镁铝尖晶石原位生成及其对耐火材料结构、性能的影响

doi:10.11896/cldb.22040125

材料导报

2023, Vol. 37

Issue (20): 22040125-5 https://doi.org/10.11896/cldb.22040125

无机非金属及其复合材料

镁铝尖晶石原位生成及其对耐火材料结构、性能的影响

刘国齐^1,2, 李红霞^1,3,*, 杨文刚^1,2, 钱凡^1,2, 李勇³

1 中钢集团洛阳耐火材料研究院有限公司,先进耐火材料国家重点实验室,河南洛阳 471039
2 有色金属新材料与先进加工技术省部共建协同创新中心,河南洛阳 471023
3 北京科技大学材料科学与工程学院,北京 100083

In-situ MgAl₂O₄ Formation and Its Influence on the Microstructure and Properties of Refractories

LIU Guoqi^1,2, LI Hongxia^1,3,*, YANG Wengang^1,2, QIAN Fan^1,2, LI Yong³

1 Sinosteel Luoyang Institute of Refractories Research Co., Ltd., State Key Laboratory of Advanced Refractories, Luoyang 471039, Henan, China
2 Provincial and Ministerial Co-construction of Collaborative Innovation Center for Non-ferrous Metal New Materials and Advanced Processing Technology, Luoyang 471023, Henan, China
3 School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

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摘要镁铝尖晶石是一种重要的耐火材料,除了利用其固有特性外,高温下镁铝尖晶石的原位生成包括二次尖晶石化是耐火材料显微结构和服役性能调控的重要手段,利用其膨胀效应,不仅可抵消烧结产生的收缩,提高铝镁浇注料、低碳镁碳耐火材料、铝镁碳耐火材料等材料的抗侵蚀性,而且严重影响功能耐火材料的可靠性。本文首先介绍了镁铝尖晶石原位生成机理,重点讨论了气相生成尖晶石的历程以及二次尖晶石化现象,然后从氧化物体系和含碳材料体系出发,基于组成、粒度、气氛、温度及生成物形态等方面系统总结了镁铝尖晶石原位生成的影响因素及其对材料结构和性能的影响,并提出了性能、结构调控的重要途径和当前研究的薄弱环节,可为制备抗侵蚀性强、可靠性高的高性能耐火材料提供重要参考。

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	刘国齐
	李红霞
	杨文刚
	钱凡
	李勇

关键词: 镁铝尖晶石原位反应气相二次尖晶石化性能调控

Abstract: MgAl₂O₄ is an important refractory. In addition to utilizing its inherent properties, the in-situ formation of MgAl₂O₄ at high temperatures, including secondary spinelization, is an important means to regulate the microstructure and service performance for refractories. Its expansion effect can offset the shrinkage caused by sintering, which can improve the corrosion resistance of liner such as Al₂O₃-MgO castables, low-carbon MgO-C refractories, and Al₂O₃-MgO-C refractories. Additionally, this effect can seriously affect the reliability of functional refractories. This paper firstly introduces the in-situ formation mechanism of MgAl₂O₄ and focuses on the formation process by gas phase and the phenomenon of secon-dary spinelization. Based on the composition, particle size, atmosphere, temperature and products morphology, the factors for in-situ MgAl₂O₄ formation and their influence on the microstructure and properties of materials are further systematically summarized in Al₂O₃-MgO-MgAl₂O₄ system and carbon-containing system, respectively. Some ways for regulating microstructure and service performance of refractories and several weak contents of current research are also proposed. This paper will provide an important reference for the preparation of refractories with high corrosion resistance and high reliability.

Key words: MgAl₂O₄ in-situ reaction gas phase secondary spinelization performance regulation

出版日期: 2023-10-25 发布日期: 2023-10-19

ZTFLH:

TQ175

基金资助: 国家重点研发计划(2021YFB3701400);国家自然科学基金(51932008);中原科技创新领军人才(204200510011)

通讯作者: *李红霞,博士,正高级工程师,博士研究生导师,宝武首席科学家。1987 年本科毕业于天津大学无机非金属材料专业,1990 年硕士毕业于天津大学无机非金属材料专业,1990—1994 年在中科院上海硅酸盐研究所攻读博士学位,获工学博士学位。主要开展耐火材料基础理论、原始创新研究、新产品开发及工程化、产业化应用。出版专著6部,发表学术论文300余篇,获授权发明专利60件。lihongx0622@126.com

作者简介: 刘国齐,工学博士,中钢集团洛阳耐火材料研究院高级技术专家,正高级工程师,硕士研究生导师。1997年河北理工学院无机非金属专业本科毕业,2000年洛阳耐火材料研究院无机非金属材料专业硕士毕业后在该院工作至今,2006年北京科技大学材料学专业博士毕业,目前主要从事功能耐火材料等方面的研究,主持或参与了多项省部级以上科研课题的研究开发工作,获国家技术发明二等奖(排名第3)1项,在Ceramic International、 Journal of Alloy and Compounds、《耐火材料》等期刊上发表学术论文100余篇,授权发明专利18件,主持修订《连铸用功能耐火制品》标准,获国务院政府特殊津贴。

引用本文:

刘国齐, 李红霞, 杨文刚, 钱凡, 李勇. 镁铝尖晶石原位生成及其对耐火材料结构、性能的影响[J]. 材料导报, 2023, 37(20): 22040125-5.
LIU Guoqi, LI Hongxia, YANG Wengang, QIAN Fan, LI Yong. In-situ MgAl₂O₄ Formation and Its Influence on the Microstructure and Properties of Refractories. Materials Reports, 2023, 37(20): 22040125-5.

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http://www.mater-rep.com/CN/10.11896/cldb.22040125 或 http://www.mater-rep.com/CN/Y2023/V37/I20/22040125

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