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材料导报  2020, Vol. 34 Issue (18): 18060-18064    https://doi.org/10.11896/cldb.19090054
  机非金属及其复合材料 |
废胶粉改性制备高模量沥青及其动态力学性能
辛雪1, 苏林萍1, 梁 明1, 姚占勇1, 范维玉2, 南国枝2, 张吉哲1
1 山东大学齐鲁交通学院,济南 250002
2 中国石油大学(华东)重质油国家重点实验室,青岛 266580
Preparation and Dynamic Mechanical Properties of High-Modulus Asphalt Modified by Waste Rubber
XIN Xue1, SU Linping1, LIANG Ming1, YAO Zhanyong1, FAN Weiyu2, NAN Guozhi2, ZHANG Jizhe1
1 School of Qilu Transportation, Shandong University, Jinan 250002, China
2 State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266580, China
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摘要 以脱油沥青(DOA)为主要原料,分别掺加不同粒径和不同含量的废胶粉制备高模量沥青,并对产物进行常规指标分析、动态力学性能分析及荧光显微检测。研究结果表明,胶粉在沥青中主要以条状或棒状形式存在,且胶粉与沥青并不完全相容,而是以分散相分散在沥青中。随着胶粉掺量的增加,高模量沥青的软化点逐渐上升,其高温性能得到明显改善,这是由于废胶粉吸收沥青中的轻质组分后发生溶胀,沥青质含量增加,使得高模量沥青组分重质化。相同温度下,G*G′和G″均随废胶粉掺量的增加呈现明显上升的趋势,说明废胶粉掺量越高,沥青模量的改善效果越明显,对高模量沥青的抗车辙性能越有利;通过拟合不同废胶粉掺量下G*/sinδ与温度的关系,计算得到每增加1%(质量分数,下同)的废胶粉,高模量沥青的高温等级增加1.66℃。
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辛雪
苏林萍
梁 明
姚占勇
范维玉
南国枝
张吉哲
关键词:  脱油沥青  高模量沥青  胶粉改性  动态力学  微观结构    
Abstract: With de-oiled asphalt (DOA) as the main raw material, waste rubber powder of different particle size and contents was added respectively to prepare high-modulus asphalt. Conventional properties analysis, dynamic mechanical analysis and fluorescence microscopy were performed for the products. Results show that rubber powder is not completely compatible with the asphalt but dispersed in the asphalt in the form of dispersed phase existing in the asphalt in the form of strip or rod. With the increase of rubber amounts, softening point increases gradually and the high-temperature performance is obviously improved. It is caused by the swelling of waste rubber powder after absorbing the light part of asphalt and the increase of asphaltene content. At the same temperature, G*, G′ and G″ all showed an obvious upward trend with the increase of waste rubber content, indicating more obvious of improvement effect and more favorable rutting resistance of high-modulus asphalt with the higher the waste rubber powder content. By fitting the relationship between G*/sinδ and temperature under different waste rubber amount, the high tempe-rature grade of high-modulus asphalt increases by 1.66℃ for every 1wt% increase of waste rubber.
Key words:  de-oiled asphalt    high-modulus asphalt    rubber modification    dynamic mechanical properties    microstructure
                    发布日期:  2020-09-12
ZTFLH:  U414  
基金资助: 国家自然科学基金青年科学基金(51908330);山东省博士后创新项目一等资助(201901007)
通讯作者:  zhanyong-y@sdu.edu.cn   
作者简介:  辛雪,山东大学博士研究生,主要从事道路沥青材料及道路智能监测传感器研究工作。以第一或第二位次发表SCI、EI论文8篇,申请国家发明专利9项。曾获得国家奖学金、山东省优秀学生、山东省“挑战杯”课外学术作品竞赛特等奖等荣誉及奖励50余项。
姚占勇,教授,博士研究生导师,山东大学齐鲁交通研究院副院长,山东大学高速公路工程技术研发中心主任。长期从事高速公路路基路面材料与结构设计,研究了黄泛区公路病害机理以及路基设计理论与工程技术,解决了黄泛区粉土路基水稳定性、动力稳定性问题;对沥青路面较大应变下检测机敏材料与相关工程技术进行了初步研究,开发了适用于道路微小应变监测的机敏监测材料与传感器,并在路面结构监测中进行了工程应用。已发表高水平SCI/EI论文60余篇;出版专著4部、地方标准3部。获省部级科技奖励6项,获得国家发明专利20余项。
引用本文:    
辛雪, 苏林萍, 梁 明, 姚占勇, 范维玉, 南国枝, 张吉哲. 废胶粉改性制备高模量沥青及其动态力学性能[J]. 材料导报, 2020, 34(18): 18060-18064.
XIN Xue, SU Linping, LIANG Ming, YAO Zhanyong, FAN Weiyu, NAN Guozhi, ZHANG Jizhe. Preparation and Dynamic Mechanical Properties of High-Modulus Asphalt Modified by Waste Rubber. Materials Reports, 2020, 34(18): 18060-18064.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19090054  或          http://www.mater-rep.com/CN/Y2020/V34/I18/18060
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