪唑硫酸乙酯盐离子液体中采用电化学法合成聚苯胺薄膜及其耐蚀性[J]. 材料导报, 2020, 34(12): 12152-12157.
[10] 冉涛, 张骞, 黎邦鑫, 刘旸, 李筠连. g-C3N4/泡沫镍整体式光催化剂的构建及光氧化去除NO[J]. 材料导报, 2019, 33(z1): 337-342.
[11] 占昌朝, 曹小华, 金文雄, 叶志刚, 谢宝华, 徐建兴, 周荣辉. 以水杨酸为模板分子的Nd掺杂分子印迹TiO2的制备及光催化性能[J]. 材料导报, 2019, 33(6): 947-953.
[12] 范海波, 任启芳, 余淼, 王苏蕾, 曹镜宇, 金震, 丁益. 磷酸银/类石墨氮化碳-硅藻土复合材料的制备及可见光催化性能[J]. 材料导报, 2019, 33(20): 3383-3389.
[13] 卫芳彬, 张雷阳, 王颖, 李洋, 刘岗. 二氧化铈掺杂钛酸铋钠基陶瓷的高储能密度及温度稳定性[J]. 材料导报, 2019, 33(16): 2648-2653.
[14] 刘钊, 王纪孝, 孙亚伟. 硫酸掺杂聚苯胺涂层的快速表面光热杀菌性能[J]. 材料导报, 2019, 33(14): 2431-2435.
[15] 李雅明, 李艳军, 张江, 丛野, 崔正威, 袁观明, 董志军, 邹涛, 李轩科. K3V5O14的合成及光催化性能和吸附性能[J]. 材料导报, 2019, 33(12): 1926-1931.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[4] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[5] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[6] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[7] DU Wenbo, YAO Zhengjun, TAO Xuewei, LUO Xixi. High-temperature Anti-oxidation Property of Al2O3 Gradient Composite Coatings on TC11 Alloys[J]. Materials Reports, 2017, 31(14): 57 -60 .
[8] ZHANG Le, ZHOU Tianyuan, CHEN Hao, YANG Hao, ZHANG Qitu, SONG Bo, WONG Chingping. Advances in Transparent Nd∶YAG Laser Ceramics[J]. Materials Reports, 2017, 31(13): 41 -50 .
[9] ZHANG Yating, REN Shaozhao, DANG Yongqiang, LIU Guoyang, LI Keke, ZHOU Anning, QIU Jieshan. Electrochemical Capacitive Properties of Coal-based Three-dimensional Graphene Electrode in Different Electrolytes[J]. Materials Reports, 2017, 31(16): 1 -5 .
[10] CHEN Bida, GAN Guisheng, WU Yiping, OU Yanjie. Advances in Persistence Phosphors Activated by Blue-light[J]. Materials Reports, 2017, 31(21): 37 -45 .
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed