有机电子传输材料在反式钙钛矿太阳能电池中的研究现状

doi:10.11896/cldb.22100210

材料导报

2024, Vol. 38

Issue (10): 22100210-11 https://doi.org/10.11896/cldb.22100210

高分子与聚合物基复合材料

有机电子传输材料在反式钙钛矿太阳能电池中的研究现状

王耀武, 王彬彬^*

河南理工大学材料科学与工程学院,河南焦作 454003

Research Status of Organic Electron Transport Materials in Inverted Perovskite Solar Cells

WANG Yaowu, WANG Binbin^*

School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, Henan, China

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摘要近年来,反式结构的钙钛矿太阳能电池凭借制备工艺简单、可低温成膜、迟滞效应低、适合与传统太阳能电池结合制备叠层器件等优点,受到了人们广泛的关注,经过几年的发展,反式钙钛矿太阳能电池的光电转化效率已从3.9%提升到25.37%。其中电子传输层作为钙钛矿太阳能电池的重要组成部分,在提取和运输载流子、阻挡空穴、调节界面能级结构和抑制电荷复合等方面起着关键性的作用。一些有机材料(富勒烯及其衍生物、苝二酰亚胺、萘二酰亚胺等)凭借容易合成和纯化、能级可调、电子迁移率高、溶解性好、化学/热稳定性良好等优势,已经广泛应用于反式钙钛矿太阳能电池。本文主要介绍了不同有机电子传输材料在反式钙钛矿太阳能电池中的研究现状,还介绍了电子传输层掺杂和界面修饰两种提升器件性能的改性手段,旨在为开发全新的有机电子传输材料提供基础性的理论指导。

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	王耀武
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关键词: 反式钙钛矿太阳能电池工作机理有机电子传输材料

Abstract: Due to their simple manufacturing processes, low-temperature film-forming technology, negligible hysteresis, and suitability for preparation of multi-stack devices with conventional solar cells, inverted perovskite solar cells (PSCs) have been extensively researched. In the past se-veral years, the power conversion efficiency of inverted PSCs has increased from 3.9% to 25.37%. As a major component of PSCs, the electron transport layer (ETL) plays a critical role in extracting and transporting carriers, blocking holes, modifying energy levels, and preventing charge recombination. Because of their ease of synthesis and purification, high electron mobility, good solubility, and excellent chemical/thermal stability, organic materials such as fullerene and its derivatives, perylene diimide, and naphthalimide have been most commonly used in the ETLs of inverted PSCs. This review mainly introduces the research status of organic ETLs, modification methods for improving device performance by ETL doping, and interface modification in inverted PSCs, thus providing basic theoretical guidelines for developing new organic ETLs.

Key words: inverted perovskite solar cell working mechanism organic electron transport material

出版日期: 2024-05-25 发布日期: 2024-05-28

ZTFLH:	TM914.4
	O649

基金资助: 国家自然科学基金(42002164;U1804156); 河南省自然科学基金(202300410171);河南省科技攻关计划项目(222102240080);河南理工大学青年骨干教师资助计划(2022XQG-13)

通讯作者: *王彬彬,博士,河南理工大学材料科学与工程学院副教授、硕士研究生导师。2004年毕业于东北师范大学获得学士学位,2007年毕业于东北师范大学获得硕士学位,2013年毕业于吉林大学获得博士学位,2014—2016年,中国科学院化学研究所从事博士后工作研究,2016至今,河南理工大学材料科学与工程学院教师。目前主要从事有机-无机杂化钙钛矿太阳能电池方面的研究。在国际期刊Journal of Materials Chemistry A、Electrochimica Acta 等发表论文10余篇,出版专著1部。wangbb@hpu.edu.cn

作者简介: 王耀武,2021年毕业于河南城建学院获得工学学士学位,现为河南理工大学材料科学与工程学院硕士研究生,在王彬彬副教授的指导下进行学习研究。目前主要的研究领域为有机-无机杂化钙钛矿太阳能电池。

引用本文:

王耀武, 王彬彬. 有机电子传输材料在反式钙钛矿太阳能电池中的研究现状[J]. 材料导报, 2024, 38(10): 22100210-11.
WANG Yaowu, WANG Binbin. Research Status of Organic Electron Transport Materials in Inverted Perovskite Solar Cells. Materials Reports, 2024, 38(10): 22100210-11.

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http://www.mater-rep.com/CN/10.11896/cldb.22100210 或 http://www.mater-rep.com/CN/Y2024/V38/I10/22100210

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