Abstract: In a world with rising concern about energy security, environmental crisis, and global warming, exploring superior catalysts for oxygen evolution reaction, super capacitor, and the treatment of pollutant ions in waste water are getting more and more attention. Layered double hydro-xide (LDH) has many properties such as memory effect, nice catalysis ability, anion exchange, acid-base and thermal stability, which has been widely concerned in various fields to solve the above problems. LDH has excellent performance for oxygen evolution electrocatalysis, low cost, adjustable structure. The intercalation reaction can be carried out between layers of LDH. However, the poor electron conductivity of LDH reduces its electrochemical performance. Moreover, the LDH layers are easy to agglomerate in the synthesis process, resulting low conductivity and low catalytic activity. These problems can be solved by improving the synthesis method of LDH and compounding LDH with various functional materials. In recent years, in order to improve the conductivity of LDH, researchers have in situ grown LDH on various conductive substrate, which can expose more active sites and as a result improve the catalytic activity of LDHs. By compounding LDH with graphene, the specific capacitance, conductivity and cycle stability of LDH/graphene composites can be enhanced, and the adsorption capacity of LDH for CO2 can also be improved, making LDH widely used to solve energy crisis and environmental pollution problems. This article reviews the synthesis methods of LDH and LDH composites, and summarizes the applications of LDH and its composites in catalysis, energy storage, and environmental protection in recent years. First, the application of LDH in electrocatalytic water oxidation and photocatalysis is introduced, and then the application of LDH materials in supercapacitors and environmental problems such as water pollution treatment is described.
作者简介: 杨正芳,现为昆明理工大学理学院的研究生,在胡觉教授的指导下进行研究。目前主要研究领域为层状双金属氢氧化物的合成与应用。 胡觉,昆明理工大学教授。2012年毕业于中国科学院合肥物质科学研究院,获博士学位,2014—2017年分别在美国布鲁克海文国家实验室和香港科技大学进行博士后研究。入选中国科学院青年创新促进会、云南省千人计划青年人才,获云南省基础研究计划“优秀青年”基金。近年来,在金属基能源催化材料领域发表论文40余篇,包括Journal of The American Chemical Society、Energy & Environmental Science、Joule、Advanced Energy Materials、Advanced Functional Materials、Nano Energy、ACS Catalysis、Small、Journal of Materials Chemistry A等。
引用本文:
杨正芳, 张悦, 蔡金霄, 刘志勇, 胡觉. 层状双金属氢氧化物及其复合材料的制备与应用研究新进展[J]. 材料导报, 2021, 35(19): 19062-19069.
YANG Zhengfang, ZHANG Yue, CAI Jinxiao, LIU Zhiyong, HU Jue. Recent Advances in the Preparation and Application of Layered Double Hydroxides and Their Composites. Materials Reports, 2021, 35(19): 19062-19069.
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