Abstract: Manganese ore slurry, phosphate ore slurry, vanadium ore slurry, magnesium slag slurry, copper slag slurry and red mud slurry are taken as the main objects of analysis, the existing desulfurization technologies of ore pulp are summarized. The experimental research or industrial application test of desulfurization technologies of manganese ore slurry, phosphate ore slurry, and vanadium ore slurry have been conducted. Industrial waste is used as a desulfurization agent in desulfurization technologies of magnesium slag slurry, copper slag slurry and red mud slurry, which can solve the problem of industrial waste treatment, and realize treating waste with waste and clean production. Meanwhile, this paper elaborates and explores the liquid phase catalytic oxidation of the alkaline metal oxide and metal ions. Then the mechanism (integrated industrial waste, such as manganese slag etc.), feasibility, and industrial applications of slurry desulfurizer in future research are pointed out.
刘娜, 孙鑫, 宁平, 李凯, 孙丽娜. 新型矿浆材料脱硫现状及研究进展[J]. 《材料导报》期刊社, 2017, 31(17): 106-111.
LIU Na, SUN Xin, NING Ping, LI Kai, SUN Lina. Current Status and Research Progress of Desulfurization Methods Using New Ore Slurry Material. Materials Reports, 2017, 31(17): 106-111.
1 James W M. The interaction of cobalt with hydrous manganese dio-xide [J]. Geo chemical et Cosmochimica Acta,1975,39(5):635. 2 Jin Huixin, Shi Lianjun, Li Junqi, et al. Study on SO2 absorption from waste gases by pyrolusite slurry [J]. Energy Eng,2003(4):33(in Chinese). 金会心, 史连军, 李军旗, 等. 用软锰矿浆吸收工业废气中SO2气体的研究[J]. 能源工程,2003(4):33. 3 Zhang Yimei, Ding Sanglan, Jang Wenju. Study in absorption of SO2 by low concentration pyrolusite slurry and thiobacillus ferrooxidans [J]. China′s Manganese Industry,2007,25(1):21(in Chinese). 张一梅, 丁桑岚, 蒋文举. 低浓度软锰矿与细菌脱除SO2的研究[J]. 中国锰业,2007,25(1):21. 4 Sun Weiyi, Su Shijun, Ding Sanglan, et al. Effect of O2 /SO2 ratio in the flue gas on manganese extract process and byproduct in the process of flue gas desulfurization with pyrolusite pulp[J].J Chem Eng Chinese Universities,2011,25(1):143(in Chinese). 孙维义, 苏仕军, 丁桑岚, 等. 烟气氧硫比对软锰矿浆烟气脱硫体系浸锰过程及脱硫产物的影响[J]. 高校化学工程学报,2011,25(1):143. 5 Wu Heng, Li Shuie, Hu Yalin. et al. Influence of pyrolusite impuritiies on desulfurization of sintering flue gas[J]. Hydrometallurgy of China,2015,34(2):146(in Chinese). 仵恒, 李水娥, 胡亚林, 等. 软锰矿中的杂质对烧结烟气脱硫的影响[J]. 湿法冶金,2015,34(2):146. 6 Sun Shili, Zhu Xiaofan. Study on pyrolusite coexisting component in flue gas desulfurization [J]. Technol Development Chem Industry,2005,34(3):54(in Chinese). 孙世利, 朱晓帆. 软锰矿共存组分在烟气脱硫过程中的实验研究[J]. 化工技术与开发,2005,34(3):54. 7 Li Shuie, Li Wei, Pan Feifei, et al. Enrichment and purification process of by-product manganes sulfate in the flue gas desulphurization [J]. Guangzhou Chem Industry,2016,44(1):53(in Chinese). 李水娥, 李伟, 潘飞飞, 等. 烟气脱硫副产物硫酸锰的富集及净化工艺的研究 [J]. 广州化工,2016,44(1):53. 8 Xu Ying, Su Shijun, Sun Weiyi. Washing recovery manganese and ammonium sulfate from the tail slag of desulfurization [J]. China′s Manganese Industry,2011,29(1):17(in Chinese). 徐莹, 苏仕军, 孙维义. 脱硫尾渣中硫酸铵及锰离子的洗涤回收[J]. 中国锰业,2011,29(1):17. 9 Lang ting, Xu Dongdong, Yi Mengyu, et al. Preparation of sulphoaluminate cement clinkers from pyrolusite flue gas desulfurization slag[J]. Environmental Eng,2014,32(10):108(in Chinese). 郎婷, 许东东, 易梦雨, 等. 软锰矿烟气脱硫渣制备硫铝酸盐水泥熟料[J]. 环境工程,2014,32(10):108. 10 Ren Zhiling, Zhu Xiaofan, Jiang Wenju, et al. Study on flue gas desulfurization reactor with pyrolusite slurry[J]. Techniques and Equipment for Environmental Pollution Control,2004,5(11):90 (in Chinese). 任志凌, 朱晓帆, 蒋文举, 等 .软锰矿浆烟气脱硫反应器试验研究[J]. 环境污染治理技术与设备,2004,5(11):90. 11 Liu Lianli, Zhang Hui. Design of multistage reactor and study on flue gas desulfurization with pyrolusite slurry [J]. Chem World,2010(8):449(in Chinese). 刘连利, 张惠. 单塔多级吸收反应器设计与软锰矿浆烟气脱硫实验研究[J]. 化学世界,2010(8):449. 12 Wu Fuzhong, Li Junqi, Cai Jiuju, et al. Study on flue gas desulfurization of sintering in pilot-scale experiment [J]. Chinese J Process Eng,2009,9(S1):66(in Chinese). 吴复忠, 李军旗, 蔡九菊, 等. 烧结烟气脱硫中试研究[J]. 过程工程学报,2009,9(S1):66. 13 Liu Huihui, Ning Ping. Study on wet desulfurization by phosphate ore pulp[J]. Industrial Minerals Processing,2006(7):12(in Chinese). 刘卉卉, 宁平. 磷矿浆催化氧化湿法脱硫研究(Ⅱ)[J]. 化工矿物与加工,2006(7):12. 14 Liu Huihui , Ning Ping. Microwave heat effect of aqueous catalytic oxidization of sulphur dioxide removal by phosphoric ore pulp [J]. Eng Sci,2005,7(S1):425(in Chinese). 刘卉卉, 宁平. 微波辐照对磷矿浆吸收SO2的影响[J]. 中国工程科学,2005,7(S1):425. 15 Meng Lei, Gan Haiming, Yang Chunping, et al. Modular experimental device of double-cycle process for desulphurization and dust removal [J]. Experimental Technol Management,2008,25(4):76(in Chinese). 孟蕾, 甘海明, 杨春平, 等. 模块组合式双循环脱硫除尘实验装置[J]. 实验技术与管理,2008,25(4):76. 16 梅毅, 武春锦, 李慧, 等. 一种脱除尾气中SO2的方法: 中国,201410496692.3[P].2015-01-07. 17 Bin Zhiyong. Progress of the research on extraction of vanadium pentoxide from stone coal and the market of the V2O5 [J].Hunan Nonferrous Metals,2006,22(1):16(in Chinese). 宾智勇. 石煤提钒研究进展与五氧化二钒的市场状况[J]. 湖南有色金属,2006,22(1):16. 18 Pan Yong, Yu Jishun, Wu Hongdan. Process evaluation of vanadium extraction from stone coal[J]. Express Information Mining Industry,2007(4):10(in Chinese). 潘勇,于吉顺,吴红丹. 石煤提钒的工艺评价[J]. 矿业快报,2007(4):10. 19 Chen Fang. Performance of desulfurizing absorbent of roasted navajoite[D]. Changsha: Hunan University,2007(in Chinese). 陈芳. 焙烧钒矿脱硫剂的脱硫性能[D].长沙:湖南大学,2010. 20 Fan Baoguo, Yang Jing, Liu June, et al. Study of the denaturing of the agent for desulfurizing magnesium slag through hydration by using additives[J]. J Eng Thermal Energy Power,2013,28(4):415(in Chinese). 樊保国, 杨靖, 刘军娥,等. 镁渣脱硫剂的水合及添加剂改性研究[J]. 热能动力工程,2013,28(4):415. 21 Duan Liping, Kou Binda, Ji Kedan, et al. Experimental research on desulfurzation performance of magnesium slag in circulating fluidized bed boiler[J]. Thermal Power Generation,2016,45(1):82(in Chinese). 段丽萍, 寇斌达, 姬克丹, 等. 镁渣应用于循环流化床锅炉脱硫的试验 [J]. 热力发电,2016,45(1):82. 22 Li Lei, Wang Hua, Hu Jianhang, et al. Study development of the comprehensive utilization of copper slag [J]. Energy Metall Ind,2009,28(1):44(in Chinese). 李磊, 王华, 胡建杭, 等.铜渣综合利用的研究进展[J]. 冶金能源,2009,28(1):44. 23 张恒. 铜渣/Ca(OH)2/H2O2混合浆液烟气同时脱硫脱硝实验研究[D].昆明:昆明理工大学,2015. 24 Li Huiping, Jin Sujing, Li Xueping, et al. Study on industrial flue gas desulfurization(FGD) by alumina red mud [J]. J Zhengzhou University:Eng Sci,2013,34(3):34(in Chinese). 李惠萍, 靳苏静, 李雪平, 等. 工业烟气的赤泥脱硫研究[J]. 郑州大学学报:工学版,2013,34(3):34. 25 Hong Yuming. The experimental study and application of new type desulfurizer [J]. Light Metals,2015(2):14(in Chinese). 洪玉明. 新型脱硫剂的试验研究及应用[J]. 轻金属,2015(2):14. 26 Zhu Xiaofan. Research in flue gas desulphurization with pyrolusite [D].Chengdu: Sichuan University,2002. 朱晓帆. 软锰矿烟气脱硫研究[D]. 成都:四川大学, 2002. 27 Liu Jianying, Tan Xiandong, Xin Xin. Progress in flue gas desulphurization with pyrolusite [J]. Resource Development Market,2009,25(3):196(in Chinese). 刘建英, 谭显东, 信欣. 软锰矿烟气脱硫的研究进展[J]. 资源开发与市场,2009,25(3):196. 28 Tang Zhengguang, Jiang Wenju. Process and mechanism of catalyzed oxidation of SO2 with pyrolusite slurry [J]. Environmental Sci Technol,2008,31(2):13(in Chinese). 汤争光, 蒋文举. 软锰矿催化氧化二氧化硫的过程与机理研究 [J]. 环境科学与技术,2008,31(2):13. 29 Huss A, Llm P K Jr, et al.Oxidation of aqueous sulfur dioxide. High-pressure studies and proposed reaction mechanisms [J] . J Phys Chem,1982,86(21):4229(in Chinese). 30 Sun Peishi, Ning Ping, Song Wenbiao. Study on purifiaction of smeltingt-gases containing SO2 in low concentration by liquid phase catalytic oxidation method [J].Enviroment Science,1996,17(4):4(in Chinese). 孙佩石, 宁平, 宋文彪. 低浓度SO2冶炼烟气的液相催化法净化处理研究 [J]. 环境科学,1996,17(4):4. 31 Han liang, Cai Xuguang, Yu Yang. Analysis of magnesium desulfurization technology [J].District Heating,2010(4):40(in Chinese). 韩良,蔡旭光,于洋. 简析氧化镁脱硫技术应用[J]. 区域供热,2010(4):40. 32 Shen Hongtufei. New flue gas desulfurization technology non-ferrous metal waste pyrometallurgical [J]. Resource Saving Environmental Protection,2015(3):270(in Chinese). 申屠洪飞. 有色金属废弃物火法冶炼烟气脱硫新工艺[J]. 资源节约环保,2015(3):270. 33 Liu Shibin, Li Chunru. Desulfurization kinetics of complex metal oxides [J]. J Flue Chem Technol,1998,26(1):83(in Chinese). 刘世斌, 李存儒. 复合金属氧化物脱硫剂脱除SO2动力学[J]. 燃料化学学报,1998,26(1):83. 34 Zhu Deqing, Pan Jian, Pan Runrun. Transition metal ions for liquid catalyzed oxidation desulphuration of flue gas of low SO2 concentration [J]. J Central South University: Sci Technol,2003,34(5):489(in Chinese). 朱德庆, 潘建, 潘润润. 过渡金属离子液相催化氧化低浓度烟气脱硫[J]. 中南工业大学学报:自然科学版,2003,34(5):489. 35 Ning Ping, Song Wenbiao, Sun Peishi. A study on catalytic oxidation of low SO2 in aqueous solution to produce compound fertilizer [J]. Enviroment Science,1991,12(5):10(in Chinese). 宁平, 宋文彪, 孙珮石. 液相催化氧化净化低浓度SO2生产复肥研究[J]. 环境科学,1991,12(5):10. 36 Zhao Yi, Ma Shuangchen, Hua Wei, et al. Study on the control technique and the law of transport for mercury resulting from combustion of coal in power plant[J]. Techniques and Equipment for Environmental Pollution Control,2003,4(11):59(in Chinese). 赵毅,马双忱,华伟, 等. 电厂燃煤过程中汞的迁移转化及控制技术研究[J]. 环境污染治理技术与设备,2003,4(11):59. 37 Chen Chuanmin, Zhao Yi, Ma Shuangchen, et al. Flue gas desulfurization based on Mn-Fe synergistic catalyzed [J].J North China Electric Power University,2001,28(4):80(in Chinese). 陈传敏,赵毅,马双忱, 等. Mn-Fe协同催化氧化脱除烟气中SO2的研究[J]. 华北电力大学学报,2001,28(4):80. 38 Ma Shuangchen, Zhao Yi, Zheng Fuling, et al. Study on reducing SO2/NOx in flue gas by aqueous catalytic oxidation [J]. China Environmental Sci,2001,21(1):33(in Chinese). 马双忱,赵毅,郑福玲, 等. 液相催化氧化脱除烟道气中SO2和NOx的研究 [J]. 中国环境科学,2001,21(1):33. 39 Ulrich R K, Rochelle G T, Parada R E. Enhanced oxygen absorption into bisulphite solution containing transition metal ion catalysts[J]. Chem Eng Sci,1986,41(8):2183. 40 Wang Hua, Zhu Sheming, Li Weifeng. New development of controlling SO2 pollution from flue gas [J]. Power System Eng,2006,22(6):5(in Chinese). 王华, 祝社民, 李伟峰. 烟气脱硫技术研究新进展[J]. 电站系统工程,2006,22(6):5. 41 Zhao Gaiju, Lu Chunmei, Tian Yuan. Desulfurzation characteristic and mechanism of red mud from alumia plant [J]. J Flue Chem Technol,2008,36(3):365(in Chinese). 赵改菊, 路春美,田园. 赤泥的固硫特性及其机理研究[J]. 燃料化学学报,2008,36(3):365. 42 Wei Peng, Li Huiping, Jin Sujing, et al. Research of alumina red mud for industrial flue gas desulfurization [J]. Chem Industry Eng Progress,2011(S1):344(in Chinese). 位朋, 李惠萍, 靳苏静, 等. 氧化铝赤泥用于工业烟气脱硫的研究[J]. 化工进展,2011(S1):344.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2017, Vol. 31 
