Abstract: Sensors are convenient, fast and sensitive, and have great potential in various detection fields. Hydroxyapatite(Ca10(PO4)6(OH)2, HAp) is the main inorganic component of the bone and tooth of vertebrate, and has been widely used as biomaterial.In recent years, it has been widely used for sensing materials and has shown great potential, due to its unique three-dimensional network structure, good stability, excellent adsorption capacity, and ion exchange feature. The performance of pure HAp is limited when used alone due to the constraints of conductivity and mechanical strength. In order to improve its comprehensive performance, researchers mainly try to modify it by ion-doping (Ag+, Fe2+, Pb2+, etc.) or preparing composite materials with other materials, such as graphene, carbon nanotubes, conductive polymers, biological enzymes and so on. Some progress has been made in improving the sensitivity and stability, and reducing the detection limits of HAp. HAp and its composites have better sensing performance for ammonia and alcohol gases than other gases, and can detect lower concentrations of toxic and harmful gases at room temperature. Due to its good ion exchange properties, HAp can detect many heavy metal ions, such as Pb2+, Cu2+, Hg2+, As3+, Cd2+ and so on, and can be used in the fields of environment protection and medical care. HAp can also be used to detect more than ten kinds of biomass, including uric acid, glucose, L-dopa, etc. If used as a carrier of biological enzymes, it can detect specific substances with excellent selectivity. HAp can also be used as a moisture-sensitive material. Modification by doping metal ions to improve the conductivity is a potential way to improve the humidity sensitivity of HAp. In addition, HAp has also been reported in photo, magnetic and thermal sensing applications. Firstly, we review the basic microstructure, properties and synthesis methods of HAp briefly. Then we mainly focus on the research progress of HAp and its composite in the fields of gas sensing, ion sensing, biosensing and humidity sensing. Finally, the research direction of HAp as sen-sing materials in the future is prospected.
吴江松, 谭彦妮, 刘晏军. 羟基磷灰石在传感领域应用的研究进展[J]. 材料导报, 2022, 36(20): 20090296-13.
WU Jiangsong, TAN Yanni, LIU Yanjun. Research Progress of the Sensing Applications of Hydroxyapatite. Materials Reports, 2022, 36(20): 20090296-13.
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