Research Progress in the Application of Core-Shell Catalysts to Air Pollution Control
QI Zhiyong1, GAO Fengyu1,2, TANG Xiaolong1,2,*, YI Honghong1,2, DU Ying1
1 School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China 2 Beijing Key Laboratory of Resource Treatment of Industrial Typical Pollutants, Beijing 100083, China
Abstract: With the development and progress of industry, air pollution is becoming more and more serious, making the end pollution control immediately urgent. Catalyst is the core of catalytic reaction, and its preparation and configuration have become the focus of the field of atmospheric pollution treatment. Conventional single catalyst has some disadvantages such as high cost, easy inactivation, and narrow use conditions. In recent years, the core-shell nanomaterials have attracted the attention of scholars in the field of composite materials owing to their unique cavity structure. They not only have dual functions and multi-functional characteristics that traditional catalysts do not have, but also have broad application prospects in the field of environmental catalysis. Because of its good thermal stability and excellent shape-selective catalytic effect, the core-shell structure catalyst shows excellent overall acti-vity in the catalytic reaction. However, the core-shell composite particles also face some problems, such as easy agglomeration, poor thickness control of core-shell dispersion, and the need to improve the bonding strength. Although some scholars have prepared Mn-based and Ce-based core-shell nanomaterials for air pollution control, and achieved good catalytic effects in recent years, there are still shortcomings in the construction of the core-shell structure and the selection of the preparation methods. At the same time, the targeted application in specific fields needs to be further improved. In this review, firstly, the main methods of preparing core-shell materials such as hydrothermal synthesis, precipitation and template methods are introduced in detail, along with the advantages and disadvantages of various preparation methods. Then the applicable methods for preparing different types of core-shell catalysts, such as metal-based core-shell material, metal oxide-based core-shell material, molecular sieve, hollow core-shell and rattle core-shell materials, are analyzed. Moreover, the research advances of different types of core-shell materials with respects to the main applicatory fields in air pollution control (NH3-SCR denitrification, VOCs removal, high and low concentration CO removal) are summarized. The paper ends with brief but comparative and prospective discussions about the merits and demerits of the currently mainstream core-shell catalysts, and about the major research directions in the near future.
齐致雍, 高凤雨, 唐晓龙, 易红宏, 杜影. 核壳催化剂用于大气污染控制的研究进展[J]. 材料导报, 2023, 37(10): 21060234-12.
QI Zhiyong, GAO Fengyu, TANG Xiaolong, YI Honghong, DU Ying. Research Progress in the Application of Core-Shell Catalysts to Air Pollution Control. Materials Reports, 2023, 37(10): 21060234-12.
1 Solar P, Polonskyi O, Olbricht A, et al. Scientific Reports, 2017, 7(1), 8514. 2 Guo Z T. Synthesis and catalytic performance of noble metal-oxide core-shell/rattle nanocatalysts. Master's Thesis, Yantai University, China, 2019 (in Chinese). 郭郑彤. 贵金属-氧化物核壳/摇铃类纳米催化剂的合成与催化性能研究. 硕士学位论文, 烟台大学, 2019. 3 Yao Y. The unique Co3O4 based and Au-Co3O4 interfacial structures significant for low temperature CO oxidation and benzene combustion. Ph. D. Thesis, Nanjing University, China, 2015 (in Chinese). 姚瑶. Co3O4基底及Au-Co3O4界面结构对低温CO氧化及苯燃烧性能的影响. 博士学位论文, 南京大学, 2015. 4 Su H Y, Tian Q, Price C, et al. Nano Today, 2020, 31(1), 100834 5 Xu W Y, Kuang X, Qin X D. Journal of University of South China (Science and Technology), 2018, 32(2), 1(in Chinese). 徐文媛, 况熙, 秦晓丹. 南华大学学报(自然科学版), 2018, 32(2), 1. 6 Wang Y J. Study on prepration of alumina/silica composite abrasive and its CMP performance. Master's Thesis, Hefei University of Technology, China, 2016 (in Chinese). 汪亚军. 氧化铝/二氧化硅复合磨料的制备及其CMP性能研究. 硕士学位论文, 合肥工业大学, 2016. 7 Hou X X, Li X Y, Chen H P. Journal of Functional Materials, 2019, 50(9), 9157(in Chinese). 侯欣辛, 李翔宇, 陈红萍. 功能材料, 2019, 50(9), 9157. 8 Wu X. Hydrothermal/solvothermal synthesis and characterization of inorganic nanomaterals. Master's Thesis, Yangzhou University, China, 2006 (in Chinese). 吴晓. 无机纳米材料的水热溶剂热合成与表征. 硕士学位论文, 扬州大学, 2006. 9 Cui H M. Mechanism of synthesis of Ni/HBEA with hierarchical core-shell structure and its application. Master's Thesis, East China Normal University, China, 2017 (in Chinese). 崔慧梅. 可控的核壳结构镍基催化剂水热制备原理及其应用. 硕士学位论文, 华东师范大学, 2017. 10 Basak S, Kundu D, Naskar M K. Ceramics International, 2014, 40(8), 12923. 11 Jiang H L, Chen H P. Guangdong Chemical Industry, 2010, 37(11), 262 (in Chinese). 蒋华麟, 陈萍华. 广东化工, 2010, 37(11), 262. 12 Dönüs Tuncel. Nanoscale Advances, 2019, 1, 19. 13 Xu T T, Su W, Jin X Q, et al. Advances in Fine Petrochemicals, 2019, 20(1), 53 (in Chinese). 徐婷婷, 孙维, 金学庆, 等. 精细石油化工进展, 2019, 20(1), 53. 14 Xu J J. Preparation and characterization of micropotous and mesoporous materials with croe-shell structure. Master's Thesis, East China Normal University, China, 2011 (in Chinese). 许佳佳. 微孔与介孔核壳结构材料的制备与表征. 硕士学位论文, 华东师范大学, 2011. 15 Liu Z M, Xie C, Wang H Y, et al. Modern Chemical Industry, 2012, 32(5), 82 (in Chinese). 刘志明, 谢成, 王海英, 等. 现代化工, 2012, 32(5), 82. 16 Zhang S W, Xia F, Nanoscale, 2021, 13(16), 7471. 17 Li S. Preparations, structure tuning and functional applications of core-shell nanomaterials. Ph. D. Thesis, Tsinghua University, China, 2015 (in Chinese). 李洒. 核壳结构纳米材料的制备、调控与功能化特性. 博士学位论文, 清华大学, 2015. 18 Li C, Li Q, Kaneti Y V. Chemical Society Reviews, 2020, 49, 4681. 19 Wang P, Wu Y, Jiang Z T. China Surface Engineering, 2019, 32(6), 157(in Chinese). 王鹏, 吴一, 姜铸锋, 等. 中国表面工程, 2019, 32(6), 157. 20 Zhang J, Zhang X F, Tu M, et al. Mod-Ernst Chemical, 2010, 30(8), 16. 21 Zhang Y L, Li N, Zhang Z Y, et al. Journal of the American Chemical Society, 2020, 142, 8490. 22 Mu X X, Chen H K, Jiang H L, et al. New Chemical Materials, 2020, 48(11), 39 (in Chinese). 慕霞霞, 陈虎魁, 蒋红丽, 等. 化工新型材料, 2020, 48(11), 39. 23 Guo Z T. Synthesis and catalytic performance of noble metal-oxide core-shell/rattle nanocatalysts. Master's Thesis, Yantai University, China, 2019 (in Chinese). 郭郑彤. 贵金属-氧化物核壳/摇铃类纳米催化剂的合成与催化性能研究. 硕士学位论文, 烟台大学, 2019. 24 Dong Z H, Lai X Y, Halpert J E, et al. Advanced Materials, 2012, 24(8), 1046. 25 Chen Z X, Zhen B Y, Li X X. Chemical Industry and Engineering Progress, 2010, 29(1), 94 (in Chinese). 陈彰旭, 郑炳云, 李先学. 化工进展, 2010, 29(1), 94. 26 Li A, Zhu W J, Li C C. Chemical Society Reviews, 2019, 48, 1874. 27 Wang K J, Mao Q F, Fei W M. RSC Advances, 2021, 11(14), 8375. 28 Li Y W, Zhang M, Wang X J, et al. Journal of Aeronautical Materials, 2018, 38(5), 10 (in Chinese). 李元伟, 张猛, 王小健, 等. 航空材料学报, 2018, 38(5), 10. 29 Sanjay S S, Green S. Characterization and applications of nanoparticles, Elsevier Press, Amsterdam, 2019. 30 Pan Y. The control of NOx emission of coal-fired boiler. Master's Thesis, North China Electric Power University, China, 2017 (in Chinese). 潘越. 燃煤锅炉氮氧化物排放控制研究. 硕士学位论文, 华北电力大学, 2017. 31 Ma D R, Liu H C, Chen Y Y. Applied Chemical Industry, 2019, 48(5), 1156 (in Chinese). 麻丁仁, 刘慧超, 陈缘缘. 应用化工, 2019, 48(5), 1156. 32 Li J, Chang H, Ma L, et al. Catalysis Today, 2011, 175(1), 147. 33 Zhang L, Zhang D, Zhang J, et al. Nanoscale, 2013, 5(20), 9821. 34 Cai S X, Hang H, Li H R, et al. Nanoscale, 2016, 8(6), 3588. 35 Huang B J, Yu D Q, Sheng Z Y, et al. Journal of Environmental Sciences, 2017, 55, 129. 36 Li S H, Huang B C, Yu C L. Catalysis Communications, 2017, 98(10), 47. 37 Chi B, Qu H X, Xing X, et al. Journal of Alloys and Compounds, 2017, 726, 906. 38 Xu J S, Tao Y Q, Wu B Z, et al. Anhui Chemical Industry, 2021, 47(1), 43 (in Chinese). 徐洁书, 陶艳琪, 吴炳智, 等. 安徽化工, 2021, 47(1), 43. 39 Liu S H, Huang B J, Yang L, et al. Guangdong Chemical Industry, 2015, 42(10), 72 (in Chinese). 刘世辉, 黄冰洁, 杨柳, 等. 广东化工, 2015, 42(10), 72. 40 Feng Y S. Effects of doping Co-Ce oxides on the structure and properties of Mn/TiO2 low-temperature deNOx catalysts. Master's Thesis, Jiangsu University of Science and Technology, China, 2013. (in Chinese). 冯云桑. Co-Ce氧化物对Mn/TiO2系低温脱硝催化剂结构与性能的影响. 硕士学位论文, 江苏科技大学, 2013. 41 Liu J, Wang L L, Fei Z Y, et al. Journal of Fuel Chemistry and Technology, 2016, 44(8), 954. 42 Sheng Z Y, Ma D R, Yu D Q, et al. Chinese Journal of Catalysis, 2018, 39, 821. 43 Zhang X P, Han X K, Li C F. Catalysts, 2021, 856, 113669. 44 Yu C Y, Yan G S, Li Z P, et al. Current Pharmaceutical Design, 2016, 22(4), 506. 45 Ghosh R S, Harold M P, Wang D. Chemical Engineering Journal, 2021, 418, 129065. 46 Du T Y, Qu H X, Liu Q, et al. Chemical Engineering Journal, 2015, 262, 1199. 47 Zhang L, Du T Y, Qu H X, et al. Chemical Engineering Journal, 2017, 313, 702. 48 Chi B, Qu H X, Xing X, et al. Journal of Alloys and Compounds, 2017, 726, 906. 49 Zhang T, Qiu F, Li J H. Applied Catalysis B:Environmental, 2016, 195, 48. 50 Wang J G, Liu J Z, Tang X J, et al. Chemical Engineering Journal, 2021, 418, 129433. 51 Shi Y, Wang X X, Xia Y F, et al. Molecular Catalysis, 2017, 433, 265. 52 Cui S H, Zhang J T, Shen Z B. et al. Chemical Industry and Engineering Progress, 2015, 34(9), 3311 (in Chinese). 崔生航, 张君涛, 申志兵. 化工进展, 2015, 34(9), 3311. 53 Xu J Q, Tang T, Zhang Q, et al. Vacuum, 2021, 188, 110174. 54 Qiao T, Liu Z G, Liu C H, et al. Applied Catalysis A:General, 2021, 617, 118128 55 Yang K. Simultaneous desulfurization and denitrification performance research on new core-shell structure adsorbent. Ph. D. Thesis, University of Science & Technology Beijing, China, 2020 (in Chinese). 杨昆. 新型核壳结构吸附剂同时脱硫脱硝性能研究. 博士学位论文, 北京科技大学, 2020. 56 Zhu N F, Wang X Q, Song H. Energy Chemical Industry, 2017, 38(5), 27 (in Chinese). 朱宁芳, 王雪芹, 宋华. 能源化工, 2017, 38(5), 27. 57 Zhang L, Du T Y, Qu H X, et al. Chemical Engineering Journal, 2017, 313(1), 702. 58 Zhang J, Wang L, Wu Z Y, et al. Industrial & Engineering Chemistry Research, 2019, 58(34), 15453. 59 Hosseini M, Barakat T, Cousin R, et al. Applied Catalysis B:Environmental, 2012, 111-112, 218. 60 Zheng J G, Tao M, Feng L. Journal of Alloys and Compounds, 2021, 873, 159802. 61 Li Y Z, Du Y H, Wei Y C, et al. Catalysis Science & Technology, 2017, 7(4), 968.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2023, Vol. 37 
