Abstract: Coal is still the most important energy in our country, and the SO2 and NOx emissions from its combustion are the most important sources of air pollution in the recent period. In this paper, the physical and chemical properties of the new oxidant material, yellow phospho-rus, and its by-product sludge phosphorus were discussed in detail. The status and operational reaction mechanism of desulfurization and denitrification by emulsified yellow phosphorus and slurry phosphorus process in the domestic and international research were summarized. Ulteriorly, the similarities and differences between the new technology and the existing technology were explored. It was concluded that the desulfurization and denitrification by alkali-containing yellow phosphorus and slurry phosphorus were a new technology with low cost and high efficiency. In addition, the engineering application of PhoSNOx technology and its purification effect were introduced with examples, and the application prospect of this techno-logy in the future was prospected.
刘宇, 李彬, 丁二卯, 雷小丽, 宁平. 新型氧化剂材料脱硫脱硝的研究进展[J]. 材料导报, 2022, 36(9): 20070192-8.
LIU Yu, LI Bin, DING Ermao, LEI Xiaoli, NING Ping. Research Progress of Desulfurization and Denitrification Using New Oxidant Materials. Materials Reports, 2022, 36(9): 20070192-8.
1 National Bureau of Statistics. The Statistical Bulletin on National Econo-mic and Social Development in 2021, 2022 (in Chinese). 国家统计局. 2021年国民经济和社会发展统计公报, 2022. 2 Xian C M, Li C, Cui S P, et al. Materials Science Forum, 2015, 814, 425. 3 Kerschner B M , Gay D A , Lehmann C M B. Magazine for Environmental Managers, 2015, 65, 6. 4 Dahlan I, Lee K T, Kamaruddin A H, et al. Journal of Hazardous Materials, 2009, 166(2-3), 1556. 5 Zhao Y, Han Y H, Ma T Z, et al. Environmental Science & Technology, 2011, 45(9), 4060. 6 Fang P, Cen C P, Wang X M, et al. Fuel Processing Technology, 2013, 106(2), 645. 7 Raghunah C V, Mondal M K. Asia-Pacific Journal of Chemical Enginee-ring, 2015, 11(1), 88. 8 Yang S L, Han Z T, Dong J M, et al. Journal of Chemistry, 2016, 2016(2), 1. 9 Skalska K, Miller J S, Ledakowicz S. Chemical Engineering & Processing Process Intensification, 2012, 61, 69. 10 Yan X N, Wang C B, Si T, et al. Journal of Chinese Society of Power Engineering, 2019, 39(6), 461(in Chinese). 严雪南, 王春波, 司桐, 等. 动力工程学报, 2019, 39(6), 461. 11 Sun W Y, Wang Q Y, Ding S L, et al. Chemical Engineering Journal, 2013, 228, 700. 12 Li M, Peng B F, Wei L S, et al. Advanced Materials Research, 2014, 1073-1076, 759. 13 Mok Y S. Journal of Industrial and Engineering Chemistry, 2005, 11(3), 45. 14 Sun C L, Zhao N, Wang H, et al. Energy & Fuels,2015,29(5-6),3276. 15 Zhang J, Zhang R, Chen X, et al. Industrial and Engineering Chemistry Research, 2014, 53, 6450. 16 Wang Z H, Zhang X, Zhu Y Q, et al. Science ＆ Engineering, 2014, 34, 204. 17 Liu D K, Shen D X, Chang S G. Environmental Science & Technology, 1991, 25, 55. 18 Chu J Y, Wu C D, Chen W J, et al. Ozone technology and application, Chemical Industry Press, China, 2002(in Chinese). 储金宇, 吴春笃, 陈万金, 等. 臭氧技术及应用, 化学工业出版社,2002. 19 Tanaka T, Morino Y. Journal of Molecular Spectroscopy, 1970, 33(3), 538. 20 Beltran F J. Ozone reaction kinetics for water and wastewater systems, China Architecture & Building Press, China, 2007, pp. 2(in Chinese). Beltran F J. 水和废水的臭氧反应动力学, 中国建筑工业出版社, 2007, pp. 2. 21 Su M.The experimental research on simultaneous removal of SO2 and NOx by advanced oxidation process with O3. Master's Thesis, North China Electric Power University, China, 2010(in Chinese). 苏敏.臭氧高级氧化技术同时脱硫脱硝的实验研究. 硕士学位论文, 华北电力大学, 2010. 22 Wang X N. Study on purification of products reclaimed from sludge phosphorus. Master's Thesis, Kunming University of Science and Technology, China, 2011(in Chinese). 王小妮.泥磷回收产品的净化提纯研究. 硕士学位论文, 昆明理工大学, 2011. 23 Huang X F. Study on preparation of phosphate and coproduction of PH3 or THPC from phosphorus sludge. Master's Thesis, Kunming University of Science and Technology, China, 2013(in Chinese). 黄小凤.泥磷制磷酸盐联产PH3/THPC研究. 硕士学位论文, 昆明理工大学, 2013. 24 Xie G Y, Sun S Y, Wang X W. Chinese Journal of Environmental Engineering, 2004, 5(1), 77(in Chinese). 谢光炎,孙水裕, 王孝武. 环境工程学报, 2004, 5(1), 77. 25 Gu Z Q. Phosphate Industry, 1989(4), 54(in Chinese). 顾志勤. 磷酸盐工业, 1989(4), 54. 26 Shen D X. China Environment Science, 1992, 12(3), 193(in Chinese). 沈迪新. 中国环境科学, 1992, 12(3), 193. 27 梅毅, 杨加强, 罗蜀峰, 等.中国专利, 201510994466.2. 2016. 28 Qin Y H, Nie C X, Zhang L. Environmental Protection Science, 2015, 41(1), 46(in Chinese). 秦毅红, 聂成肖, 张丽. 环境保护科学, 2015, 41(1), 46. 29 Chang S G, Liu D K. Nature, 1990, 343(6254), 151. 30 Chang S G. Environmental Progress & Sustainable Energy, 1992, 11(1), 66. 31 Liu N, Sun X, Ning P, et al. Materials Reports A: Review Papers, 2017, 31(9), 106(in Chinese). 刘娜, 孙鑫, 宁平,等. 材料导报:综述篇, 2017, 31(9), 106. 32 Li T Q. Journal of Cheng-du University of Science and Technology, 1993(1), 23(in Chinese). 李天全. 成都科技大学学报, 1993(1),23. 33 Qin L, Wang X N, Li Z Z, et al. Applied Chemical Industry, 2019, 48(3), 567(in Chinese). 覃岭, 王小妮, 李紫珍, 等. 应用化工, 2019, 48(3), 567. 34 Li S, Yang J Q, Wang C, et al. Energy & Fuels, 2018, 32, 5279. 35 Yang J Q.Study on removal of NOx from flue gas with yellow phosphorus composite pulp. Master's Thesis, Kunming University of Science and Technology, China, 2017(in Chinese). 杨加强.黄磷复合矿浆脱除烟气NOx的研究. 硕士学位论文, 昆明理工大学, 2017. 36 Wang L, Zhao W R, Wu Z B. Chemical Engineering Journal, 2007, 132(1-3), 227. 37 Karatza D, Prisciandaro M, Lancia A, et al. Industrial Engineering Chemistry Research, 2004, 43(16), 4876. 38 Oliveira A S, Costa A S, Demétrio I F, et al. Applied Catalysis B: Environmental, 2015, 162, 475. 39 Li B, Liu Y, Zhao X T, et al. Journal of Hazardous Materials, 2021, 403,123971. 40 Martins C R, Cabral Neto C A, Alves J F, et al. Journal of the Brazilian Chemical Society, 1999, 10(6), 453. 41 Nie C X. Study on simultaneous desulfurization and denitrification technology by liquid phase oxidation. Master's Thesis, Central South University, China, 2014(in Chinese). 聂成肖. 液相氧化同时脱硫脱硝技术研究. 硕士学位论文, 中南大学, 2014. 42 Li B, Wu H, Liu X L, et al. Journal of Hazardous Materials. 2020, 392, 122270. 43 Xiao H L. Study onliquid phase desulfurization and denitrification of nonferrous metal smelting slag. Master's Thesis, Kunming University of Science and Technology, China, 2019(in Chinese). 肖荷露. 有色金属冶炼渣液相脱硫脱硝研究. 硕士学位论文, 昆明理工大学, 2019. 44 Brandt C, Van Eldik R. Transition Metal Chemistry,1998,23(6),667. 45 Wu C J, Lv W H, Mei Y, et al,Chemical Industry and Engineering Progress. 2015, 34(12), 4368(in Chinese). 武春锦, 吕武华, 梅毅, 等. 化工进展, 2015, 34(12), 4368. 46 Wang F, Jia L J, Gao J Y, et al. Environmental Protection of Chemical Industry, 2018, 38(1), 72(in Chinese). 王访, 贾丽娟, 高冀芸, 等. 化工环保, 2018, 38(1), 72. 47 王访, 宁平, 贾丽娟, 等. 中国专利, 201710137346. X, 2017. 48 Liu H H, Ning P. Industrial Minerals & Processing, 2005(7), 14(in Chinese). 刘卉卉, 宁平. 化工矿物与加工, 2005(7), 14. 49 Jia L J, Li Z Z, Yao M, et al. Journal of Environmental Engineering, 2020, 146(7), 04020071. 50 宁平, 殷梁淘, 张秋林, 等.中国专利, 201811487659.9, 2019. 51 Yang J Q, Mei Y, Wang C, et al. Chemical Industry and Engineering Progress, 2017(2), 695(in Chinese). 杨加强, 梅毅, 王驰, 等. 化工进展, 2017(2), 695. 52 Yao S M, Wang B W. Chemical Industry and Engineering, 2020, 37(3), 1(in Chinese). 姚淑美, 王保伟. 化学工业与工程, 2020, 37(3), 1. 53 Yang Z K, Wu N, He R Y, et al. Applied Chemical Industry, 2020, 49(5), 1219(in Chinese). 杨忠凯, 武宁, 何如意, 等. 应用化工, 2020, 49(5), 1219. 54 Liu C L, Li J, Yang C L, et al. Chinese Journal of Chemical Enginee-ring, 2019, 27(10), 2566. 55 Chen L. Environmental Protection of Chemical Industry, 1997(3), 145(in Chinese). 陈理. 化工环保, 1997(3), 145. 56 Xing Y Q. Foreign Environmental Science and Technology, 1993(4), 57(in Chinese). 邢有权. 国外环境科学技术, 1993(4), 57. 57 Shen D X. China Environmental Protection Industry, 2002(8), 30(in Chinese). 沈迪新. 中国环保产业, 2002(8), 30.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2022, Vol. 36 
