矿浆法同时脱硫脱硝的研究进展与展望

doi:10.11896/cldb.20080316

材料导报

2022, Vol. 36

Issue (9): 20080316-7 https://doi.org/10.11896/cldb.20080316

无机非金属及其复合材料

矿浆法同时脱硫脱硝的研究进展与展望

骆燕苏¹, 李凯¹, 王驰², 王飞¹, 宋辛¹, 包加成¹, 宁平^1,*, 孙鑫^1,*

1 昆明理工大学环境科学与工程学院,昆明 650500
2 昆明理工大学化学工程学院,昆明 650500

Research Progress and Prospect of Simultaneous Desulfurization and Denitrification by Slurry

LUO Yansu¹, LI Kai¹, WANG Chi², WANG Fei¹, SONG Xin¹, BAO Jiacheng¹, NING Ping^1,*, SUN Xin^1,*

1 Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China
2 Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China

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摘要目前,寻求更高效和低廉的湿法同步脱硫脱硝技术对我国大气污染防治具有重要意义。本文重点介绍了矿浆法同步脱硫脱硝的研究进展,主要包括软锰矿浆、磷矿浆、钢渣浆液、铜渣浆液、赤泥浆液和水淬锰渣浆液等,并对其同步脱硫脱硝去除机理进行了深入探讨。同时对比评述了这六种矿浆脱硫脱硝技术的优缺点,总结发现利用矿浆结合氧化剂法同步脱硝技术不仅脱硫效率高、成本低,还可回收其尾液进行资源化利用,固废利用率高,并指出矿浆法仍存在机理研究不足、工业推广受限等问题。结合已有的研究成果,对未来矿浆法同步脱硫脱硝的研究提出了新的方向,认为对矿物或矿渣本身的改性以提高其脱硝性能以及对矿浆法全过程资源化的研究将成为新的热点。

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	骆燕苏
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	宋辛
	包加成
	宁平
	孙鑫

关键词: 矿浆同步脱硫脱硝资源化利用

Abstract: Presently, it is greatly significant for air pollution control to seek a highly efficient and low-cost wet process used for simultaneous removing SO₂ and NO_x. In this review, the emphasis is laid on the research progress of varied slurry methods for simultaneous removal of SO₂ and NO_x, including pyrolusite slurry, phosphate rock slurry, steel slag slurry, copper slag slurry, red mud slurry, water quenching manganese slag slurry, and so on. The review has made a further discussion on removal mechanisms of simultaneous removal of SO₂ and NO_x by different slurry methods. Meanwhile, the merits and shortcomings of the above six slurry methods are compared and evaluated. It is concluded that the slurry methods combined with oxidant methods not only obtain higher desulfurization efficiency and lower cost, but also can achieve recovery from tail liquid for resource utilization, obtaining the high utilization ratio of solid waste. Also, we point out the existed weakness of slurry methods, such as still lack of mechanism research and limited industrial scale. Furthermore, combining the existing research results, the future research directions for developing new slurry methods for simultaneous removal of SO₂ and NO_x are provided. It is believed that the modification of minerals or slag itself to improve its denitrification performance and the research on the resource utilization of the whole process of the slurry method will become new research focus.

Key words: slurry simultaneous desulfurization and denitrification resource utilization

出版日期: 2022-05-10 发布日期: 2022-05-09

ZTFLH:

X756

基金资助: 国家重点研发计划(2018YFC1900305;2018YFC0213400);国家自然科学基金(51708266;51968034;21667015;41807373);中国国家留学基金委(201808535082);云南省科技计划(2019FB069)

通讯作者: ningpingkmust@163.com; sunxin_kmust@163.com

作者简介: 骆燕苏,2018年6月、2021年6月分别于哈尔滨商业大学和昆明理工大学获得工学学士学位和硕士学位,硕士研究生期间在孙鑫教授的指导下进行研究。目前主要研究领域为矿浆法脱硫脱硝。
宁平,昆明理工大学环境科学与工程学院教授昆明理工大学教授。国家万人计划入选者、国家百千万人才、全国先进科技工作者、云南省科技领军人才,开展废气净化及资源化利用研究35年,先后任国家教育部环境工程教学指导分委员会副主任委员、中国环境科学学会理事、中国化学会理事等,现任冶金及化工行业废气资源化国家地方联合工程研究中心主任。主持国家863计划、国家支撑计划、国家自然科学基金重点等项目22项;以第一作者或通讯作者发表SCI、EI学术论文165篇;出版专著、教材29部;以第一发明人获授权发明专利56项;获国家技术发明二等奖1项,获国家教学成果一等奖、二等奖各1项。
孙鑫,昆明理工大学环境科学与工程学院教授。2010年于西北农林科技大学本科毕业,2015年于昆明理工大学环境工程专业博士毕业后留校工作至今,2019—2020年在美国怀俄明大学从事博士后研究。目前主要从事工业废气净化及资源化、大宗工业固体废物资源化利用等方面的研究工作。发表论文20余篇,包括Advanced Functional Mate-rials、Chemical Engineering Journal、Separation and Purification Technology等。

引用本文:

骆燕苏, 李凯, 王驰, 王飞, 宋辛, 包加成, 宁平, 孙鑫. 矿浆法同时脱硫脱硝的研究进展与展望[J]. 材料导报, 2022, 36(9): 20080316-7.
LUO Yansu, LI Kai, WANG Chi, WANG Fei, SONG Xin, BAO Jiacheng, NING Ping, SUN Xin. Research Progress and Prospect of Simultaneous Desulfurization and Denitrification by Slurry. Materials Reports, 2022, 36(9): 20080316-7.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.20080316 或 http://www.mater-rep.com/CN/Y2022/V36/I9/20080316

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