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材料导报  2020, Vol. 34 Issue (6): 6161-6165    https://doi.org/10.11896/cldb.19010153
  高分子与聚合物基复合材料 |
共价有机聚合物/石墨烯复合材料的制备及锂电性能研究
高国梁1,2, 张海涛1, 李晨斌1, 王德宇1, 沈彩1
1 中国科学院宁波材料技术与工程研究所,宁波 315201;
2 华东师范大学物理与材料科学学院,上海市磁共振重点实验室,上海 200062
Synthesis and Li-ion Storage Properties of COPs/rGO Composites
GAO Guoliang1,2, ZHANG Haitao1, LI Chenbin1, WANG Deyu1, SHEN Cai1
1 Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China;
2 Shanghai Key Laboratory of Magnetic Resonance, College of Physics and Materials Science, East China Normal University, Shanghai 200062, China
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摘要 共价有机聚合物(COPs)作为一类新型材料,凭借其诸多优异特性得到越来越广泛的应用。本实验以三聚氰胺和1,4-二溴丁烷为原料合成片层结构的三聚氰胺基共价有机聚合物,片层厚度为3.5nm左右。采用原位掺杂石墨烯(rGO)的方式制备COPs/rGO复合材料并测试了其作为锂电池负极材料的电化学性能。实验结果显示,电极材料在50mA/g的条件下充放电循环100次后仍然保持有420mAh/g的放电比容量,同时表现出优异的高电流密度和倍率性能。由此可以看出该COPs/rGO复合材料是一种很有前景的储锂材料。
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高国梁
张海涛
李晨斌
王德宇
沈彩
关键词:  锂电池  共价有机聚合物  石墨烯  电化学性能    
Abstract: Covalent organic polymer (COPs) is a kind of crystalline microporous polymer, which has been widely used due to its many excellent properties, such as high specific surface area, abundant pore size structure, low weight density. Here, melamine-based COPs with the lamellar structure were synthesized using melamine and 1,4-dibromobutane. The thickness of the flake is about 3.5 nm. COPs/rGO composites were prepared by in situ doping graphene (rGO) and the electrochemical performance as a lithium-ion battery anode materials was studied. The composite materials show a reversible capacity of 420 mAh/g after 100 cycles at a current density of 50 mA/g, at the same time, it shows excellent high current density and rate capability.
Key words:  lithium-ion batteries    covalent organic polymer    graphene    electrochemical performance
                    发布日期:  2020-03-12
ZTFLH:  TM912.9  
基金资助: 宁波市自然科学基金(2018A610011);高性能陶瓷和超微结构国家重点实验室(SKL201805SIC)
作者简介:  高国梁,2017年6月毕业于华南师范大学,获得硕士学位。于2016年4月至2017年4月在中科院宁波材料技术与工程研究所联合培养学习,主要从事锂离子电池负极材料的研究;沈彩,中国科学院宁波材料技术与工程研究所,副研究员,硕士生导师。宁波市“3315计划”创新人才; 中科院青年创新促进会会员。2008年在英国圣安得鲁斯大学化学系获得博士学位。曾在美国马里兰大学、德国海德堡大学、丹麦奥胡斯大学从事研究工作。主要致力于材料表/界面微观结构分析与新型锂离子电池电极材料的开发。在JACS, ACS Nano, Chem. Sci. Small Methods, Ultramicroscopy和Journal of Microscopy等学术期刊上发表论文70多篇,引用1 600多次,H-index 27;申请发明专利10多项 (授权7项)。主持国家自然科学基金青年基金、宁波市自然科学基金等项目。作为子课题/子任务负责人参与国家重点研发计划“新能源汽车”专项、宁波市“科技创新2025”重大专项“高比能锂金属二次电池技术”等项目。
引用本文:    
高国梁, 张海涛, 李晨斌, 王德宇, 沈彩. 共价有机聚合物/石墨烯复合材料的制备及锂电性能研究[J]. 材料导报, 2020, 34(6): 6161-6165.
GAO Guoliang, ZHANG Haitao, LI Chenbin, WANG Deyu, SHEN Cai. Synthesis and Li-ion Storage Properties of COPs/rGO Composites. Materials Reports, 2020, 34(6): 6161-6165.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19010153  或          http://www.mater-rep.com/CN/Y2020/V34/I6/6161
1 Martin W, Jurgen O B, Michael E S, et al. Advanced Materials, 1998, 10 (10), 725.
2 Cote A P, Benin A I, Ockwig N W, et al. Science, 2005, 310, 1166.
3 Hani M, Hunt J R, Mendoza C J L, et al. Science, 2007, 316, 268.
4 Huang N, Wang P, Jiang D. Nature Reviews Materials, 2016, 1 (10),16068.
5 Sang S H, Hiroyasu F, Omar M Y. Journal of the American Chemical Society, 2008, 130 (35), 11580.
6 Buyukcakir O, Je S H, Talapaneni S N, et al. ACS Applied Materials & Interfaces, 2017, 9 (8), 7209.
7 Furukawa H, Yaghi O M. Journal of the American Chemical Society, 2009,131 (25), 8875.
8 Wei P, Qi M, Wang Z, et al. Journal of the American Chemical Society, 2018, 140 (13), 4623.
9 Ding S, Gao J, Wang Q, et al. Journal of the American Chemical Society, 201, 133 (49), 19816.
10 Xie M, Xiong X, Yang L, et al. Chemical Communications, 2018, 54, 2300.
11 Sick T, Hufnagel A, Kampmann J, et al. Journal of the American Chemical Society, 2018, 140 (6), 2085.
12 Ding X, Chen L, Yoshihito H, et al. Journal of the American Chemical Society, 2011, 133 (37), 14510.
13 Lei Z, Yang Q, Xu Y, et al. Nature Communications, 2018, 9, 576.
14 Patil N, Aqil A, Ouhib F, et al. Advanced Materials, 2017, 29 (40), 1703373.
15 Wang S, Wang Q, Shao P, et al. Journal of the American Chemical Socie-ty, 2017, 139 (12), 4258.
16 Nurettin S, Sahin D, Kivanc S. Journal of Porous Materials, 2016, 23, 1025.
17 Merline D J, Vukusic S, Abdala A A. Polymer Journal, 2013, 45, 413.
18 Mircescu N E, Oltean M, Vasile C, et al. Vibrational Spectroscopy, 2012, 62 (9), 165.
19 Kang H, Liu H, Li C, et al. ACS Applied Materials & Interfaces, 2018, 10, 27023.
20 Yang H, Zhang S, Han L, et al. ACS Applied Materials & Interfaces, 2016, 8 (8), 5366.
21 Gou L, Ma L, Zhao M J, et al. Journal of Materials Science, 2019, 54 (2), 1529.
22 Pei X Y, Mo D C, Lyu S S, et al. Applied Surface Science, 2019, 465, 470.
23 Chen H, Michel A, Matthieu C, et al. Journal of the American Chemical Society, 2009, 131 (25), 8984.
24 Takeo S, Hiroki O, Shuhei S, et al. Advanced Materials, 2009, 21 (16), 1627.
25 Luo Z, Liu L, Ning J, et al. Angewandte Chemie International Edition, 2018, 57, 9443.
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